test4.json

{"licenses": [{"name": "", "id": 0, "url": ""}], "info": {"contributor": "Jiang Guo", "date_created": "Feb. 01", "description": "A dataset for chemical visual diagram analysis", "url": "", "version": "v1", "year": "2022"}, "categories": [{"id": 1, "name": "structure"}, {"id": 2, "name": "text"}, {"id": 3, "name": "identifier"}, {"id": 4, "name": "supplement"}], "images": [{"id": 976, "width": 1088, "height": 1428, "file_name": "ja0547477-Scheme-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [276.35, 565.06, 330.63, 73.58], "category_id": 1}, {"id": 1, "bbox": [0.0, 926.52, 522.71, 462.9], "category_id": 1}, {"id": 2, "bbox": [238.51, 1380.85, 57.12, 42.86], "category_id": 3}, {"id": 3, "bbox": [680.53, 2.86, 406.31, 157.16], "category_id": 1}, {"id": 4, "bbox": [432.74, 625.06, 57.13, 47.86], "category_id": 3}, {"id": 5, "bbox": [399.18, 1130.83, 138.53, 57.86], "category_id": 2}, {"id": 6, "bbox": [238.51, 845.08, 53.55, 43.58], "category_id": 3}, {"id": 7, "bbox": [0.0, 0.0, 291.35, 160.02], "category_id": 1}, {"id": 8, "bbox": [238.51, 501.48, 55.69, 41.43], "category_id": 3}, {"id": 9, "bbox": [818.35, 500.76, 59.27, 47.15], "category_id": 3}, {"id": 10, "bbox": [860.48, 690.78, 200.66, 57.87], "category_id": 2}, {"id": 11, "bbox": [148.53, 120.01, 56.41, 45.01], "category_id": 3}, {"id": 12, "bbox": [17.14, 645.78, 496.29, 227.16], "category_id": 1}, {"id": 13, "bbox": [565.56, 925.81, 521.28, 463.61], "category_id": 1}, {"id": 14, "bbox": [611.26, 213.59, 474.87, 307.18], "category_id": 1}, {"id": 15, "bbox": [343.48, 17.14, 289.92, 90.73], "category_id": 2}, {"id": 16, "bbox": [799.07, 1380.85, 56.41, 42.86], "category_id": 3}, {"id": 17, "bbox": [359.9, 255.03, 274.93, 147.15], "category_id": 2}, {"id": 18, "bbox": [17.14, 272.88, 496.29, 253.6], "category_id": 1}, {"id": 19, "bbox": [861.91, 120.01, 46.41, 40.72], "category_id": 3}], "caption": "Scheme 2. Synthesis of Chiral Sulfoxide Cyclization Precursor 15a ", "pdf": {"Page": 5, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 64, 389, 88], "ImageBB": [106, 92, 378, 449]}, "reactions": [{"reactants": [7], "conditions": [15], "products": [3]}, {"reactants": [18], "conditions": [17], "products": [14]}, {"reactants": [12], "conditions": [4], "products": [18]}, {"reactants": [14], "conditions": [10], "products": [13]}, {"reactants": [13], "conditions": [5], "products": [1]}], "diagram_type": "tree"}, {"id": 102, "width": 1348, "height": 852, "file_name": "ja026640e-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [180.02, 9.01, 350.38, 257.47], "category_id": 1}, {"id": 1, "bbox": [867.0, 282.82, 65.56, 32.56], "category_id": 3}, {"id": 2, "bbox": [6.88, 348.67, 1336.62, 493.42], "category_id": 4}, {"id": 3, "bbox": [325.48, 279.15, 16.67, 32.56], "category_id": 3}, {"id": 4, "bbox": [585.85, 89.68, 87.55, 31.34], "category_id": 2}, {"id": 5, "bbox": [766.76, 12.67, 404.17, 255.04], "category_id": 1}], "reactions": [{"reactants": [0], "conditions": [4], "products": [5]}], "corefs": [[0, 3], [5, 1]], "caption": "Table 1. Product Studies for the Ene Reaction of ArNO, PTAD and 1O2 with the Optically Active Tiglic Amides 1a,b ", "pdf": {"Page": 1, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 323, 757, 348], "ImageBB": [439, 352, 776, 565]}, "diagram_type": "single"}, {"id": 117, "width": 1336, "height": 1540, "file_name": "op980184q-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [295.9, 86.0, 84.1, 60.1], "category_id": 2}, {"id": 1, "bbox": [10.9, 1303.9, 521.1, 188.1], "category_id": 1}, {"id": 2, "bbox": [815.0, 1001.0, 512.0, 177.1], "category_id": 1}, {"id": 3, "bbox": [16.0, 1001.0, 499.0, 171.1], "category_id": 1}, {"id": 4, "bbox": [32.8, 523.9, 515.2, 176.2], "category_id": 1}, {"id": 5, "bbox": [931.0, 86.0, 255.0, 61.0], "category_id": 2}, {"id": 6, "bbox": [188.0, 1500.0, 50.1, 40.0], "category_id": 3}, {"id": 7, "bbox": [199.0, 1203.0, 45.0, 51.0], "category_id": 3}, {"id": 8, "bbox": [559.7, 85.0, 306.3, 154.0], "category_id": 1}, {"id": 9, "bbox": [1070.0, 833.03, 51.0, 53.0], "category_id": 3}, {"id": 10, "bbox": [239.0, 734.93, 47.0, 56.1], "category_id": 3}, {"id": 11, "bbox": [747.9, 1311.9, 562.1, 175.1], "category_id": 1}, {"id": 12, "bbox": [14.9, 75.9, 216.1, 161.2], "category_id": 1}, {"id": 13, "bbox": [669.9, 253.0, 43.1, 57.1], "category_id": 3}, {"id": 14, "bbox": [57.95, 256.03, 57.0, 48.0], "category_id": 3}, {"id": 15, "bbox": [543.0, 1031.9, 202.0, 58.1], "category_id": 2}, {"id": 16, "bbox": [982.0, 1194.0, 54.0, 47.0], "category_id": 3}, {"id": 17, "bbox": [1021.0, 1489.0, 46.0, 51.0], "category_id": 3}, {"id": 18, "bbox": [590.0, 525.0, 182.0, 70.0], "category_id": 2}, {"id": 19, "bbox": [804.0, 661.0, 532.0, 179.0], "category_id": 1}, {"id": 20, "bbox": [812.0, 421.0, 524.0, 161.0], "category_id": 1}, {"id": 21, "bbox": [997.0, 309.0, 36.0, 48.0], "category_id": 3}, {"id": 22, "bbox": [878.0, 200.0, 300.0, 119.0], "category_id": 1}, {"id": 23, "bbox": [590.0, 621.0, 180.0, 51.0], "category_id": 2}, {"id": 24, "bbox": [1058.92, 563.58, 43.66, 43.66], "category_id": 3}], "reactions": [{"reactants": [12], "conditions": [0], "products": [8]}, {"reactants": [8], "conditions": [5, 22], "products": [4]}, {"reactants": [4], "conditions": [18, 23], "products": [20, 19]}, {"reactants": [3], "conditions": [15], "products": [2]}], "corefs": [[12, 14], [8, 13], [22, 21], [4, 10], [20, 24], [19, 9], [3, 7], [2, 16], [1, 6], [11, 17]], "caption": "Figure 1. Compound 1.", "pdf": {"Page": 1, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 309, 576, 323], "ImageBB": [440, 333, 774, 718]}, "diagram_type": "multiple"}, {"id": 643, "width": 1352, "height": 1448, "file_name": "ol500618w-Table-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [710.33, 85.33, 301.57, 89.77], "category_id": 2}, {"id": 1, "bbox": [467.93, 137.79, 139.17, 103.51], "category_id": 1}, {"id": 2, "bbox": [1087.73, 0.0, 154.07, 129.2], "category_id": 1}, {"id": 3, "bbox": [1018.33, 245.66, 295.97, 132.64], "category_id": 1}, {"id": 4, "bbox": [1014.0, 436.0, 338.0, 52.5], "category_id": 2}, {"id": 5, "bbox": [0.0, 238.2, 313.6, 129.3], "category_id": 1}, {"id": 6, "bbox": [71.3, 24.2, 169.1, 127.3], "category_id": 1}, {"id": 7, "bbox": [703.0, 204.0, 311.0, 138.0], "category_id": 2}, {"id": 8, "bbox": [88.31, 442.28, 126.88, 52.25], "category_id": 2}, {"id": 9, "bbox": [8.0, 517.0, 1344.0, 931.0], "category_id": 4}, {"id": 10, "bbox": [127.0, 384.0, 54.0, 47.0], "category_id": 3}, {"id": 11, "bbox": [1140.0, 388.0, 56.0, 45.0], "category_id": 3}, {"id": 12, "bbox": [501.0, 274.0, 69.0, 52.0], "category_id": 3}, {"id": 13, "bbox": [468.97, 339.65, 130.61, 54.12], "category_id": 2}], "reactions": [{"reactants": [6, 1], "conditions": [0, 7], "products": [2]}, {"reactants": [5, 1], "conditions": [0, 7], "products": [3]}], "corefs": [[5, 10], [1, 12], [3, 11]], "caption": "Table 4. Chemoselective Cyanation of Alkenyl Halides", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 390, 110], "ImageBB": [82, 116, 420, 478]}, "diagram_type": "single"}, {"id": 1271, "width": 1800, "height": 1912, "file_name": "op0602270-Scheme-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [495.42, 0.0, 331.88, 325.2], "category_id": 1}, {"id": 1, "bbox": [269.71, 1497.84, 109.99, 69.83], "category_id": 2}, {"id": 2, "bbox": [645.58, 381.63, 328.05, 66.96], "category_id": 2}, {"id": 3, "bbox": [1347.59, 1061.69, 452.41, 398.85], "category_id": 3}, {"id": 4, "bbox": [877.99, 1505.5, 297.44, 67.91], "category_id": 2}, {"id": 5, "bbox": [61.21, 1092.3, 440.91, 322.33], "category_id": 1}, {"id": 6, "bbox": [948.76, 882.83, 387.35, 110.95], "category_id": 2}, {"id": 7, "bbox": [877.99, 1095.17, 387.35, 324.24], "category_id": 1}, {"id": 8, "bbox": [379.7, 1356.29, 51.64, 56.43], "category_id": 3}, {"id": 9, "bbox": [642.71, 471.54, 447.6, 64.09], "category_id": 2}, {"id": 10, "bbox": [495.42, 585.36, 340.49, 322.34], "category_id": 1}, {"id": 11, "bbox": [495.42, 1587.75, 393.09, 324.25], "category_id": 1}, {"id": 12, "bbox": [0.0, 886.66, 383.52, 109.99], "category_id": 2}], "caption": "Scheme 3. Synthetic approach to 4,5-dihydro-3H-dinaphtho[2,1-c;1\u2032,2\u2032-e]phosphepine ligands 6", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 53, 599, 67], "ImageBB": [200, 71, 650, 549]}, "reactions": [{"reactants": [0], "conditions": [2, 9], "products": [10]}, {"reactants": [10], "conditions": [12], "products": [5]}, {"reactants": [5], "conditions": [1], "products": [11]}, {"reactants": [11], "conditions": [4], "products": [7]}, {"reactants": [10], "conditions": [6], "products": [7]}], "diagram_type": "graph"}, {"id": 119, "width": 1344, "height": 732, "file_name": "op980039c-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [566.0, 419.0, 371.0, 67.2], "category_id": 2}, {"id": 1, "bbox": [690.86, 503.71, 114.14, 55.66], "category_id": 2}, {"id": 2, "bbox": [1102.0, 679.0, 37.0, 48.0], "category_id": 3}, {"id": 3, "bbox": [234.0, 4.0, 328.0, 272.0], "category_id": 1}, {"id": 4, "bbox": [2.0, 27.0, 132.0, 216.0], "category_id": 1}, {"id": 5, "bbox": [955.0, 359.0, 385.0, 261.0], "category_id": 1}, {"id": 6, "bbox": [399.0, 289.0, 65.0, 51.0], "category_id": 3}, {"id": 7, "bbox": [44.0, 292.0, 40.0, 48.0], "category_id": 3}], "reactions": [{"reactants": [4, 3], "conditions": [0, 1], "products": [5]}], "corefs": [[4, 7], [3, 6], [5, 2]], "caption": "Table 1. 1.3-Dipolar cycloaddition of the N-imine (4) with the alkyne (5b) ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 267, 396, 295], "ImageBB": [75, 72, 411, 255]}, "diagram_type": "single"}, {"id": 446, "width": 1344, "height": 988, "file_name": "op200174k-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [29.3, 66.6, 213.7, 341.8], "category_id": 1}, {"id": 1, "bbox": [258.0, 87.6, 203.8, 315.1], "category_id": 1}, {"id": 2, "bbox": [492.0, 104.0, 318.4, 117.1], "category_id": 2}, {"id": 3, "bbox": [1108.8, 275.0, 207.2, 69.0], "category_id": 2}, {"id": 4, "bbox": [519.0, 257.0, 237.0, 142.0], "category_id": 2}, {"id": 5, "bbox": [1.0, 633.0, 1343.0, 355.0], "category_id": 4}, {"id": 6, "bbox": [105.0, 449.0, 70.0, 60.0], "category_id": 3}, {"id": 7, "bbox": [377.0, 454.0, 45.0, 53.0], "category_id": 3}, {"id": 8, "bbox": [903.0, 546.0, 75.0, 55.0], "category_id": 3}, {"id": 9, "bbox": [1179.0, 202.0, 70.0, 67.0], "category_id": 3}, {"id": 10, "bbox": [504.0, 431.0, 282.0, 50.0], "category_id": 2}, {"id": 11, "bbox": [823.0, 0.0, 299.0, 514.0], "category_id": 1}], "reactions": [{"reactants": [0, 1], "conditions": [2, 4, 10], "products": [11, 9]}], "corefs": [[0, 6], [1, 7], [11, 8]], "caption": "Table 1. Summary of Ir-Catalyzed Reactions (5% Catalyst) in Sealed Reaction Vesselsa ", "pdf": {"Page": 5, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [71, 92, 405, 122], "ImageBB": [71, 133, 407, 380]}, "diagram_type": "single"}, {"id": 608, "width": 2816, "height": 456, "file_name": "acs.oprd.5b00370-Table-c5.