docs: improve section on override options

Author: sweb

docs/modules/airflow/pages/usage-guide/overrides.adoc

@@ -40,8 +40,8 @@ webservers:
       config: {}
 ----
 
-Although Kubernetes can override these settings in one of two ways (Configuration overrides, or Environment Variable overrides), the effect is the same
-and currently only the latter is implemented.
+Note that `configOverrides` is specifically supported for customizing `webserver_config.py`.
+To override standard Airflow configuration properties (listed in the Configuration Reference), use `envOverrides` with the `AIRFLOW__SECTION__KEY` format, as the operator injects these via environment variables rather than modifying a static config file.
 This is described in the following section.
 
 == Environment Variables