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1645.5, 0.0, 441.5, 352.6], "category_id": 1}, {"id": 1, "bbox": [1346.63, 203.63, 84.0, 51.0], "category_id": 2}, {"id": 2, "bbox": [968.2, 301.2, 61.8, 61.6], "category_id": 3}, {"id": 3, "bbox": [1994.18, 303.31, 53.09, 59.46], "category_id": 3}, {"id": 4, "bbox": [1288.0, 78.0, 200.0, 110.0], "category_id": 2}, {"id": 5, "bbox": [2.0, 376.0, 2814.0, 74.0], "category_id": 4}, {"id": 6, "bbox": [722.0, 2.0, 437.0, 352.0], "category_id": 1}], "reactions": [{"reactants": [6], "conditions": [4, 1], "products": [0]}], "corefs": [[6, 2], [0, 3]], "caption": "Table 5. Batch Experiments for the Reduction of Thebaine Using p-Toluenesulfonyl Hydrazidea", "pdf": {"Page": 7, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 89, 624, 111], "ImageBB": [82, 116, 786, 230]}, "diagram_type": "single"}, {"id": 389, "width": 1356, "height": 2648, "file_name": "op500224x-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [465.0, 1207.0, 302.0, 308.0], "category_id": 1}, {"id": 1, "bbox": [166.71, 6.98, 42.59, 49.69], "category_id": 3}, {"id": 2, "bbox": [126.0, 1526.0, 186.0, 94.0], "category_id": 3}, {"id": 3, "bbox": [88.0, 718.0, 141.0, 47.0], "category_id": 3}, {"id": 4, "bbox": [415.0, 716.0, 144.0, 58.0], "category_id": 3}, {"id": 5, "bbox": [764.0, 710.0, 139.0, 103.0], "category_id": 3}, {"id": 6, "bbox": [1091.0, 718.0, 167.0, 98.0], "category_id": 3}, {"id": 7, "bbox": [797.0, 1124.0, 181.0, 87.6], "category_id": 3}, {"id": 8, "bbox": [1125.0, 1120.15, 160.0, 89.0], "category_id": 3}, {"id": 9, "bbox": [401.0, 1124.0, 177.0, 86.0], "category_id": 3}, {"id": 10, "bbox": [57.0, 1124.0, 175.0, 105.0], "category_id": 3}, {"id": 11, "bbox": [994.0, 2395.0, 142.0, 83.7], "category_id": 3}, {"id": 12, "bbox": [573.0, 2392.0, 152.0, 90.6], "category_id": 3}, {"id": 13, "bbox": [115.0, 2384.0, 169.0, 98.7], "category_id": 3}, {"id": 14, "bbox": [323.0, 1959.0, 165.8, 83.0], "category_id": 3}, {"id": 15, "bbox": [828.0, 1954.0, 177.0, 88.0], "category_id": 3}, {"id": 16, "bbox": [925.0, 1529.0, 169.0, 87.6], "category_id": 3}, {"id": 17, "bbox": [63.0, 27.0, 210.0, 158.0], "category_id": 1}, {"id": 18, "bbox": [2.0, 130.0, 285.0, 225.0], "category_id": 1}, {"id": 19, "bbox": [528.0, 16.0, 305.0, 314.0], "category_id": 1}, {"id": 20, "bbox": [1066.0, 27.0, 290.0, 300.0], "category_id": 1}, {"id": 21, "bbox": [290.0, 116.0, 202.0, 61.0], "category_id": 2}, {"id": 22, "bbox": [290.0, 210.0, 216.0, 98.0], "category_id": 2}, {"id": 23, "bbox": [839.0, 111.0, 227.0, 58.0], "category_id": 2}, {"id": 24, "bbox": [856.0, 210.0, 179.0, 142.0], "category_id": 2}, {"id": 25, "bbox": [1163.0, 366.0, 56.0, 61.0], "category_id": 3}, {"id": 26, "bbox": [639.0, 366.0, 56.0, 44.0], "category_id": 3}, {"id": 27, "bbox": [107.0, 363.0, 39.0, 56.0], "category_id": 3}, {"id": 28, "bbox": [13.0, 469.0, 285.0, 216.0], "category_id": 1}, {"id": 29, "bbox": [323.0, 471.0, 325.0, 225.0], "category_id": 1}, {"id": 30, "bbox": [678.0, 457.0, 302.0, 248.0], "category_id": 1}, {"id": 31, "bbox": [1011.0, 441.0, 322.0, 291.0], "category_id": 1}, {"id": 32, "bbox": [1052.0, 829.0, 304.0, 267.0], "category_id": 1}, {"id": 33, "bbox": [703.0, 821.0, 366.0, 294.0], "category_id": 1}, {"id": 34, "bbox": [287.0, 816.0, 424.0, 283.0], "category_id": 1}, {"id": 35, "bbox": [2.0, 816.0, 296.0, 283.0], "category_id": 1}, {"id": 36, "bbox": [71.0, 1232.0, 288.0, 266.0], "category_id": 1}, {"id": 37, "bbox": [853.0, 1212.0, 410.0, 286.0], "category_id": 1}, {"id": 38, "bbox": [246.0, 1632.0, 291.0, 316.0], "category_id": 1}, {"id": 39, "bbox": [709.0, 1601.0, 385.0, 353.0], "category_id": 1}, {"id": 40, "bbox": [4.0, 2078.0, 364.0, 317.0], "category_id": 1}, {"id": 41, "bbox": [434.0, 2059.0, 397.0, 325.0], "category_id": 1}, {"id": 42, "bbox": [903.0, 2029.0, 438.0, 405.0], "category_id": 1}, {"id": 43, "bbox": [9.0, 2498.0, 1347.0, 150.0], "category_id": 2}, {"id": 44, "bbox": [517.0, 1526.1, 183.0, 96.0], "category_id": 3}], "reactions": [{"reactants": [17, 18], "conditions": [21, 22], "products": [19]}, {"reactants": [19], "conditions": [23, 24], "products": [20]}], "corefs": [[17, 1], [18, 27], [19, 26], [20, 25], [28, 3], [29, 4], [30, 5], [31, 6], [35, 10], [34, 9], [33, 7], [32, 8], [36, 2], [0, 44], [37, 16], [38, 14], [39, 15], [40, 13], [41, 12], [42, 11]], "caption": "Table 1. Rh-catalyzed cyclization with kinetic protonation and reduction ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 95, 775, 125], "ImageBB": [448, 131, 787, 793]}, "diagram_type": "single"}, {"id": 318, "width": 1324, "height": 924, "file_name": "ol3023177-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [891.0, 2.0, 259.0, 185.0], "category_id": 1}, {"id": 1, "bbox": [496.0, 46.0, 185.0, 105.0], "category_id": 1}, {"id": 2, "bbox": [156.0, 39.0, 241.0, 108.0], "category_id": 1}, {"id": 3, "bbox": [1140.0, 129.0, 29.0, 38.0], "category_id": 3}, {"id": 4, "bbox": [610.0, 136.0, 53.0, 49.0], "category_id": 3}, {"id": 5, "bbox": [271.0, 143.0, 34.0, 41.0], "category_id": 3}, {"id": 6, "bbox": [7.0, 255.0, 1303.0, 665.0], "category_id": 4}], "reactions": [{"reactants": [2, 1], "conditions": [], "products": [0]}], "corefs": [[2, 5], [1, 4], [0, 3]], "caption": "Table 3. Scope of H-Bonding Directed Hydroaminationa", "pdf": {"Page": 4, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [71, 85, 374, 101], "ImageBB": [74, 112, 405, 343]}, "diagram_type": "single"}, {"id": 996, "width": 1352, "height": 1344, "file_name": "ja402810t-Scheme-c5.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1002.33, 989.57, 244.84, 238.76], "category_id": 1}, {"id": 1, "bbox": [428.8, 554.64, 728.41, 380.82], "category_id": 1}, {"id": 2, "bbox": [4.06, 0.0, 625.54, 529.9], "category_id": 1}, {"id": 3, "bbox": [116.33, 1292.59, 267.83, 46.67], "category_id": 2}, {"id": 4, "bbox": [723.68, 0.0, 628.32, 526.24], "category_id": 1}, {"id": 5, "bbox": [85.89, 577.64, 269.86, 182.63], "category_id": 1}, {"id": 6, "bbox": [683.1, 989.57, 233.34, 238.76], "category_id": 1}, {"id": 7, "bbox": [0.0, 896.9, 495.08, 395.69], "category_id": 1}], "caption": "Scheme 5", "pdf": {"Page": 8, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 138, 110], "ImageBB": [82, 116, 420, 452]}, "reactions": [{"reactants": [2], "conditions": [], "products": [4]}, {"reactants": [4], "conditions": [5], "products": [1]}, {"reactants": [1], "conditions": [], "products": [7, 6, 0]}, {"reactants": [6], "conditions": [], "products": [0]}, {"reactants": [0], "conditions": [], "products": [6]}], "diagram_type": "multiple"}, {"id": 1268, "width": 1356, "height": 1856, "file_name": "op060114g-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [593.22, 0.0, 279.44, 425.24], "category_id": 1}, {"id": 1, "bbox": [1068.55, 1121.58, 158.75, 56.64], "category_id": 3}, {"id": 2, "bbox": [8.36, 1132.73, 162.46, 51.99], "category_id": 3}, {"id": 3, "bbox": [444.69, 1558.89, 376.91, 57.57], "category_id": 2}, {"id": 4, "bbox": [910.72, 626.71, 219.1, 52.93], "category_id": 2}, {"id": 5, "bbox": [1003.56, 415.95, 200.53, 56.64], "category_id": 3}, {"id": 6, "bbox": [964.57, 1371.34, 280.37, 417.81], "category_id": 1}, {"id": 7, "bbox": [1036.98, 0.0, 282.22, 415.95], "category_id": 1}, {"id": 8, "bbox": [433.55, 990.67, 265.51, 60.35], "category_id": 2}, {"id": 9, "bbox": [910.72, 1792.86, 293.37, 63.14], "category_id": 3}, {"id": 10, "bbox": [570.94, 415.95, 167.11, 53.85], "category_id": 3}, {"id": 11, "bbox": [318.43, 204.26, 239.52, 56.64], "category_id": 2}, {"id": 12, "bbox": [38.99, 718.63, 273.87, 417.81], "category_id": 1}, {"id": 13, "bbox": [803.03, 522.73, 333.29, 91.91], "category_id": 2}, {"id": 14, "bbox": [105.83, 1252.5, 278.51, 53.85], "category_id": 2}, {"id": 15, "bbox": [0.0, 346.32, 180.1, 48.28], "category_id": 2}, {"id": 16, "bbox": [38.99, 42.71, 262.73, 225.62], "category_id": 1}, {"id": 17, "bbox": [1073.19, 697.28, 282.81, 423.38], "category_id": 1}, {"id": 18, "bbox": [433.55, 841.19, 477.17, 107.7], "category_id": 2}, {"id": 19, "bbox": [440.04, 1456.76, 303.58, 64.99], "category_id": 2}, {"id": 20, "bbox": [38.99, 1371.34, 273.87, 422.45], "category_id": 1}, {"id": 21, "bbox": [0.0, 1805.86, 202.38, 50.14], "category_id": 3}, {"id": 22, "bbox": [318.43, 105.84, 234.87, 70.57], "category_id": 2}, {"id": 23, "bbox": [55.0, 290.61, 63.83, 59.42], "category_id": 3}], "caption": "Scheme 1", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 357, 135, 371], "ImageBB": [73, 375, 412, 839]}, "reactions": [{"reactants": [16], "conditions": [22, 11], "products": [0, 7]}, {"reactants": [0], "conditions": [13, 4], "products": [17]}, {"reactants": [17], "conditions": [18, 2], "products": [12]}, {"reactants": [12], "conditions": [14], "products": [20]}, {"reactants": [20], "conditions": [19, 3], "products": [6]}], "diagram_type": "tree"}, {"id": 585, "width": 1352, "height": 460, "file_name": "acs.oprd.6b00180-Table-c9.png", "license": 0, "bboxes": [{"id": 0, "bbox": [131.0, 196.0, 35.0, 44.0], "category_id": 3}, {"id": 1, "bbox": [10.0, 258.0, 1340.0, 202.0], "category_id": 4}, {"id": 2, "bbox": [654.0, 84.0, 286.0, 42.0], "category_id": 2}, {"id": 3, "bbox": [695.0, 149.0, 201.0, 42.0], "category_id": 2}, {"id": 4, "bbox": [1013.4, 3.9, 333.5, 192.2], "category_id": 1}, {"id": 5, "bbox": [0.9, 59.3, 265.1, 129.8], "category_id": 1}, {"id": 6, "bbox": [362.0, 76.2, 249.0, 124.8], "category_id": 1}, {"id": 7, "bbox": [1220.0, 192.94, 30.0, 43.0], "category_id": 3}], "reactions": [{"reactants": [5, 6], "conditions": [2, 3], "products": [4]}], "corefs": [[5, 0], [4, 7]], "caption": "Table 9. Suzuki Reaction of 4-Amino-2-bromopyridine (3) and PhB(OH)2 in H2O ", "pdf": {"Page": 6, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 649, 412, 679], "ImageBB": [82, 685, 420, 800]}, "diagram_type": "single"}, {"id": 931, "width": 2820, "height": 772, "file_name": "acs.oprd.5b00209-Scheme-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [873.23, 18.34, 256.74, 150.91], "category_id": 2}, {"id": 1, "bbox": [423.21, 452.74, 268.04, 110.01], "category_id": 2}, {"id": 2, "bbox": [969.15, 191.81, 105.81, 53.6], "category_id": 2}, {"id": 3, "bbox": [1721.06, 678.4, 125.55, 52.19], "category_id": 3}, {"id": 4, "bbox": [602.37, 307.47, 64.89, 49.36], "category_id": 3}, {"id": 5, "bbox": [1967.93, 76.16, 424.63, 187.58], "category_id": 1}, {"id": 6, "bbox": [730.75, 471.07, 479.64, 196.05], "category_id": 1}, {"id": 7, "bbox": [918.37, 681.22, 63.48, 49.37], "category_id": 3}, {"id": 8, "bbox": [1388.13, 307.47, 66.31, 46.54], "category_id": 3}, {"id": 9, "bbox": [1227.31, 67.7, 389.36, 210.15], "category_id": 1}, {"id": 10, "bbox": [1636.42, 0.0, 205.96, 163.61], "category_id": 2}, {"id": 11, "bbox": [427.44, 80.39, 420.39, 184.76], "category_id": 1}, {"id": 12, "bbox": [1227.31, 592.37, 289.2, 105.78], "category_id": 2}, {"id": 13, "bbox": [1719.65, 188.99, 117.09, 57.83], "category_id": 2}, {"id": 14, "bbox": [1232.96, 411.84, 225.71, 153.73], "category_id": 2}, {"id": 15, "bbox": [2154.15, 306.06, 55.01, 49.36], "category_id": 3}, {"id": 16, "bbox": [1548.95, 483.77, 475.41, 166.42], "category_id": 1}], "caption": "Scheme 4. Current Manufacturing Process of Amino-Diol Intermediate 4-HBr", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 438, 522, 453], "ImageBB": [82, 459, 787, 652]}, "reactions": [{"reactants": [11], "conditions": [0, 2], "products": [9]}, {"reactants": [9], "conditions": [10, 13], "products": [5]}, {"reactants": [5], "conditions": [1], "products": [6]}, {"reactants": [6], "conditions": [14, 12], "products": [16]}], "diagram_type": "multiple"}, {"id": 544, "width": 1348, "height": 408, "file_name": "acs.orglett.5b03590-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [798.0, 171.0, 174.0, 35.0], "category_id": 2}, {"id": 1, "bbox": [1085.0, 226.0, 50.0, 39.0], "category_id": 3}, {"id": 2, "bbox": [0.0, 289.0, 1341.0, 119.0], "category_id": 4}, {"id": 3, "bbox": [342.0, 170.0, 165.0, 38.0], "category_id": 2}, {"id": 4, "bbox": [803.0, 68.0, 162.0, 91.0], "category_id": 1}, {"id": 5, "bbox": [117.1, 12.1, 220.9, 203.9], "category_id": 1}, {"id": 6, "bbox": [630.0, 227.9, 50.0, 36.1], "category_id": 3}, {"id": 7, "bbox": [988.1, 6.0, 246.9, 220.0], "category_id": 1}, {"id": 8, "bbox": [344.0, 104.1, 164.9, 56.9], "category_id": 1}, {"id": 9, "bbox": [222.0, 226.0, 56.1, 41.1], "category_id": 3}, {"id": 10, "bbox": [534.2, 18.1, 249.8, 202.8], "category_id": 1}], "reactions": [{"reactants": [10], "conditions": [8, 3], "products": [5]}, {"reactants": [10], "conditions": [4, 0], "products": [7]}], "corefs": [[5, 9], [10, 6], [7, 1]], "caption": "Table 1. Cascades Forming Triazinonesa or Pyridazinones:b Optimization Using \u03b1-Ketocarbazone 1a ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 398, 416, 435], "ImageBB": [82, 440, 419, 542]}, "diagram_type": "single"}, {"id": 800, "width": 1416, "height": 916, "file_name": "jo501006u-Figure-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [114.0, 113.0, 179.5, 63.0], "category_id": 1}, {"id": 1, "bbox": [746.0, 155.0, 209.0, 54.0], "category_id": 2}, {"id": 2, "bbox": [846.27, 93.13, 260.57, 46.53], "category_id": 2}, {"id": 3, "bbox": [579.0, 35.0, 297.0, 57.5], "category_id": 2}, {"id": 4, "bbox": [1138.0, 122.0, 219.0, 53.0], "category_id": 1}, {"id": 5, "bbox": [583.03, 93.13, 255.26, 43.87], "category_id": 1}, {"id": 6, "bbox": [372.98, 113.07, 203.41, 63.81], "category_id": 1}], "reactions": [{"reactants": [0, 6], "conditions": [3, 5, 2, 1], "products": [4]}], "corefs": [], "caption": "Figure 4. Time-courses of the cross coupling reaction of n-NonCl with n-BuMgCl with 5 mol % of CuCl2 and 300 mol % (\u25c6), 100 mol % (\u25a0), 50 mol % (\u25b2), 10 mol % (\u25cf), or 5 mol % (\u25c7) of phenylpropyne. ", "pdf": {"Page": 5, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 613, 784, 669], "ImageBB": [433, 375, 787, 604]}, "diagram_type": "single"}, {"id": 4, "width": 1356, "height": 788, "file_name": "jacs.5b12989-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [678.07, 211.47, 38.6, 31.49], "category_id": 3}, {"id": 1, "bbox": [5.98, 266.48, 1340.08, 452.33], "category_id": 4}, {"id": 2, "bbox": [590.63, 12.18, 182.98, 174.86], "category_id": 1}, {"id": 3, "bbox": [205.27, 17.27, 187.05, 170.78], "category_id": 1}, {"id": 4, "bbox": [788.9, 38.62, 101.64, 59.96], "category_id": 2}, {"id": 5, "bbox": [965.82, 12.18, 180.98, 174.86], "category_id": 1}, {"id": 6, "bbox": [398.46, 113.86, 150.45, 68.19], "category_id": 2}, {"id": 7, "bbox": [400.49, 68.11, 158.58, 31.48], "category_id": 2}, {"id": 8, "bbox": [790.93, 109.79, 134.18, 31.49], "category_id": 2}, {"id": 9, "bbox": [285.59, 211.47, 35.56, 31.49], "category_id": 3}, {"id": 10, "bbox": [1054.28, 211.47, 49.78, 31.49], "category_id": 3}], "reactions": [{"reactants": [3], "conditions": [7, 6], "products": [2]}, {"reactants": [2], "conditions": [4, 8], "products": [5]}], "corefs": [[3, 9], [2, 0], [5, 10]], "caption": "Table 1. Boron Reagent Variation", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 799, 636, 814], "ImageBB": [448, 820, 787, 1017]}, "diagram_type": "single"}, {"id": 777, "width": 1348, "height": 1084, "file_name": "jo951899j-Table-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [873.0, 347.0, 140.6, 46.7], "category_id": 3}, {"id": 1, "bbox": [264.37, 426.95, 251.8, 207.3], "category_id": 3}, {"id": 2, "bbox": [2.0, 691.0, 1344.0, 393.0], "category_id": 4}, {"id": 3, "bbox": [482.0, 1.0, 212.5, 165.0], "category_id": 2}, {"id": 4, "bbox": [772.3, 34.8, 429.7, 292.8], "category_id": 1}, {"id": 5, "bbox": [146.8, 152.2, 396.1, 237.6], "category_id": 1}, {"id": 6, "bbox": [175.0, 373.0, 85.4, 50.0], "category_id": 3}, {"id": 7, "bbox": [298.91, 55.25, 118.0, 46.2], "category_id": 3}, {"id": 8, "bbox": [493.0, 191.0, 151.6, 47.6], "category_id": 2}], "reactions": [{"reactants": [7, 5], "conditions": [3, 8], "products": [4]}], "corefs": [[5, 6], [5, 1], [4, 0]], "caption": "Table 4. Synthesis of the Saccharide Amino Acid                Conjugates 11a-f ", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [85, 594, 375, 619], "ImageBB": [63, 628, 400, 899]}, "diagram_type": "single"}, {"id": 338, "width": 1348, "height": 1200, "file_name": "ol203001w-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [229.0, 364.0, 122.9, 57.4], "category_id": 3}, {"id": 1, "bbox": [1.0, 436.8, 1347.0, 763.2], "category_id": 4}, {"id": 2, "bbox": [860.5, 6.5, 371.5, 308.8], "category_id": 1}, {"id": 3, "bbox": [1052.91, 332.91, 80.0, 53.0], "category_id": 3}, {"id": 4, "bbox": [116.6, 2.0, 338.4, 359.1], "category_id": 1}, {"id": 5, "bbox": [521.0, 235.0, 268.0, 66.0], "category_id": 2}, {"id": 6, "bbox": [463.0, 102.0, 387.0, 106.0], "category_id": 2}], "reactions": [{"reactants": [4], "conditions": [6, 5], "products": [2]}], "corefs": [[4, 0], [2, 3]], "caption": "Table 1. Optimization of the Reaction Conditions", "pdf": {"Page": 2, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 280, 703, 293], "ImageBB": [436, 305, 773, 605]}, "diagram_type": "single"}, {"id": 1176, "width": 1348, "height": 3324, "file_name": "ol202528k-Scheme-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [265.85, 688.41, 485.05, 143.01], "category_id": 2}, {"id": 1, "bbox": [61.48, 79.82, 322.34, 154.64], "category_id": 1}, {"id": 2, "bbox": [222.65, 1060.89, 146.21, 58.2], "category_id": 3}, {"id": 3, "bbox": [867.32, 475.57, 390.46, 151.32], "category_id": 1}, {"id": 4, "bbox": [1010.21, 606.93, 43.2, 43.24], "category_id": 3}, {"id": 5, "bbox": [1010.21, 1060.89, 126.28, 54.87], "category_id": 3}, {"id": 6, "bbox": [86.4, 863.01, 425.35, 186.24], "category_id": 1}, {"id": 7, "bbox": [513.41, 987.72, 189.42, 138.02], "category_id": 2}, {"id": 8, "bbox": [1025.17, 264.39, 216.0, 204.53], "category_id": 2}, {"id": 9, "bbox": [86.4, 437.32, 400.43, 181.25], "category_id": 1}, {"id": 10, "bbox": [220.98, 626.89, 136.25, 49.88], "category_id": 3}, {"id": 11, "bbox": [792.55, 866.34, 490.16, 186.23], "category_id": 1}, {"id": 12, "bbox": [1010.21, 216.17, 136.25, 48.22], "category_id": 3}, {"id": 13, "bbox": [706.15, 41.57, 571.57, 166.28], "category_id": 1}, {"id": 14, "bbox": [384.3, 188.67, 39.07, 41.86], "category_id": 2}, {"id": 15, "bbox": [524.0, 901.1, 81.76, 41.28], "category_id": 2}, {"id": 16, "bbox": [616.66, 897.21, 140.2, 49.07], "category_id": 1}, {"id": 17, "bbox": [383.82, 0.0, 352.24, 162.96], "category_id": 2}, {"id": 18, "bbox": [513.41, 581.99, 343.94, 91.46], "category_id": 2}, {"id": 19, "bbox": [0.0, 1218.86, 1348.0, 1227.17], "category_id": 2}, {"id": 20, "bbox": [598.15, 259.4, 146.22, 94.78], "category_id": 2}, {"id": 21, "bbox": [202.71, 226.15, 43.2, 48.22], "category_id": 3}, {"id": 22, "bbox": [422.9, 189.56, 225.1, 269.38], "category_id": 1}, {"id": 23, "bbox": [524.3, 851.37, 216.0, 43.93], "category_id": 1}, {"id": 24, "bbox": [513.41, 463.93, 345.6, 84.8], "category_id": 2}], "caption": "Scheme 2", "pdf": {"Page": 2, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 205, 488, 218], "ImageBB": [436, 229, 773, 1060]}, "reactions": [{"reactants": [1, 22], "conditions": [17, 20], "products": [13]}, {"reactants": [13], "conditions": [8], "products": [3]}, {"reactants": [3], "conditions": [24, 18], "products": [9]}, {"reactants": [9], "conditions": [0], "products": [6]}, {"reactants": [6], "conditions": [23, 15, 16, 7], "products": [11]}], "diagram_type": "tree"}, {"id": 1285, "width": 1344, "height": 1160, "file_name": "op200019k-Scheme-c9.png", "license": 0, "bboxes": [{"id": 0, "bbox": [748.31, 149.19, 207.08, 49.74], "category_id": 2}, {"id": 1, "bbox": [342.22, 487.91, 174.81, 52.42], "category_id": 2}, {"id": 2, "bbox": [302.55, 286.29, 298.52, 89.38], "category_id": 2}, {"id": 3, "bbox": [553.33, 16.13, 197.0, 145.83], "category_id": 1}, {"id": 4, "bbox": [996.4, 10.75, 193.64, 189.52], "category_id": 1}, {"id": 5, "bbox": [601.07, 742.61, 77.32, 77.29], "category_id": 2}, {"id": 6, "bbox": [841.09, 946.24, 193.64, 47.72], "category_id": 2}, {"id": 7, "bbox": [601.07, 643.15, 149.93, 77.29], "category_id": 3}, {"id": 8, "bbox": [323.39, 567.21, 227.93, 79.3], "category_id": 2}, {"id": 9, "bbox": [1019.26, 430.11, 170.78, 194.89], "category_id": 1}, {"id": 10, "bbox": [564.76, 438.18, 185.57, 197.58], "category_id": 1}, {"id": 11, "bbox": [1106.67, 188.85, 46.39, 39.65], "category_id": 3}, {"id": 12, "bbox": [748.31, 50.4, 172.79, 53.77], "category_id": 2}, {"id": 13, "bbox": [778.57, 577.29, 209.76, 45.7], "category_id": 2}, {"id": 14, "bbox": [996.4, 262.1, 233.98, 81.32], "category_id": 2}, {"id": 15, "bbox": [875.38, 879.04, 80.01, 45.03], "category_id": 2}, {"id": 16, "bbox": [612.5, 1035.63, 153.96, 77.28], "category_id": 3}, {"id": 17, "bbox": [114.97, 439.52, 193.63, 195.56], "category_id": 1}, {"id": 18, "bbox": [698.56, 742.61, 132.45, 79.98], "category_id": 2}, {"id": 19, "bbox": [1020.61, 643.15, 159.34, 79.3], "category_id": 3}, {"id": 20, "bbox": [837.73, 477.83, 77.32, 43.01], "category_id": 2}, {"id": 21, "bbox": [613.5, 192.21, 146.5, 73.09], "category_id": 3}, {"id": 22, "bbox": [303.22, 136.43, 268.94, 83.33], "category_id": 2}, {"id": 23, "bbox": [581.5, 842.08, 166.81, 190.86], "category_id": 1}, {"id": 24, "bbox": [126.3, 197.58, 152.8, 75.82], "category_id": 3}, {"id": 25, "bbox": [323.39, 50.4, 219.86, 53.77], "category_id": 2}, {"id": 26, "bbox": [121.69, 74.6, 196.33, 78.63], "category_id": 1}, {"id": 27, "bbox": [224.56, 640.46, 57.15, 43.68], "category_id": 3}], "caption": "Scheme 9. HF and HCl addition to cyclopropanolactone 34", "pdf": {"Page": 5, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [437, 92, 771, 107], "ImageBB": [437, 117, 773, 407]}, "reactions": [{"reactants": [26], "conditions": [25, 22], "products": [3]}, {"reactants": [3], "conditions": [12, 0], "products": [4]}, {"reactants": [4], "conditions": [14], "products": [9]}, {"reactants": [3], "conditions": [2], "products": [17]}, {"reactants": [17], "conditions": [1, 8], "products": [10]}, {"reactants": [10], "conditions": [5, 18], "products": [23]}, {"reactants": [23], "conditions": [15, 6], "products": [9]}], "diagram_type": "graph"}, {"id": 438, "width": 2820, "height": 1168, "file_name": "op200351g-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1868.0, 121.0, 667.0, 328.6], "category_id": 1}, {"id": 1, "bbox": [1660.91, 279.83, 178.64, 68.05], "category_id": 2}, {"id": 2, "bbox": [1144.12, 271.32, 153.12, 59.55], "category_id": 2}, {"id": 3, "bbox": [1641.0, 167.0, 231.0, 60.7], "category_id": 2}, {"id": 4, "bbox": [603.0, 288.0, 121.0, 39.0], "category_id": 2}, {"id": 5, "bbox": [822.0, 39.0, 254.0, 391.0], "category_id": 1}, {"id": 6, "bbox": [1354.0, 16.0, 268.0, 406.0], "category_id": 1}, {"id": 7, "bbox": [245.0, 579.0, 2266.0, 452.0], "category_id": 4}, {"id": 8, "bbox": [13.0, 1065.0, 643.0, 79.0], "category_id": 2}, {"id": 9, "bbox": [343.0, 14.1, 243.5, 394.9], "category_id": 1}, {"id": 10, "bbox": [560.0, 189.62, 212.0, 49.58], "category_id": 2}, {"id": 11, "bbox": [1113.0, 177.0, 214.7, 52.4], "category_id": 2}, {"id": 12, "bbox": [1382.0, 424.0, 195.0, 105.0], "category_id": 3}, {"id": 13, "bbox": [337.0, 428.0, 180.0, 95.0], "category_id": 3}, {"id": 14, "bbox": [856.0, 431.0, 186.0, 93.0], "category_id": 3}, {"id": 15, "bbox": [2072.0, 416.0, 186.0, 116.0], "category_id": 3}], "reactions": [{"reactants": [9], "conditions": [10, 4], "products": [5]}, {"reactants": [5], "conditions": [11, 2], "products": [6]}, {"reactants": [6], "conditions": [3, 1], "products": [0]}], "corefs": [[9, 13], [5, 14], [6, 12], [0, 15]], "caption": "Table 1. Scale-up results for the synthesis of ketoamides 11 and 1", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 455, 110], "ImageBB": [82, 116, 787, 408]}, "diagram_type": "single"}, {"id": 985, "width": 1356, "height": 692, "file_name": "ja200818w-Scheme-c8.png", "license": 0, "bboxes": [{"id": 0, "bbox": [4.07, 2.71, 282.19, 245.66], "category_id": 1}, {"id": 1, "bbox": [873.02, 394.95, 160.77, 55.64], "category_id": 2}, {"id": 2, "bbox": [38.67, 255.83, 167.55, 45.47], "category_id": 3}, {"id": 3, "bbox": [1029.04, 67.86, 281.51, 199.51], "category_id": 1}, {"id": 4, "bbox": [634.25, 163.54, 352.06, 54.29], "category_id": 2}, {"id": 5, "bbox": [202.15, 367.8, 224.53, 91.61], "category_id": 2}, {"id": 6, "bbox": [490.44, 350.84, 280.83, 197.47], "category_id": 1}, {"id": 7, "bbox": [984.27, 265.33, 367.66, 50.22], "category_id": 3}, {"id": 8, "bbox": [450.42, 561.2, 368.34, 82.79], "category_id": 3}, {"id": 9, "bbox": [294.4, 38.68, 322.21, 133.01], "category_id": 2}, {"id": 10, "bbox": [322.21, 199.51, 264.55, 50.89], "category_id": 2}], "caption": "Scheme 8. CO-Release and Regeneration of 25 and *25", "pdf": {"Page": 6, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [437, 474, 746, 489], "ImageBB": [436, 499, 775, 672]}, "reactions": [{"reactants": [0], "conditions": [9, 10], "products": [4, 3]}, {"reactants": [3], "conditions": [1], "products": [6]}, {"reactants": [6], "conditions": [5], "products": [0]}], "diagram_type": "graph"}, {"id": 1167, "width": 1328, "height": 692, "file_name": "ol0701619-Scheme-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1023.74, 302.1, 28.56, 35.85], "category_id": 2}, {"id": 1, "bbox": [412.9, 302.76, 28.88, 35.19], "category_id": 2}, {"id": 2, "bbox": [896.18, 490.66, 35.21, 41.17], "category_id": 2}, {"id": 3, "bbox": [673.63, 297.45, 25.91, 37.18], "category_id": 2}, {"id": 4, "bbox": [924.75, 64.4, 31.22, 33.2], "category_id": 2}, {"id": 5, "bbox": [95.66, 385.09, 251.12, 210.48], "category_id": 1}, {"id": 6, "bbox": [986.53, 8.63, 337.48, 264.26], "category_id": 1}, {"id": 7, "bbox": [832.41, 297.45, 30.56, 40.5], "category_id": 2}, {"id": 8, "bbox": [482.31, 455.47, 340.8, 233.05], "category_id": 1}, {"id": 9, "bbox": [1001.15, 422.94, 322.86, 262.26], "category_id": 1}, {"id": 10, "bbox": [2.66, 41.83, 338.14, 229.73], "category_id": 1}, {"id": 11, "bbox": [399.93, 53.78, 34.54, 33.86], "category_id": 2}, {"id": 12, "bbox": [496.92, 2.66, 335.49, 267.57], "category_id": 1}, {"id": 13, "bbox": [17.94, 474.06, 67.76, 48.47], "category_id": 2}], "caption": "Scheme 2. Proposed Mechanisms for the Dehydrogenation of                 Amino Acid Residuesa ", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [77, 365, 406, 392], "ImageBB": [76, 397, 408, 570]}, "reactions": [{"reactants": [12], "conditions": [11], "products": [10]}, {"reactants": [10], "conditions": [1], "products": [8]}, {"reactants": [12], "conditions": [3], "products": [8]}, {"reactants": [12], "conditions": [4], "products": [6]}, {"reactants": [12], "conditions": [7], "products": [9]}, {"reactants": [6], "conditions": [0], "products": [8]}, {"reactants": [9], "conditions": [2], "products": [8]}], "diagram_type": "graph"}, {"id": 833, "width": 1352, "height": 260, "file_name": "jo302439t-Figure-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [594.5, 214.9, 167.5, 40.1], "category_id": 2}, {"id": 1, "bbox": [503.6, 49.2, 346.9, 86.0], "category_id": 1}, {"id": 2, "bbox": [1078.9, 45.4, 270.1, 173.6], "category_id": 1}, {"id": 3, "bbox": [56.0, 218.0, 180.0, 37.0], "category_id": 2}, {"id": 4, "bbox": [1086.0, 222.0, 210.0, 32.0], "category_id": 2}, {"id": 5, "bbox": [0.0, 39.0, 281.0, 177.0], "category_id": 1}], "reactions": [{"reactants": [5], "conditions": [], "products": [1]}, {"reactants": [1], "conditions": [], "products": [2]}, {"reactants": [2], "conditions": [], "products": [1]}, {"reactants": [1], "conditions": [], "products": [5]}], "corefs": [], "caption": "Figure 4. Compound 5 at 0.4 M concentration in THF-d8 solution. 13   C NMR line shapes for C2 and C3 (left) observed at di\ufb00erent temperatures, K, and (right) calculated to \ufb01t with \ufb01rst-order rate constants. ", "pdf": {"Page": 4, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 566, 417, 623], "ImageBB": [82, 626, 420, 691]}, "diagram_type": "single"}, {"id": 341, "width": 1348, "height": 1448, "file_name": "ol202499g-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [649.0, 13.6, 276.2, 67.4], "category_id": 2}, {"id": 1, "bbox": [663.0, 122.0, 257.3, 55.0], "category_id": 2}, {"id": 2, "bbox": [45.5, 12.6, 193.9, 141.6], "category_id": 1}, {"id": 3, "bbox": [78.1, 240.8, 1153.7, 118.3], "category_id": 4}, {"id": 4, "bbox": [456.0, 175.0, 64.0, 50.0], "category_id": 3}, {"id": 5, "bbox": [6.0, 421.0, 1342.0, 1027.0], "category_id": 4}, {"id": 6, "bbox": [113.0, 171.0, 38.0, 56.0], "category_id": 3}, {"id": 7, "bbox": [1133.0, 191.0, 47.0, 47.0], "category_id": 3}, {"id": 8, "bbox": [296.0, 0.0, 300.0, 184.0], "category_id": 1}, {"id": 9, "bbox": [960.0, 1.0, 342.0, 190.0], "category_id": 1}], "reactions": [{"reactants": [2, 8], "conditions": [0, 1], "products": [9]}], "corefs": [[2, 6], [8, 4], [9, 7]], "caption": "Table 1. Direct Allylic Alkylation of O-Protected Cyanohydrins with MBH Adducts 2a ", "pdf": {"Page": 3, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [71, 87, 405, 114], "ImageBB": [71, 126, 408, 488]}, "diagram_type": "single"}, {"id": 485, "width": 1352, "height": 1092, "file_name": "ol061289d-Figure-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [775.0, 783.0, 225.0, 46.0], "category_id": 2}, {"id": 1, "bbox": [1142.0, 1059.0, 16.0, 16.0], "category_id": 4}, {"id": 2, "bbox": [898.0, 458.0, 43.0, 40.0], "category_id": 3}, {"id": 3, "bbox": [493.0, 823.0, 32.0, 40.0], "category_id": 3}, {"id": 4, "bbox": [340.0, 567.0, 37.0, 40.0], "category_id": 3}, {"id": 5, "bbox": [669.81, 136.0, 458.49, 312.07], "category_id": 1}, {"id": 6, "bbox": [213.0, 210.07, 387.0, 171.0], "category_id": 1}, {"id": 7, "bbox": [244.9, 529.0, 831.1, 563.0], "category_id": 4}, {"id": 8, "bbox": [362.0, 458.0, 50.0, 38.0], "category_id": 3}, {"id": 9, "bbox": [769.54, 590.61, 249.0, 43.0], "category_id": 2}], "reactions": [{"reactants": [6], "conditions": [], "products": [5]}], "corefs": [[6, 8], [5, 2]], "caption": "Figure 2. HPLC chromatographs for the reaction of 4 with bromoacetylated Val-OMe. HPLC conditions: Kromasil C18, 0-65% B in A over 30 min, A ) H2O + 0.1% TFA, B ) CH3CN + 0.08% TFA. ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 337, 775, 392], "ImageBB": [439, 52, 777, 325]}, "diagram_type": "single"}, {"id": 1363, "width": 1704, "height": 364, "file_name": "op9002642-Scheme-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [0.0, 23.85, 185.83, 264.87], "category_id": 1}, {"id": 1, "bbox": [770.59, 24.7, 192.65, 267.42], "category_id": 1}, {"id": 2, "bbox": [864.36, 314.27, 33.24, 42.58], "category_id": 3}, {"id": 3, "bbox": [110.82, 315.12, 40.06, 41.73], "category_id": 3}, {"id": 4, "bbox": [381.89, 24.7, 193.5, 267.42], "category_id": 1}, {"id": 5, "bbox": [1526.7, 312.56, 146.61, 40.89], "category_id": 3}, {"id": 6, "bbox": [1489.19, 23.0, 194.35, 269.12], "category_id": 1}, {"id": 7, "bbox": [1166.97, 20.44, 191.8, 266.57], "category_id": 1}, {"id": 8, "bbox": [479.06, 314.27, 35.81, 42.58], "category_id": 3}, {"id": 9, "bbox": [1219.82, 310.01, 108.26, 46.84], "category_id": 3}], "caption": "Scheme 2. Proposed Intermediates Detected During Reduction of 2 to 3", "pdf": {"Page": 3, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 46, 456, 60], "ImageBB": [197, 65, 623, 156]}, "reactions": [{"reactants": [0], "conditions": [], "products": [4]}, {"reactants": [4], "conditions": [], "products": [1]}, {"reactants": [1], "conditions": [], "products": [7, 6]}], "diagram_type": "single"}, {"id": 30, "width": 1288, "height": 764, "file_name": "ja806814c-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [108.64, 5.92, 141.98, 147.89], "category_id": 1}, {"id": 1, "bbox": [598.58, 19.72, 141.99, 107.48], "category_id": 1}, {"id": 2, "bbox": [1113.17, 70.98, 67.07, 29.6], "category_id": 2}, {"id": 3, "bbox": [376.78, 38.45, 70.02, 33.54], "category_id": 2}, {"id": 4, "bbox": [316.64, 93.65, 190.29, 34.53], "category_id": 2}, {"id": 5, "bbox": [903.2, 37.46, 53.26, 34.53], "category_id": 2}, {"id": 6, "bbox": [830.25, 93.65, 193.24, 34.53], "category_id": 2}, {"id": 7, "bbox": [7.1, 200.12, 1275.66, 558.98], "category_id": 4}], "reactions": [{"reactants": [0], "conditions": [3, 4], "products": [1]}, {"reactants": [1], "conditions": [5, 6], "products": [2]}], "corefs": [], "caption": "Table 1. TRF Reactions Studieda", "pdf": {"Page": 1, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [425, 423, 593, 437], "ImageBB": [432, 445, 754, 636]}, "diagram_type": "single"}, {"id": 1107, "width": 1776, "height": 1476, "file_name": "jo980755c-Scheme-c5.png", "license": 0, "bboxes": [{"id": 0, "bbox": [837.8, 57.74, 318.3, 76.39], "category_id": 1}, {"id": 1, "bbox": [0.0, 71.95, 359.82, 81.73], "category_id": 1}, {"id": 2, "bbox": [1163.86, 1153.91, 242.55, 73.73], "category_id": 1}, {"id": 3, "bbox": [1074.13, 315.35, 332.28, 67.51], "category_id": 2}, {"id": 4, "bbox": [801.16, 731.88, 595.36, 62.01], "category_id": 2}, {"id": 5, "bbox": [771.04, 1290.03, 223.26, 49.61], "category_id": 3}, {"id": 6, "bbox": [743.63, 1357.2, 309.18, 92.52], "category_id": 2}, {"id": 7, "bbox": [1163.86, 1298.7, 309.14, 124.37], "category_id": 2}, {"id": 8, "bbox": [419.35, 1278.28, 270.08, 56.85], "category_id": 3}, {"id": 9, "bbox": [390.92, 1358.0, 316.28, 115.7], "category_id": 2}, {"id": 10, "bbox": [422.9, 59.5, 190.13, 87.1], "category_id": 1}, {"id": 11, "bbox": [839.58, 190.99, 523.29, 59.51], "category_id": 3}, {"id": 12, "bbox": [640.57, 42.64, 103.06, 62.18], "category_id": 2}, {"id": 13, "bbox": [762.29, 533.87, 541.06, 192.77], "category_id": 1}, {"id": 14, "bbox": [455.77, 1103.28, 204.34, 154.57], "category_id": 1}, {"id": 15, "bbox": [1524.57, 1161.91, 163.47, 69.29], "category_id": 2}, {"id": 16, "bbox": [1491.7, 1353.78, 284.3, 64.85], "category_id": 2}, {"id": 17, "bbox": [747.18, 1115.72, 221.22, 150.12], "category_id": 1}, {"id": 18, "bbox": [1253.6, 0.0, 89.73, 183.88], "category_id": 1}], "caption": "Scheme 5. Proposed Mechanism for the Oxidation of Aromatic Alkenes by Oxoruthenium(IV)", "pdf": {"Page": 7, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [114, 64, 734, 78], "ImageBB": [203, 83, 647, 452]}, "reactions": [{"reactants": [1, 10], "conditions": [12], "products": [0, 18]}, {"reactants": [0, 18], "conditions": [3], "products": [13]}, {"reactants": [13], "conditions": [], "products": [14]}, {"reactants": [13], "conditions": [], "products": [17]}, {"reactants": [13], "conditions": [], "products": [2]}, {"reactants": [13], "conditions": [], "products": [15]}], "diagram_type": "tree"}, {"id": 103, "width": 2264, "height": 1024, "file_name": "ja012741l-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [16.0, 74.3, 1442.33, 840.6], "category_id": 1}, {"id": 1, "bbox": [310.68, 967.0, 240.74, 54.64], "category_id": 3}, {"id": 2, "bbox": [1872.94, 967.0, 385.87, 46.1], "category_id": 3}, {"id": 3, "bbox": [1389.77, 622.75, 76.54, 31.29], "category_id": 2}, {"id": 4, "bbox": [1355.16, 697.3, 169.73, 41.93], "category_id": 2}, {"id": 5, "bbox": [1861.0, 510.93, 393.36, 214.99], "category_id": 1}], "reactions": [{"reactants": [0], "conditions": [3, 4], "products": [5]}], "corefs": [[0, 1], [5, 2]], "caption": "Figure 1. Structure of bleomycin A2, and conversion to catabolite deamido BLM A2 via the action of bleomycin hydrolase.", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 331, 644, 344], "ImageBB": [142, 68, 708, 324]}, "diagram_type": "single"}, {"id": 201, "width": 784, "height": 428, "file_name": "op049889k-Figure-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [388.0, 6.0, 302.0, 231.0], "category_id": 1}, {"id": 1, "bbox": [479.0, 250.0, 42.0, 46.0], "category_id": 3}, {"id": 2, "bbox": [578.0, 180.0, 206.0, 177.0], "category_id": 1}, {"id": 3, "bbox": [3.0, 232.0, 39.0, 47.0], "category_id": 3}, {"id": 4, "bbox": [208.0, 152.0, 110.0, 59.0], "category_id": 2}, {"id": 5, "bbox": [679.0, 375.0, 37.0, 51.0], "category_id": 3}], "reactions": [{"reactants": [3], "conditions": [4], "products": [0, 2]}], "corefs": [[0, 1], [2, 5]], "caption": "Figure 3. [3+2] Cycloaddition strategy.", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 370, 297, 384], "ImageBB": [144, 258, 340, 365]}, "diagram_type": "single"}, {"id": 1127, "width": 1368, "height": 772, "file_name": "jo991524o-Scheme-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [207.36, 444.28, 345.59, 282.73], "category_id": 1}, {"id": 1, "bbox": [821.89, 47.92, 164.25, 67.09], "category_id": 2}, {"id": 2, "bbox": [639.18, 590.1, 148.5, 58.87], "category_id": 2}, {"id": 3, "bbox": [270.32, 55.45, 251.15, 61.61], "category_id": 2}, {"id": 4, "bbox": [113.6, 219.75, 49.96, 45.18], "category_id": 3}, {"id": 5, "bbox": [271.0, 151.97, 146.45, 62.3], "category_id": 2}, {"id": 6, "bbox": [638.49, 490.84, 256.63, 69.14], "category_id": 2}, {"id": 7, "bbox": [1119.58, 718.11, 55.44, 43.81], "category_id": 3}, {"id": 8, "bbox": [985.45, 442.23, 314.8, 237.55], "category_id": 1}, {"id": 9, "bbox": [646.7, 230.7, 60.91, 46.55], "category_id": 3}, {"id": 10, "bbox": [524.21, 8.9, 310.69, 221.8], "category_id": 1}, {"id": 11, "bbox": [358.6, 727.01, 54.74, 43.81], "category_id": 3}, {"id": 12, "bbox": [0.0, 8.9, 266.21, 219.75], "category_id": 1}, {"id": 13, "bbox": [982.72, 0.0, 311.37, 225.91], "category_id": 1}, {"id": 14, "bbox": [1169.5, 334.0, 64.4, 49.9], "category_id": 2}, {"id": 15, "bbox": [1102.48, 225.91, 60.22, 47.23], "category_id": 3}], "caption": "Scheme 4", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [573, 64, 636, 78], "ImageBB": [446, 84, 788, 277]}, "reactions": [{"reactants": [12], "conditions": [3, 5], "products": [10]}, {"reactants": [10], "conditions": [1], "products": [13]}, {"reactants": [0], "conditions": [6, 2], "products": [8]}], "diagram_type": "tree"}, {"id": 908, "width": 1356, "height": 940, "file_name": "acs.joc.5b00632-Figure-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [546.0, 752.0, 90.0, 49.0], "category_id": 2}, {"id": 1, "bbox": [786.0, 43.0, 434.0, 187.0], "category_id": 1}, {"id": 2, "bbox": [136.0, 43.0, 345.0, 188.0], "category_id": 1}, {"id": 3, "bbox": [162.0, 351.0, 418.0, 233.0], "category_id": 1}, {"id": 4, "bbox": [794.0, 344.0, 417.0, 197.0], "category_id": 1}, {"id": 5, "bbox": [166.0, 681.0, 332.0, 246.0], "category_id": 1}, {"id": 6, "bbox": [662.0, 690.0, 330.0, 246.0], "category_id": 1}, {"id": 7, "bbox": [599.0, 116.0, 93.0, 48.0], "category_id": 2}, {"id": 8, "bbox": [654.0, 416.0, 92.0, 47.0], "category_id": 2}, {"id": 9, "bbox": [1154.0, 780.0, 34.0, 47.0], "category_id": 3}, {"id": 10, "bbox": [860.2, 550.0, 347.8, 46.0], "category_id": 3}, {"id": 11, "bbox": [172.0, 243.0, 269.0, 92.0], "category_id": 3}], "reactions": [{"reactants": [2], "conditions": [7], "products": [1]}, {"reactants": [1], "conditions": [], "products": [4]}, {"reactants": [4], "conditions": [], "products": [1]}, {"reactants": [4], "conditions": [8], "products": [3]}, {"reactants": [3], "conditions": [], "products": [5]}, {"reactants": [5], "conditions": [0], "products": [6]}, {"reactants": [6], "conditions": [], "products": [9]}], "corefs": [[2, 11], [4, 10]], "caption": "Figure 2. Proposed clopidogrel bioactivation pathway.", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 869, 712, 883], "ImageBB": [448, 625, 787, 860]}, "diagram_type": "tree"}, {"id": 154, "width": 2816, "height": 1688, "file_name": "op700160a-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1409.0, 8.0, 293.0, 184.0], "category_id": 1}, {"id": 1, "bbox": [1799.0, 82.0, 176.0, 249.0], "category_id": 1}, {"id": 2, "bbox": [2061.0, 84.0, 178.0, 245.0], "category_id": 1}, {"id": 3, "bbox": [575.0, 157.0, 110.0, 121.0], "category_id": 1}, {"id": 4, "bbox": [9.0, 410.0, 2783.0, 1121.0], "category_id": 4}, {"id": 5, "bbox": [610.0, 349.0, 32.0, 35.0], "category_id": 3}, {"id": 6, "bbox": [959.0, 349.0, 28.0, 37.0], "category_id": 3}, {"id": 7, "bbox": [820.0, 137.0, 303.0, 165.0], "category_id": 1}, {"id": 8, "bbox": [1207.0, 171.0, 175.0, 48.0], "category_id": 2}, {"id": 9, "bbox": [1359.0, 256.0, 199.0, 39.0], "category_id": 2}, {"id": 10, "bbox": [1842.0, 345.0, 79.0, 49.0], "category_id": 3}, {"id": 11, "bbox": [2079.0, 344.0, 85.0, 50.0], "category_id": 3}, {"id": 12, "bbox": [1535.0, 190.0, 48.0, 33.0], "category_id": 3}], "reactions": [{"reactants": [3, 7], "conditions": [8, 0, 9], "products": [1, 2]}], "corefs": [[3, 5], [7, 6], [0, 12], [1, 10], [2, 11]], "caption": "Table 3. Use of scandium (III) catalyst and chiral ligand, 10, to directly access (\u2013)-1a", "pdf": {"Page": 5, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 530, 523, 544], "ImageBB": [58, 558, 762, 980]}, "diagram_type": "single"}, {"id": 512, "width": 1352, "height": 848, "file_name": "ol051365x-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [548.0, 299.0, 199.0, 53.0], "category_id": 2}, {"id": 1, "bbox": [473.0, 726.0, 385.0, 122.0], "category_id": 3}, {"id": 2, "bbox": [328.0, 366.0, 198.0, 36.0], "category_id": 2}, {"id": 3, "bbox": [333.0, 480.0, 602.0, 227.0], "category_id": 1}, {"id": 4, "bbox": [597.0, 405.0, 154.0, 51.0], "category_id": 2}, {"id": 5, "bbox": [824.0, 364.0, 174.0, 46.0], "category_id": 2}, {"id": 6, "bbox": [767.0, 141.4, 306.0, 203.6], "category_id": 1}, {"id": 7, "bbox": [285.0, 143.2, 323.8, 209.8], "category_id": 1}], "reactions": [{"reactants": [7], "conditions": [], "products": [6]}, {"reactants": [6], "conditions": [], "products": [7]}], "corefs": [[3, 1]], "caption": "Figure 1. Twisted \u03c0-electron system chromophores.", "pdf": {"Page": 1, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 887, 713, 900], "ImageBB": [439, 668, 777, 880]}, "diagram_type": "single"}, {"id": 947, "width": 1352, "height": 744, "file_name": "acs.orglett.5b02498-Scheme-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [864.36, 449.49, 343.58, 204.8], "category_id": 1}, {"id": 1, "bbox": [277.97, 0.0, 183.29, 137.21], "category_id": 1}, {"id": 2, "bbox": [502.52, 93.28, 248.89, 38.52], "category_id": 2}, {"id": 3, "bbox": [277.97, 220.35, 292.86, 157.49], "category_id": 1}, {"id": 4, "bbox": [60.19, 227.78, 177.88, 138.57], "category_id": 1}, {"id": 5, "bbox": [551.89, 233.87, 264.45, 73.67], "category_id": 2}, {"id": 6, "bbox": [567.45, 319.71, 247.54, 72.32], "category_id": 2}, {"id": 7, "bbox": [942.82, 667.81, 39.22, 30.41], "category_id": 3}, {"id": 8, "bbox": [588.41, 518.43, 259.04, 40.55], "category_id": 2}, {"id": 9, "bbox": [785.9, 2.7, 248.22, 133.84], "category_id": 1}, {"id": 10, "bbox": [502.52, 16.22, 261.74, 68.27], "category_id": 2}, {"id": 11, "bbox": [280.0, 488.69, 294.89, 157.49], "category_id": 1}, {"id": 12, "bbox": [61.55, 494.77, 179.9, 139.24], "category_id": 1}, {"id": 13, "bbox": [819.72, 180.47, 327.35, 222.38], "category_id": 1}, {"id": 14, "bbox": [926.58, 395.41, 73.72, 35.15], "category_id": 3}, {"id": 15, "bbox": [568.8, 574.53, 294.21, 102.74], "category_id": 2}, {"id": 16, "bbox": [968.63, 84.93, 109.1, 36.71], "category_id": 2}, {"id": 17, "bbox": [809.57, 181.8, 78.51, 36.7], "category_id": 2}, {"id": 18, "bbox": [1013.49, 207.29, 79.53, 35.68], "category_id": 2}, {"id": 19, "bbox": [1035.92, 248.07, 78.51, 33.65], "category_id": 2}], "caption": "Scheme 3. Control Experiments", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 262, 110], "ImageBB": [82, 116, 420, 302]}, "reactions": [{"reactants": [1], "conditions": [10, 2], "products": [9]}, {"reactants": [4, 3], "conditions": [5, 6], "products": [13]}, {"reactants": [12, 11], "conditions": [8, 15], "products": [0]}], "diagram_type": "multiple"}, {"id": 1168, "width": 1352, "height": 3784, "file_name": "ol070339r-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [767.08, 721.21, 286.0, 88.97], "category_id": 2}, {"id": 1, "bbox": [250.01, 295.3, 806.86, 461.88], "category_id": 1}, {"id": 2, "bbox": [659.12, 1162.27, 49.25, 51.11], "category_id": 3}, {"id": 3, "bbox": [659.12, 579.24, 49.25, 45.43], "category_id": 3}, {"id": 4, "bbox": [681.85, 1277.74, 270.85, 107.9], "category_id": 2}, {"id": 5, "bbox": [257.59, 760.96, 812.54, 520.56], "category_id": 1}, {"id": 6, "bbox": [511.39, 257.44, 49.24, 49.22], "category_id": 3}, {"id": 7, "bbox": [1045.51, 104.11, 43.56, 49.22], "category_id": 3}, {"id": 8, "bbox": [833.37, 194.97, 268.96, 104.12], "category_id": 2}, {"id": 9, "bbox": [234.86, 35.97, 492.45, 291.51], "category_id": 1}, {"id": 10, "bbox": [632.61, 1427.28, 113.64, 64.36], "category_id": 3}, {"id": 11, "bbox": [833.37, 0.0, 280.32, 191.19], "category_id": 1}, {"id": 12, "bbox": [767.08, 586.81, 198.88, 136.3], "category_id": 1}, {"id": 13, "bbox": [971.64, 630.35, 39.77, 51.11], "category_id": 3}], "caption": "Scheme 1. Synthesis of 1 and the Corresponding Eu(III)                      Complex ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [457, 75, 756, 102], "ImageBB": [439, 107, 777, 1053]}, "reactions": [{"reactants": [9, 11], "conditions": [8], "products": [1]}, {"reactants": [1, 12], "conditions": [0], "products": [5]}, {"reactants": [5], "conditions": [4], "products": [10]}], "diagram_type": "tree"}, {"id": 376, "width": 2816, "height": 1788, "file_name": "ol101406k-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [806.0, 154.2, 49.4, 45.8], "category_id": 3}, {"id": 1, "bbox": [1574.0, 8.0, 233.4, 134.6], "category_id": 1}, {"id": 2, "bbox": [948.0, 25.0, 209.6, 60.4], "category_id": 2}, {"id": 3, "bbox": [1911.2, 3.2, 161.8, 140.0], "category_id": 1}, {"id": 4, "bbox": [1271.8, 12.8, 215.8, 142.0], "category_id": 1}, {"id": 5, "bbox": [745.8, 16.0, 159.0, 137.2], "category_id": 1}, {"id": 6, "bbox": [0.0, 228.0, 2814.0, 1560.0], "category_id": 4}, {"id": 7, "bbox": [1323.2, 157.2, 59.8, 40.8], "category_id": 3}, {"id": 8, "bbox": [1981.0, 145.0, 37.0, 38.0], "category_id": 3}, {"id": 9, "bbox": [1635.0, 149.0, 40.0, 44.0], "category_id": 3}], "reactions": [{"reactants": [5], "conditions": [2], "products": [4, 1, 3]}], "corefs": [[5, 0], [4, 7], [1, 9], [3, 8]], "caption": "Table 1. Uncatalyzed and Enzyme Catalyzed Azidolysis: Substrate Scope", "pdf": {"Page": 2, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 75, 439, 88], "ImageBB": [58, 97, 762, 544]}, "diagram_type": "single"}, {"id": 1254, "width": 648, "height": 1212, "file_name": "op049953y-Scheme-c5.png", "license": 0, "bboxes": [{"id": 0, "bbox": [315.14, 212.21, 214.54, 49.11], "category_id": 2}, {"id": 1, "bbox": [315.14, 853.67, 332.86, 154.01], "category_id": 2}, {"id": 2, "bbox": [27.88, 5.46, 561.19, 148.54], "category_id": 1}, {"id": 3, "bbox": [390.9, 468.07, 64.24, 47.29], "category_id": 3}, {"id": 4, "bbox": [27.88, 677.24, 558.16, 153.4], "category_id": 1}, {"id": 5, "bbox": [315.14, 560.83, 270.9, 56.99], "category_id": 2}, {"id": 6, "bbox": [31.51, 1034.96, 487.26, 160.06], "category_id": 1}, {"id": 7, "bbox": [390.9, 129.14, 43.03, 44.26], "category_id": 3}, {"id": 8, "bbox": [313.32, 1164.1, 64.24, 47.9], "category_id": 3}, {"id": 9, "bbox": [315.14, 853.67, 332.72, 154.01], "category_id": 2}, {"id": 10, "bbox": [31.55, 347.72, 558.71, 146.95], "category_id": 1}], "caption": "Scheme 5. Initial route used to prepare vinyl sulfone 15", "pdf": {"Page": 6, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 548, 390, 562], "ImageBB": [157, 566, 319, 869]}, "reactions": [{"reactants": [2], "conditions": [0], "products": [10]}, {"reactants": [10], "conditions": [5], "products": [4]}, {"reactants": [4], "conditions": [9], "products": [6]}], "diagram_type": "tree"}, {"id": 288, "width": 1352, "height": 2052, "file_name": "ol702044z-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [211.5, 0.0, 246.5, 246.0], "category_id": 1}, {"id": 1, "bbox": [510.2, 62.0, 306.8, 93.0], "category_id": 2}, {"id": 2, "bbox": [874.0, 37.0, 271.0, 207.0], "category_id": 1}, {"id": 3, "bbox": [516.0, 157.0, 282.0, 49.0], "category_id": 2}, {"id": 4, "bbox": [13.0, 253.0, 1339.0, 1799.0], "category_id": 4}], "reactions": [{"reactants": [0], "conditions": [1, 3], "products": [2]}], "corefs": [], "caption": "Table 2. Scope of the Intramolecular Palladium-Catalyzed Direct Functionalization of Alkenyl Triflatesa ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 312, 748, 340], "ImageBB": [439, 341, 777, 854]}, "diagram_type": "single"}, {"id": 918, "width": 1352, "height": 1248, "file_name": "acs.joc.5b01703-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [406.48, 774.7, 443.0, 332.2], "category_id": 1}, {"id": 1, "bbox": [160.29, 1088.64, 48.02, 44.65], "category_id": 3}, {"id": 2, "bbox": [721.65, 342.36, 509.29, 96.07], "category_id": 3}, {"id": 3, "bbox": [477.49, 29.09, 36.53, 40.6], "category_id": 2}, {"id": 4, "bbox": [231.31, 322.73, 31.79, 45.34], "category_id": 3}, {"id": 5, "bbox": [483.58, 207.04, 232.66, 215.83], "category_id": 2}, {"id": 6, "bbox": [1123.4, 606.9, 228.6, 80.52], "category_id": 2}, {"id": 7, "bbox": [240.1, 1156.97, 388.89, 49.39], "category_id": 3}, {"id": 8, "bbox": [160.29, 506.09, 204.26, 176.59], "category_id": 1}, {"id": 9, "bbox": [156.23, 692.15, 206.29, 48.72], "category_id": 3}, {"id": 10, "bbox": [14.88, 783.49, 382.13, 347.77], "category_id": 1}, {"id": 11, "bbox": [881.94, 767.93, 441.65, 365.36], "category_id": 1}, {"id": 12, "bbox": [973.25, 1149.53, 248.22, 48.04], "category_id": 3}, {"id": 13, "bbox": [1091.61, 396.48, 260.39, 200.27], "category_id": 1}, {"id": 14, "bbox": [1125.43, 698.24, 226.57, 80.52], "category_id": 2}, {"id": 15, "bbox": [827.84, 8.8, 367.25, 325.44], "category_id": 1}, {"id": 16, "bbox": [567.45, 1075.1, 51.4, 46.69], "category_id": 3}, {"id": 17, "bbox": [491.7, 2.03, 204.25, 138.02], "category_id": 1}, {"id": 18, "bbox": [0.0, 18.27, 428.8, 334.91], "category_id": 1}, {"id": 19, "bbox": [0.0, 458.73, 365.9, 48.71], "category_id": 2}, {"id": 20, "bbox": [491.7, 141.41, 233.33, 43.98], "category_id": 2}], "caption": "Scheme 1. First Generation Synthesis of Naamidine A and Analogues ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 357, 412, 387], "ImageBB": [82, 394, 420, 706]}, "reactions": [{"reactants": [18], "conditions": [3, 17, 20, 5], "products": [15]}, {"reactants": [15], "conditions": [19, 8, 9], "products": [10, 0]}, {"reactants": [15], "conditions": [13, 6, 14], "products": [11]}], "diagram_type": "tree"}, {"id": 1355, "width": 1048, "height": 656, "file_name": "op900008a-Scheme-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [683.64, 433.77, 35.12, 32.52], "category_id": 2}, {"id": 1, "bbox": [6.29, 241.8, 267.37, 152.11], "category_id": 1}, {"id": 2, "bbox": [370.13, 237.6, 305.12, 152.11], "category_id": 1}, {"id": 3, "bbox": [459.25, 7.87, 22.55, 31.99], "category_id": 2}, {"id": 4, "bbox": [166.72, 369.26, 41.41, 34.09], "category_id": 3}, {"id": 5, "bbox": [676.82, 221.87, 33.03, 32.52], "category_id": 2}, {"id": 6, "bbox": [580.88, 11.54, 426.75, 114.87], "category_id": 1}, {"id": 7, "bbox": [562.53, 613.68, 46.66, 37.76], "category_id": 3}, {"id": 8, "bbox": [6.29, 4.72, 362.79, 116.44], "category_id": 1}, {"id": 9, "bbox": [924.8, 371.88, 39.84, 34.62], "category_id": 3}, {"id": 10, "bbox": [859.27, 160.5, 29.35, 35.67], "category_id": 2}, {"id": 11, "bbox": [307.22, 236.03, 20.44, 23.6], "category_id": 2}, {"id": 12, "bbox": [736.06, 243.37, 305.65, 150.54], "category_id": 1}, {"id": 13, "bbox": [371.7, 483.6, 309.32, 150.53], "category_id": 1}, {"id": 14, "bbox": [562.53, 376.6, 41.94, 34.62], "category_id": 3}], "caption": "Scheme 4 a", "pdf": {"Page": 4, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 207, 125, 221], "ImageBB": [96, 230, 358, 394]}, "reactions": [{"reactants": [8], "conditions": [3], "products": [6]}, {"reactants": [6], "conditions": [10], "products": [12]}, {"reactants": [12], "conditions": [5], "products": [2]}, {"reactants": [1], "conditions": [11], "products": [2]}, {"reactants": [12], "conditions": [0], "products": [13]}], "diagram_type": "tree"}, {"id": 1159, "width": 1352, "height": 1224, "file_name": "ol052474e-Scheme-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [780.49, 692.45, 313.15, 261.03], "category_id": 1}, {"id": 1, "bbox": [326.67, 2.7, 117.01, 192.05], "category_id": 1}, {"id": 2, "bbox": [541.75, 108.2, 172.46, 50.04], "category_id": 2}, {"id": 3, "bbox": [541.75, 38.54, 198.84, 50.72], "category_id": 2}, {"id": 4, "bbox": [524.84, 764.13, 236.04, 49.37], "category_id": 2}, {"id": 5, "bbox": [803.49, 363.13, 267.15, 211.66], "category_id": 1}, {"id": 6, "bbox": [541.75, 480.8, 176.52, 48.68], "category_id": 2}, {"id": 7, "bbox": [744.65, 956.18, 388.22, 100.76], "category_id": 3}, {"id": 8, "bbox": [325.32, 362.46, 120.39, 214.36], "category_id": 1}, {"id": 9, "bbox": [562.71, 695.16, 157.59, 53.42], "category_id": 2}, {"id": 10, "bbox": [803.49, 2.7, 267.15, 192.05], "category_id": 1}, {"id": 11, "bbox": [744.65, 193.4, 388.22, 148.77], "category_id": 3}, {"id": 12, "bbox": [562.71, 406.41, 157.59, 56.13], "category_id": 2}, {"id": 13, "bbox": [0.0, 1165.8, 1352.0, 58.2], "category_id": 2}, {"id": 14, "bbox": [225.9, 695.84, 299.2, 125.77], "category_id": 1}, {"id": 15, "bbox": [744.65, 577.5, 386.19, 100.08], "category_id": 3}], "caption": "Scheme 4", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [212, 555, 265, 568], "ImageBB": [73, 573, 411, 879]}, "reactions": [{"reactants": [1], "conditions": [2, 3], "products": [10]}, {"reactants": [8], "conditions": [12, 6], "products": [5]}, {"reactants": [14], "conditions": [9, 4], "products": [0]}], "diagram_type": "multiple"}, {"id": 393, "width": 1356, "height": 1156, "file_name": "op5001463-Figure-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [860.0, 1096.0, 41.0, 53.0], "category_id": 3}, {"id": 1, "bbox": [794.0, 9.0, 343.0, 145.0], "category_id": 1}, {"id": 2, "bbox": [924.0, 592.0, 57.0, 39.0], "category_id": 3}, {"id": 3, "bbox": [192.99, 602.86, 34.09, 43.39], "category_id": 3}, {"id": 4, "bbox": [318.1, 179.0, 40.5, 42.2], "category_id": 3}, {"id": 5, "bbox": [906.0, 156.0, 38.4, 39.2], "category_id": 3}, {"id": 6, "bbox": [424.3, 1095.9, 46.0, 54.0], "category_id": 3}, {"id": 7, "bbox": [220.0, 1099.0, 47.1, 49.3], "category_id": 3}, {"id": 8, "bbox": [501.0, 597.5, 50.2, 44.5], "category_id": 3}, {"id": 9, "bbox": [831.1, 712.89, 330.2, 356.51], "category_id": 1}, {"id": 10, "bbox": [477.8, 711.69, 348.6, 441.71], "category_id": 1}, {"id": 11, "bbox": [192.8, 720.8, 311.7, 302.4], "category_id": 1}, {"id": 12, "bbox": [217.95, 383.05, 152.35, 255.05], "category_id": 1}, {"id": 13, "bbox": [398.2, 238.5, 339.9, 338.9], "category_id": 1}, {"id": 14, "bbox": [831.0, 258.2, 327.5, 313.8], "category_id": 1}, {"id": 15, "bbox": [207.1, 1.3, 339.2, 179.2], "category_id": 1}], "reactions": [{"reactants": [15], "conditions": [], "products": [1]}, {"reactants": [1], "conditions": [12], "products": [13]}, {"reactants": [13], "conditions": [], "products": [14]}], "corefs": [[15, 4], [1, 5], [12, 3], [13, 8], [14, 2], [11, 7], [10, 6], [9, 0]], "caption": "Figure 2. Impurities.", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 414, 551, 428], "ImageBB": [448, 116, 787, 405]}, "diagram_type": "multiple"}, {"id": 510, "width": 1344, "height": 1172, "file_name": "ol051488h-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [329.0, 177.0, 211.4, 163.9], "category_id": 1}, {"id": 1, "bbox": [896.6, 175.3, 386.0, 201.1], "category_id": 1}, {"id": 2, "bbox": [547.0, 0.0, 261.6, 215.1], "category_id": 1}, {"id": 3, "bbox": [1026.0, 392.0, 95.0, 48.9], "category_id": 3}, {"id": 4, "bbox": [635.4, 282.0, 132.6, 53.7], "category_id": 2}, {"id": 5, "bbox": [378.71, 383.0, 43.0, 44.0], "category_id": 3}, {"id": 6, "bbox": [118.0, 386.0, 96.7, 44.0], "category_id": 3}, {"id": 7, "bbox": [60.9, 170.4, 206.1, 193.5], "category_id": 1}, {"id": 8, "bbox": [110.9, 436.3, 165.7, 54.1], "category_id": 2}, {"id": 9, "bbox": [764.0, 121.0, 92.0, 58.0], "category_id": 3}, {"id": 10, "bbox": [583.0, 203.0, 178.0, 52.0], "category_id": 2}, {"id": 11, "bbox": [12.0, 555.0, 1332.0, 617.0], "category_id": 4}], "reactions": [{"reactants": [7, 0], "conditions": [2, 10, 4], "products": [1]}], "corefs": [[7, 6], [0, 5], [2, 9], [1, 3]], "caption": "Table 2. Asymmetric Conjugate Addition of Aldehydes 3a-g to Vinyl Sulfone 2 Catalyzed by Diamine 4c ", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 211, 402, 239], "ImageBB": [74, 244, 410, 537]}, "diagram_type": "single"}, {"id": 224, "width": 1332, "height": 956, "file_name": "op020010f-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [759.0, 411.1, 568.0, 93.9], "category_id": 2}, {"id": 1, "bbox": [471.0, 637.0, 471.0, 45.0], "category_id": 2}, {"id": 2, "bbox": [7.4, 702.0, 697.0, 254.0], "category_id": 1}, {"id": 3, "bbox": [2.5, 2.5, 638.5, 235.0], "category_id": 1}, {"id": 4, "bbox": [0.0, 325.6, 609.4, 255.4], "category_id": 1}, {"id": 5, "bbox": [877.0, 85.0, 271.0, 55.2], "category_id": 2}, {"id": 6, "bbox": [770.0, 791.0, 538.0, 94.4], "category_id": 2}, {"id": 7, "bbox": [450.0, 273.0, 358.8, 51.1], "category_id": 2}], "reactions": [{"reactants": [3], "conditions": [7], "products": [4]}, {"reactants": [4], "conditions": [1], "products": [2]}], "corefs": [[3, 5], [4, 0], [2, 6]], "caption": "Figure 1. Biosynthetic pathway from penicillin N to deacetoxycephalosporin C and deacetylcephalosporin C. ", "pdf": {"Page": 1, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 478, 775, 506], "ImageBB": [442, 233, 775, 472]}, "diagram_type": "tree"}, {"id": 695, "width": 1352, "height": 440, "file_name": "ol0487783-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [318.12, 286.31, 44.86, 47.92], "category_id": 2}, {"id": 1, "bbox": [203.0, 303.0, 31.0, 45.0], "category_id": 3}, {"id": 2, "bbox": [494.0, 317.0, 36.0, 46.0], "category_id": 3}, {"id": 3, "bbox": [901.0, 303.0, 35.0, 48.0], "category_id": 3}, {"id": 4, "bbox": [318.0, 380.0, 346.0, 56.0], "category_id": 2}, {"id": 5, "bbox": [318.0, 194.0, 175.0, 48.0], "category_id": 2}, {"id": 6, "bbox": [318.0, 147.0, 235.0, 49.0], "category_id": 2}, {"id": 7, "bbox": [127.0, 196.0, 136.0, 108.0], "category_id": 1}, {"id": 8, "bbox": [365.3, 268.0, 369.7, 99.0], "category_id": 1}, {"id": 9, "bbox": [780.0, 168.0, 448.6, 214.0], "category_id": 1}], "reactions": [{"reactants": [7], "conditions": [6, 5, 0, 8, 4], "products": [9]}], "corefs": [[7, 1], [9, 3]], "caption": "Figure 1. One-pot preparation of C,C-dicyclopropylmethylamines.", "pdf": {"Page": 1, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 825, 775, 838], "ImageBB": [439, 703, 777, 813]}, "diagram_type": "single"}, {"id": 825, "width": 1348, "height": 532, "file_name": "jo400755q-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [486.0, 179.0, 346.0, 98.0], "category_id": 2}, {"id": 1, "bbox": [492.0, 74.0, 379.0, 97.0], "category_id": 2}, {"id": 2, "bbox": [282.07, 385.0, 62.0, 53.0], "category_id": 3}, {"id": 3, "bbox": [992.05, 386.0, 74.0, 47.0], "category_id": 3}, {"id": 4, "bbox": [881.3, 13.9, 308.7, 355.1], "category_id": 1}, {"id": 5, "bbox": [162.2, 2.0, 271.3, 357.8], "category_id": 1}], "reactions": [{"reactants": [5], "conditions": [1, 0], "products": [4]}], "corefs": [[5, 2], [4, 3]], "caption": "Table 1. Optimization of the Reaction Conditionsa", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 554, 371, 575], "ImageBB": [82, 581, 419, 714]}, "diagram_type": "single"}, {"id": 124, "width": 1344, "height": 1040, "file_name": "op970105v-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [478.0, 40.0, 364.0, 371.0], "category_id": 1}, {"id": 1, "bbox": [498.66, 410.64, 413.0, 100.0], "category_id": 3}, {"id": 2, "bbox": [348.32, 164.66, 84.0, 48.0], "category_id": 2}, {"id": 3, "bbox": [838.0, 90.0, 368.0, 304.6], "category_id": 1}, {"id": 4, "bbox": [31.0, 416.0, 424.3, 104.3], "category_id": 3}, {"id": 5, "bbox": [918.64, 410.64, 411.0, 98.0], "category_id": 3}, {"id": 6, "bbox": [2.0, 1.0, 347.0, 409.0], "category_id": 1}, {"id": 7, "bbox": [2.0, 544.0, 1336.0, 496.0], "category_id": 4}], "reactions": [{"reactants": [6], "conditions": [2], "products": [0, 3]}], "corefs": [[6, 4], [0, 1], [3, 5]], "caption": "Table 1", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [73, 50, 119, 64], "ImageBB": [73, 63, 409, 323]}, "diagram_type": "single"}, {"id": 202, "width": 2808, "height": 2436, "file_name": "op049803n-Table-c7.png", "license": 0, "bboxes": [{"id": 0, "bbox": [447.0, 2177.0, 1889.4, 259.0], "category_id": 4}, {"id": 1, "bbox": [476.0, 1592.0, 1483.6, 269.0], "category_id": 4}, {"id": 2, "bbox": [1587.0, 1899.0, 258.0, 234.2], "category_id": 1}, {"id": 3, "bbox": [1916.0, 2001.0, 217.3, 86.0], "category_id": 2}, {"id": 4, "bbox": [2194.23, 2001.57, 133.88, 84.9], "category_id": 2}, {"id": 5, "bbox": [1199.0, 1504.0, 153.0, 57.0], "category_id": 2}, {"id": 6, "bbox": [1495.0, 1337.0, 256.0, 229.0], "category_id": 1}, {"id": 7, "bbox": [1177.0, 1355.0, 253.0, 124.0], "category_id": 2}, {"id": 8, "bbox": [1006.0, 1455.0, 144.0, 71.0], "category_id": 2}, {"id": 9, "bbox": [1820.0, 1455.0, 105.0, 62.0], "category_id": 2}, {"id": 10, "bbox": [654.0, 1901.0, 261.0, 242.0], "category_id": 1}, {"id": 11, "bbox": [986.0, 2003.0, 224.0, 75.0], "category_id": 2}, {"id": 12, "bbox": [1272.0, 2005.0, 113.0, 73.0], "category_id": 2}, {"id": 13, "bbox": [1394.0, 2069.0, 133.0, 54.0], "category_id": 2}, {"id": 14, "bbox": [0.0, 4.0, 2808.0, 1227.0], "category_id": 4}, {"id": 15, "bbox": [660.0, 1342.0, 275.0, 224.0], "category_id": 1}], "reactions": [{"reactants": [15, 8], "conditions": [7, 5], "products": [6, 9]}, {"reactants": [10, 11, 12], "conditions": [13], "products": [2, 3, 4]}], "corefs": [], "caption": "Table 7. Summary of kernel reaction metrics analysis for sildenafil (Viagra) synthesis determined by algorithm described in text under the assumptions of recoverable reaction solvents and catalysts, solvents used in workup and purification procedures, and each intermediate product committed as a substrate in the next consecutive step in the sequencea ", "pdf": {"Page": 13, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 53, 769, 95], "ImageBB": [74, 98, 776, 707]}, "diagram_type": "multiple"}, {"id": 110, "width": 1348, "height": 700, "file_name": "ja001164i-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [446.63, 46.4, 460.83, 42.7], "category_id": 2}, {"id": 1, "bbox": [289.96, 220.37, 23.36, 32.52], "category_id": 3}, {"id": 2, "bbox": [1113.0, 223.42, 23.36, 30.49], "category_id": 3}, {"id": 3, "bbox": [181.1, 5.71, 170.88, 189.19], "category_id": 1}, {"id": 4, "bbox": [1014.32, 7.74, 160.7, 186.14], "category_id": 1}, {"id": 5, "bbox": [6.35, 290.68, 1336.06, 402.13], "category_id": 4}, {"id": 6, "bbox": [552.44, 125.76, 270.58, 73.21], "category_id": 2}], "reactions": [{"reactants": [3], "conditions": [0, 6], "products": [4]}], "corefs": [[3, 1], [4, 2]], "caption": "Table 3. Enantioselective Protonation of Silyl Enol Ethers 3a", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 64, 745, 78], "ImageBB": [439, 86, 776, 261]}, "diagram_type": "single"}, {"id": 956, "width": 1356, "height": 1180, "file_name": "acs.orglett.6b01181-Scheme-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [845.89, 4.07, 165.51, 263.19], "category_id": 1}, {"id": 1, "bbox": [439.56, 649.16, 49.52, 41.38], "category_id": 3}, {"id": 2, "bbox": [1024.29, 137.7, 128.21, 94.97], "category_id": 2}, {"id": 3, "bbox": [612.54, 228.6, 229.96, 59.69], "category_id": 2}, {"id": 4, "bbox": [14.92, 257.09, 291.01, 230.63], "category_id": 1}, {"id": 5, "bbox": [374.44, 820.78, 287.62, 282.86], "category_id": 1}, {"id": 6, "bbox": [715.65, 130.24, 141.77, 53.59], "category_id": 2}, {"id": 7, "bbox": [404.97, 237.42, 52.91, 48.84], "category_id": 3}, {"id": 8, "bbox": [439.56, 348.66, 170.95, 59.02], "category_id": 2}, {"id": 9, "bbox": [1140.97, 4.07, 200.78, 218.42], "category_id": 1}, {"id": 10, "bbox": [1024.97, 69.87, 111.25, 48.16], "category_id": 2}, {"id": 11, "bbox": [656.63, 1085.4, 238.77, 48.4], "category_id": 1}, {"id": 12, "bbox": [158.73, 4.07, 362.91, 286.93], "category_id": 1}, {"id": 13, "bbox": [1174.21, 212.32, 63.76, 51.55], "category_id": 3}, {"id": 14, "bbox": [978.17, 431.42, 341.2, 263.19], "category_id": 1}, {"id": 15, "bbox": [904.67, 1090.81, 52.42, 41.08], "category_id": 3}, {"id": 16, "bbox": [1056.25, 1056.81, 41.08, 42.5], "category_id": 3}, {"id": 17, "bbox": [1122.83, 834.41, 106.24, 41.08], "category_id": 2}, {"id": 18, "bbox": [112.6, 477.54, 85.48, 48.84], "category_id": 3}, {"id": 19, "bbox": [613.22, 32.56, 214.35, 69.87], "category_id": 2}, {"id": 20, "bbox": [193.33, 431.42, 320.17, 268.62], "category_id": 1}, {"id": 21, "bbox": [997.84, 648.48, 40.7, 50.88], "category_id": 3}, {"id": 22, "bbox": [875.06, 195.36, 38.66, 44.77], "category_id": 3}, {"id": 23, "bbox": [1040.67, 332.95, 96.32, 45.33], "category_id": 2}, {"id": 24, "bbox": [162.39, 221.04, 100.58, 43.91], "category_id": 2}, {"id": 25, "bbox": [257.3, 252.2, 68.0, 38.25], "category_id": 2}, {"id": 26, "bbox": [872.09, 841.5, 236.57, 259.23], "category_id": 1}], "caption": "Scheme 4. Proposed Reaction Pathway", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 217, 669, 232], "ImageBB": [448, 239, 787, 534]}, "reactions": [{"reactants": [9], "conditions": [10, 2], "products": [0]}, {"reactants": [19], "conditions": [6], "products": [3]}, {"reactants": [3, 0], "conditions": [], "products": [23, 14]}, {"reactants": [14], "conditions": [], "products": [26, 17]}, {"reactants": [26, 11], "conditions": [], "products": [5]}, {"reactants": [5], "conditions": [], "products": [20]}, {"reactants": [20], "conditions": [], "products": [5]}, {"reactants": [20], "conditions": [8], "products": [12, 3]}, {"reactants": [12], "conditions": [24, 25], "products": [4]}], "diagram_type": "graph"}, {"id": 842, "width": 1352, "height": 1120, "file_name": "jo201996w-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [378.1, 22.0, 205.9, 163.0], "category_id": 1}, {"id": 1, "bbox": [675.0, 50.0, 143.0, 50.0], "category_id": 2}, {"id": 2, "bbox": [615.0, 129.0, 283.0, 91.0], "category_id": 2}, {"id": 3, "bbox": [1136.0, 236.0, 32.0, 42.0], "category_id": 3}, {"id": 4, "bbox": [103.0, 238.0, 39.0, 38.0], "category_id": 3}, {"id": 5, "bbox": [347.0, 234.0, 264.0, 148.0], "category_id": 3}, {"id": 6, "bbox": [957.8, 5.0, 370.2, 212.0], "category_id": 1}, {"id": 7, "bbox": [33.9, 27.0, 221.1, 161.0], "category_id": 1}, {"id": 8, "bbox": [16.0, 406.0, 1322.0, 681.0], "category_id": 4}], "reactions": [{"reactants": [7, 0], "conditions": [1, 2], "products": [6]}], "corefs": [[7, 4], [0, 5], [6, 3]], "caption": "Table 1. Synthesis of 2,2\u2032-Dinitrogen-Substituted Azo- benzenes 3 ", "pdf": {"Page": 2, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [70, 235, 405, 266], "ImageBB": [69, 272, 407, 552]}, "diagram_type": "single"}, {"id": 868, "width": 1352, "height": 2596, "file_name": "jo2001275-Figure-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1102.0, 755.7, 64.0, 65.6], "category_id": 3}, {"id": 1, "bbox": [1144.42, 354.58, 63.56, 50.18], "category_id": 3}, {"id": 2, "bbox": [462.4, 755.3, 77.6, 59.7], "category_id": 3}, {"id": 3, "bbox": [538.91, 344.54, 56.87, 50.18], "category_id": 3}, {"id": 4, "bbox": [348.0, 3.0, 382.0, 388.0], "category_id": 1}, {"id": 5, "bbox": [977.1, 436.0, 374.9, 391.6], "category_id": 1}, {"id": 6, "bbox": [951.0, 10.0, 397.7, 393.2], "category_id": 1}, {"id": 7, "bbox": [398.7, 439.7, 318.3, 375.3], "category_id": 1}, {"id": 8, "bbox": [175.04, 588.0, 126.0, 63.0], "category_id": 2}, {"id": 9, "bbox": [1.45, 161.96, 64.06, 52.75], "category_id": 3}, {"id": 10, "bbox": [130.0, 107.0, 208.0, 73.0], "category_id": 2}, {"id": 11, "bbox": [758.0, 104.0, 196.0, 92.0], "category_id": 2}, {"id": 12, "bbox": [951.0, 888.0, 167.0, 85.0], "category_id": 3}, {"id": 13, "bbox": [4.0, 1599.0, 1348.0, 997.0], "category_id": 4}, {"id": 14, "bbox": [739.0, 597.0, 180.0, 114.0], "category_id": 2}, {"id": 15, "bbox": [730.0, 477.0, 208.0, 95.0], "category_id": 2}, {"id": 16, "bbox": [336.0, 835.7, 855.0, 675.3], "category_id": 1}, {"id": 17, "bbox": [761.0, 221.0, 146.0, 63.0], "category_id": 2}, {"id": 18, "bbox": [177.0, 509.0, 130.0, 53.0], "category_id": 2}, {"id": 19, "bbox": [95.0, 205.0, 262.0, 111.0], "category_id": 2}], "reactions": [{"reactants": [9], "conditions": [10, 19], "products": [4]}, {"reactants": [4], "conditions": [11, 17], "products": [6]}, {"reactants": [6], "conditions": [18, 8], "products": [7]}, {"reactants": [7], "conditions": [15, 14], "products": [5]}], "corefs": [[4, 3], [6, 1], [7, 2], [5, 0]], "caption": "Figure 2. Biological evaluation of damsin and psilostachyin C.", "pdf": {"Page": 3, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [71, 780, 368, 794], "ImageBB": [71, 117, 409, 766]}, "diagram_type": "multiple"}, {"id": 726, "width": 1272, "height": 2160, "file_name": "ol0171867-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [522.0, 132.0, 237.0, 114.0], "category_id": 2}, {"id": 1, "bbox": [341.0, 95.0, 144.0, 67.0], "category_id": 2}, {"id": 2, "bbox": [525.0, 4.6, 368.0, 110.4], "category_id": 2}, {"id": 3, "bbox": [46.5, 70.3, 183.0, 119.0], "category_id": 1}, {"id": 4, "bbox": [6.0, 257.7, 1266.0, 1902.3], "category_id": 4}, {"id": 5, "bbox": [952.6, 76.0, 291.7, 111.8], "category_id": 1}], "reactions": [{"reactants": [3, 1], "conditions": [2, 0], "products": [5]}], "corefs": [], "caption": "Table 1. Copper-Catalyzed Amination: Effect of Diol Liganda", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 75, 771, 89], "ImageBB": [449, 92, 767, 632]}, "diagram_type": "single"}, {"id": 883, "width": 1348, "height": 564, "file_name": "ol503587n-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [275.0, 179.0, 42.0, 41.0], "category_id": 3}, {"id": 1, "bbox": [234.0, 376.0, 37.0, 41.0], "category_id": 3}, {"id": 2, "bbox": [13.0, 450.0, 1335.0, 114.0], "category_id": 4}, {"id": 3, "bbox": [614.0, 192.0, 27.0, 36.0], "category_id": 3}, {"id": 4, "bbox": [151.4, 102.3, 214.6, 113.8], "category_id": 1}, {"id": 5, "bbox": [125.58, 258.84, 188.12, 128.26], "category_id": 1}, {"id": 6, "bbox": [913.0, 136.0, 321.0, 182.7], "category_id": 1}, {"id": 7, "bbox": [1046.0, 301.0, 24.8, 38.1], "category_id": 3}, {"id": 8, "bbox": [505.7, 3.4, 235.3, 209.0], "category_id": 1}, {"id": 9, "bbox": [482.6, 268.3, 270.4, 93.7], "category_id": 2}], "reactions": [{"reactants": [4, 5], "conditions": [8, 9], "products": [6]}], "corefs": [[4, 0], [5, 1], [8, 3], [6, 7]], "caption": "Table 1. Coupling of Aniline and Benzyl Alcohol Using Catalyst 1a ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 396, 125], "ImageBB": [82, 131, 419, 272]}, "diagram_type": "single"}, {"id": 1337, "width": 1356, "height": 1940, "file_name": "op5003165-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [108.66, 759.89, 208.6, 254.27], "category_id": 1}, {"id": 1, "bbox": [889.67, 488.15, 88.29, 47.56], "category_id": 2}, {"id": 2, "bbox": [575.33, 694.87, 61.12, 51.43], "category_id": 3}, {"id": 3, "bbox": [0.0, 1584.8, 404.57, 250.39], "category_id": 1}, {"id": 4, "bbox": [516.15, 1858.48, 48.51, 42.7], "category_id": 3}, {"id": 5, "bbox": [837.28, 1197.58, 418.16, 252.32], "category_id": 1}, {"id": 6, "bbox": [1155.51, 306.67, 107.69, 111.61], "category_id": 2}, {"id": 7, "bbox": [837.28, 116.46, 126.13, 74.73], "category_id": 2}, {"id": 8, "bbox": [692.72, 1742.02, 82.47, 68.91], "category_id": 2}, {"id": 9, "bbox": [818.85, 1579.95, 532.64, 255.24], "category_id": 1}, {"id": 10, "bbox": [815.94, 803.56, 290.09, 155.28], "category_id": 1}, {"id": 11, "bbox": [3.88, 1934.18, 1347.61, 5.82], "category_id": 4}, {"id": 12, "bbox": [1042.96, 19.41, 282.33, 164.98], "category_id": 1}, {"id": 13, "bbox": [138.74, 1194.67, 403.6, 255.23], "category_id": 1}, {"id": 14, "bbox": [889.67, 1043.27, 49.48, 40.76], "category_id": 3}, {"id": 15, "bbox": [693.69, 1677.97, 83.44, 43.67], "category_id": 2}, {"id": 16, "bbox": [476.37, 488.15, 328.9, 168.87], "category_id": 1}, {"id": 17, "bbox": [311.43, 55.32, 97.99, 44.64], "category_id": 2}, {"id": 18, "bbox": [346.36, 902.55, 98.96, 67.94], "category_id": 2}, {"id": 19, "bbox": [1136.1, 233.89, 40.75, 39.79], "category_id": 3}, {"id": 20, "bbox": [1024.53, 480.39, 327.93, 166.92], "category_id": 1}, {"id": 21, "bbox": [572.42, 1046.18, 42.69, 37.85], "category_id": 3}, {"id": 22, "bbox": [617.05, 1253.87, 129.03, 48.52], "category_id": 2}, {"id": 23, "bbox": [108.66, 230.98, 39.78, 42.7], "category_id": 3}, {"id": 24, "bbox": [160.08, 1043.27, 42.69, 40.76], "category_id": 3}, {"id": 25, "bbox": [414.28, 1659.53, 204.71, 163.04], "category_id": 1}, {"id": 26, "bbox": [1042.96, 1858.48, 36.87, 40.76], "category_id": 3}, {"id": 27, "bbox": [850.5, 52.5, 100.0, 35.0], "category_id": 2}, {"id": 28, "bbox": [837.28, 559.0, 178.52, 147.51], "category_id": 2}, {"id": 29, "bbox": [136.8, 1858.48, 43.66, 40.76], "category_id": 3}, {"id": 30, "bbox": [516.15, 777.36, 205.68, 256.21], "category_id": 1}, {"id": 31, "bbox": [957.59, 1472.23, 40.75, 36.87], "category_id": 3}, {"id": 32, "bbox": [837.28, 1196.61, 418.16, 253.29], "category_id": 1}, {"id": 33, "bbox": [617.05, 1319.86, 158.14, 76.67], "category_id": 2}, {"id": 34, "bbox": [315.31, 123.25, 100.91, 73.76], "category_id": 2}, {"id": 35, "bbox": [579.21, 230.98, 41.72, 43.67], "category_id": 3}, {"id": 36, "bbox": [1155.51, 697.78, 37.84, 41.73], "category_id": 3}, {"id": 37, "bbox": [350.24, 840.44, 108.66, 46.58], "category_id": 2}, {"id": 38, "bbox": [243.52, 1472.23, 50.45, 38.82], "category_id": 3}, {"id": 39, "bbox": [477.34, 0.0, 312.4, 208.65], "category_id": 1}, {"id": 40, "bbox": [3.88, 15.53, 241.58, 177.6], "category_id": 1}], "caption": "Scheme 1. Original synthesis of (1)", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 366, 650, 381], "ImageBB": [448, 387, 787, 872]}, "reactions": [{"reactants": [40], "conditions": [17, 34], "products": [39]}, {"reactants": [39], "conditions": [27, 7], "products": [12]}, {"reactants": [12], "conditions": [6], "products": [20]}, {"reactants": [20], "conditions": [1, 28], "products": [16]}, {"reactants": [0], "conditions": [37, 18], "products": [30]}, {"reactants": [30, 10], "conditions": [], "products": [32]}, {"reactants": [32], "conditions": [22, 33], "products": [13]}, {"reactants": [3, 25], "conditions": [15, 8], "products": [9]}], "diagram_type": "tree"}, {"id": 194, "width": 1320, "height": 1012, "file_name": "op0600106-Figure-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [818.0, 970.0, 46.0, 40.0], "category_id": 3}, {"id": 1, "bbox": [112.0, 730.0, 45.0, 44.0], "category_id": 3}, {"id": 2, "bbox": [946.0, 130.0, 71.0, 51.0], "category_id": 2}, {"id": 3, "bbox": [933.0, 235.0, 104.0, 106.0], "category_id": 2}, {"id": 4, "bbox": [652.0, 518.0, 336.0, 438.0], "category_id": 1}, {"id": 5, "bbox": [0.0, 393.0, 246.0, 312.0], "category_id": 1}, {"id": 6, "bbox": [1190.0, 420.0, 45.0, 46.0], "category_id": 3}, {"id": 7, "bbox": [266.42, 500.83, 237.94, 51.41], "category_id": 1}, {"id": 8, "bbox": [777.56, 345.14, 63.15, 49.94], "category_id": 3}, {"id": 9, "bbox": [1075.3, 69.0, 241.8, 317.0], "category_id": 1}, {"id": 10, "bbox": [323.1, 585.7, 134.1, 150.3], "category_id": 2}, {"id": 11, "bbox": [537.9, 6.0, 370.9, 488.0], "category_id": 1}, {"id": 12, "bbox": [267.0, 447.0, 236.0, 43.2], "category_id": 1}], "reactions": [{"reactants": [5], "conditions": [12, 7, 10], "products": [11, 4]}, {"reactants": [11], "conditions": [2, 3], "products": [9]}], "corefs": [[5, 1], [11, 8], [9, 6], [4, 0]], "caption": "Figure 2. Example of synthesis of cyclic sulfamide 13.", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 309, 375, 323], "ImageBB": [73, 53, 403, 306]}, "diagram_type": "tree"}, {"id": 390, "width": 1356, "height": 1440, "file_name": "op500224x-Figure-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [50.2, 577.0, 289.8, 272.9], "category_id": 1}, {"id": 1, "bbox": [10.7, 152.8, 248.3, 141.8], "category_id": 1}, {"id": 2, "bbox": [478.0, 192.7, 266.2, 271.3], "category_id": 1}, {"id": 3, "bbox": [987.7, 1057.7, 343.0, 214.6], "category_id": 1}, {"id": 4, "bbox": [574.9, 1045.7, 291.1, 226.3], "category_id": 1}, {"id": 5, "bbox": [1008.0, 182.0, 271.7, 272.0], "category_id": 1}, {"id": 6, "bbox": [55.0, 1047.7, 297.0, 227.3], "category_id": 1}, {"id": 7, "bbox": [257.0, 229.7, 200.1, 64.3], "category_id": 2}, {"id": 8, "bbox": [281.9, 317.7, 149.1, 95.4], "category_id": 2}, {"id": 9, "bbox": [997.0, 575.0, 277.7, 277.8], "category_id": 1}, {"id": 10, "bbox": [510.0, 570.0, 300.6, 278.9], "category_id": 1}, {"id": 11, "bbox": [1142.0, 1278.0, 93.0, 51.0], "category_id": 3}, {"id": 12, "bbox": [143.0, 456.0, 100.0, 54.0], "category_id": 3}, {"id": 13, "bbox": [512.0, 471.0, 230.0, 42.0], "category_id": 3}, {"id": 14, "bbox": [510.0, 506.0, 240.0, 44.0], "category_id": 3}, {"id": 15, "bbox": [889.0, 464.0, 421.0, 44.0], "category_id": 3}, {"id": 16, "bbox": [889.0, 508.0, 424.0, 48.0], "category_id": 3}, {"id": 17, "bbox": [184.0, 131.0, 101.0, 58.0], "category_id": 3}, {"id": 18, "bbox": [382.0, 680.0, 63.0, 49.0], "category_id": 2}, {"id": 19, "bbox": [443.0, 1104.0, 130.0, 58.0], "category_id": 2}, {"id": 20, "bbox": [1145.0, 933.0, 100.0, 50.0], "category_id": 2}, {"id": 21, "bbox": [1106.0, 850.0, 89.0, 58.0], "category_id": 3}, {"id": 22, "bbox": [650.0, 852.0, 97.0, 58.0], "category_id": 3}, {"id": 23, "bbox": [164.0, 850.0, 100.0, 55.0], "category_id": 3}, {"id": 24, "bbox": [161.0, 1282.0, 107.0, 58.0], "category_id": 3}, {"id": 25, "bbox": [694.0, 1278.0, 102.0, 60.0], "category_id": 3}, {"id": 26, "bbox": [1.0, 1.0, 1355.0, 107.0], "category_id": 4}, {"id": 27, "bbox": [792.0, 203.0, 165.0, 124.0], "category_id": 2}, {"id": 28, "bbox": [978.0, 1331.0, 378.0, 109.0], "category_id": 2}, {"id": 29, "bbox": [754.0, 349.0, 249.0, 101.5], "category_id": 2}, {"id": 30, "bbox": [0.55, 241.25, 256.73, 208.48], "category_id": 1}], "reactions": [{"reactants": [1, 30], "conditions": [7, 8], "products": [2]}, {"reactants": [2], "conditions": [27, 29], "products": [5]}, {"reactants": [0], "conditions": [18], "products": [10]}, {"reactants": [10], "conditions": [], "products": [9]}, {"reactants": [9], "conditions": [20], "products": [3]}, {"reactants": [3], "conditions": [], "products": [4]}, {"reactants": [4], "conditions": [19], "products": [6]}], "corefs": [[1, 17], [30, 12], [2, 13], [2, 14], [5, 15], [5, 16], [0, 23], [10, 22], [9, 21], [6, 24], [4, 25], [3, 11]], "caption": "Figure 4. Synthesis of cyclopropyl pyrrolidines.", "pdf": {"Page": 7, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 849, 679, 863], "ImageBB": [448, 480, 787, 840]}, "diagram_type": "tree"}, {"id": 834, "width": 1352, "height": 512, "file_name": "jo302288z-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [294.9, 374.0, 1020.1, 91.0], "category_id": 4}, {"id": 1, "bbox": [31.0, 242.0, 416.0, 133.0], "category_id": 1}, {"id": 2, "bbox": [159.0, 6.0, 166.0, 183.0], "category_id": 1}, {"id": 3, "bbox": [799.0, 57.0, 370.0, 302.0], "category_id": 1}, {"id": 4, "bbox": [216.0, 376.0, 52.0, 38.0], "category_id": 3}, {"id": 5, "bbox": [494.0, 102.0, 243.0, 91.0], "category_id": 2}, {"id": 6, "bbox": [502.0, 199.0, 213.0, 85.0], "category_id": 2}], "reactions": [{"reactants": [2, 1], "conditions": [5, 6], "products": [3]}], "corefs": [[1, 4]], "caption": "Table 3. Michael Reactions of 1a with 2 by Catalyst 3f under Solvent-Free Conditions for 2 ha ", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 629, 417, 659], "ImageBB": [82, 494, 420, 622]}, "diagram_type": "single"}, {"id": 1163, "width": 1352, "height": 1312, "file_name": "ol060531d-Scheme-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [217.1, 945.88, 250.93, 99.38], "category_id": 2}, {"id": 1, "bbox": [124.45, 117.64, 59.51, 53.42], "category_id": 3}, {"id": 2, "bbox": [1125.43, 284.64, 59.51, 55.44], "category_id": 3}, {"id": 3, "bbox": [197.49, 406.34, 256.33, 96.01], "category_id": 2}, {"id": 4, "bbox": [1029.39, 32.45, 194.11, 175.79], "category_id": 1}, {"id": 5, "bbox": [954.99, 1210.91, 61.55, 47.33], "category_id": 3}, {"id": 6, "bbox": [551.89, 383.35, 676.34, 298.17], "category_id": 1}, {"id": 7, "bbox": [218.46, 1062.84, 283.38, 58.83], "category_id": 2}, {"id": 8, "bbox": [968.52, 686.93, 48.02, 47.32], "category_id": 3}, {"id": 9, "bbox": [195.46, 0.0, 142.03, 135.9], "category_id": 2}, {"id": 10, "bbox": [563.39, 290.73, 68.99, 45.3], "category_id": 3}, {"id": 11, "bbox": [192.49, 168.55, 190.58, 133.88], "category_id": 2}, {"id": 12, "bbox": [125.8, 1022.95, 57.49, 54.77], "category_id": 3}, {"id": 13, "bbox": [762.91, 45.3, 263.77, 93.3], "category_id": 2}, {"id": 14, "bbox": [551.89, 745.75, 666.2, 453.67], "category_id": 1}, {"id": 15, "bbox": [348.99, 0.0, 470.06, 300.19], "category_id": 1}, {"id": 16, "bbox": [197.49, 526.69, 286.09, 54.09], "category_id": 2}], "caption": "Scheme 4", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [578, 278, 631, 291], "ImageBB": [439, 296, 777, 624]}, "reactions": [{"reactants": [1], "conditions": [9, 11], "products": [15]}, {"reactants": [15], "conditions": [13], "products": [4]}, {"reactants": [4], "conditions": [3, 16], "products": [6]}, {"reactants": [12], "conditions": [0, 7], "products": [14]}], "diagram_type": "multiple"}, {"id": 498, "width": 1280, "height": 1104, "file_name": "ol053021c-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [525.0, 165.8, 354.9, 102.3], "category_id": 2}, {"id": 1, "bbox": [523.0, 72.6, 356.2, 56.4], "category_id": 2}, {"id": 2, "bbox": [927.7, 20.8, 346.4, 260.4], "category_id": 1}, {"id": 3, "bbox": [134.3, 1.5, 343.1, 261.9], "category_id": 1}, {"id": 4, "bbox": [2.0, 291.8, 1278.0, 812.2], "category_id": 4}, {"id": 5, "bbox": [665.2, 26.62, 68.07, 50.32], "category_id": 3}], "reactions": [{"reactants": [3], "conditions": [5, 1, 0], "products": [2]}], "corefs": [], "caption": "Table 2. Arylation of Heteroarenes Bearing Basic Nitrogensa", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 429, 763, 443], "ImageBB": [448, 452, 768, 728]}, "diagram_type": "single"}, {"id": 968, "width": 1220, "height": 1152, "file_name": "ja0289088-Scheme-c9.png", "license": 0, "bboxes": [{"id": 0, "bbox": [418.67, 600.4, 200.79, 43.32], "category_id": 2}, {"id": 1, "bbox": [418.67, 543.04, 201.4, 50.65], "category_id": 2}, {"id": 2, "bbox": [0.0, 1217.27, 1220.0, -65.27], "category_id": 2}, {"id": 3, "bbox": [371.07, 3.66, 227.64, 165.35], "category_id": 1}, {"id": 4, "bbox": [64.08, 630.3, 231.31, 183.04], "category_id": 1}, {"id": 5, "bbox": [175.77, 771.24, 121.45, 57.97], "category_id": 2}, {"id": 6, "bbox": [418.67, 481.42, 180.04, 56.74], "category_id": 2}, {"id": 7, "bbox": [0.0, 1010.43, 192.86, 141.57], "category_id": 1}, {"id": 8, "bbox": [7.32, 405.76, 158.07, 54.91], "category_id": 2}, {"id": 9, "bbox": [443.69, 686.43, 125.11, 44.54], "category_id": 2}, {"id": 10, "bbox": [372.29, 280.06, 231.91, 185.44], "category_id": 1}, {"id": 11, "bbox": [347.87, 493.01, 53.1, 43.93], "category_id": 3}, {"id": 12, "bbox": [504.95, 423.22, 66.38, 55.31], "category_id": 2}, {"id": 13, "bbox": [854.84, 752.36, 127.23, 59.47], "category_id": 2}, {"id": 14, "bbox": [443.69, 201.35, 292.95, 45.77], "category_id": 2}, {"id": 15, "bbox": [737.86, 616.87, 245.34, 181.22], "category_id": 1}, {"id": 16, "bbox": [778.75, 803.58, 59.81, 42.1], "category_id": 3}, {"id": 17, "bbox": [793.4, 392.33, 129.38, 43.93], "category_id": 2}, {"id": 18, "bbox": [813.54, 435.65, 406.46, 49.43], "category_id": 2}, {"id": 19, "bbox": [792.18, 1011.65, 189.8, 137.89], "category_id": 1}], "caption": "Scheme 9. Catalytic Cycle for Alkene Epoxidation", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 64, 693, 76], "ImageBB": [455, 80, 760, 368]}, "reactions": [{"reactants": [3], "conditions": [14], "products": [10, 12]}, {"reactants": [10, 12], "conditions": [17, 18], "products": [15, 13]}, {"reactants": [15, 13, 19], "conditions": [], "products": [4, 5, 7]}, {"reactants": [4, 5], "conditions": [9], "products": [15, 13]}, {"reactants": [4, 5], "conditions": [8], "products": [10, 12]}], "diagram_type": "graph"}, {"id": 271, "width": 1332, "height": 2444, "file_name": "ol801034x-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [590.0, 181.0, 346.0, 87.0], "category_id": 2}, {"id": 1, "bbox": [0.0, 39.0, 306.0, 223.0], "category_id": 1}, {"id": 2, "bbox": [1123.0, 278.0, 49.0, 48.0], "category_id": 3}, {"id": 3, "bbox": [477.0, 278.0, 44.0, 50.0], "category_id": 3}, {"id": 4, "bbox": [132.0, 281.0, 33.0, 49.0], "category_id": 3}, {"id": 5, "bbox": [582.0, 0.0, 335.0, 141.0], "category_id": 2}, {"id": 6, "bbox": [340.0, 0.0, 238.0, 218.0], "category_id": 1}, {"id": 7, "bbox": [960.0, 31.0, 368.0, 199.0], "category_id": 1}, {"id": 8, "bbox": [39.0, 364.0, 1254.0, 2080.0], "category_id": 4}], "reactions": [{"reactants": [1, 6], "conditions": [5, 0], "products": [7]}], "corefs": [[1, 4], [6, 3], [7, 2]], "caption": "Table 2. Reaction of 1 with Aldehydes to Generate 2-Aryl and 2-Vinyl Indolesa ", "pdf": {"Page": 3, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 75, 385, 102], "ImageBB": [60, 111, 393, 722]}, "diagram_type": "single"}, {"id": 1323, "width": 2820, "height": 932, "file_name": "op300331b-Scheme-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [651.75, 297.36, 365.37, 59.19], "category_id": 2}, {"id": 1, "bbox": [349.85, 555.25, 414.75, 245.22], "category_id": 1}, {"id": 2, "bbox": [1904.45, 388.96, 71.95, 56.37], "category_id": 3}, {"id": 3, "bbox": [459.89, 834.29, 64.89, 59.19], "category_id": 3}, {"id": 4, "bbox": [1864.95, 511.57, 602.37, 300.17], "category_id": 1}, {"id": 5, "bbox": [1431.87, 202.94, 183.39, 74.69], "category_id": 2}, {"id": 6, "bbox": [1252.71, 388.96, 70.53, 57.78], "category_id": 3}, {"id": 7, "bbox": [1718.24, 114.15, 338.57, 242.4], "category_id": 1}, {"id": 8, "bbox": [1091.89, 114.15, 335.74, 243.8], "category_id": 1}, {"id": 9, "bbox": [1132.8, 549.62, 517.73, 249.44], "category_id": 1}, {"id": 10, "bbox": [1616.67, 542.57, 259.57, 155.02], "category_id": 1}, {"id": 11, "bbox": [1255.53, 834.29, 71.94, 59.19], "category_id": 3}, {"id": 12, "bbox": [655.98, 191.66, 347.03, 70.46], "category_id": 2}, {"id": 13, "bbox": [2158.38, 834.29, 56.43, 54.96], "category_id": 3}, {"id": 14, "bbox": [746.26, 624.31, 301.89, 73.28], "category_id": 2}, {"id": 15, "bbox": [465.53, 390.37, 52.2, 54.96], "category_id": 3}, {"id": 16, "bbox": [348.44, 164.88, 231.36, 212.8], "category_id": 1}, {"id": 17, "bbox": [2073.74, 4.23, 251.1, 250.85], "category_id": 1}], "caption": "Scheme 3. Proposed new synthetic route to NHE-1 inhibitor 1", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 746, 437, 761], "ImageBB": [82, 767, 787, 1000]}, "reactions": [{"reactants": [16], "conditions": [12, 0], "products": [8]}, {"reactants": [8], "conditions": [5], "products": [7]}, {"reactants": [7, 17], "conditions": [], "products": [1]}, {"reactants": [1], "conditions": [14], "products": [9]}, {"reactants": [9, 10], "conditions": [], "products": [4]}], "diagram_type": "multiple"}, {"id": 439, "width": 2820, "height": 1248, "file_name": "op200334x-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [4.0, 1151.0, 671.0, 80.0], "category_id": 2}, {"id": 1, "bbox": [1235.0, 483.0, 93.0, 91.0], "category_id": 3}, {"id": 2, "bbox": [1717.0, 488.0, 98.0, 82.0], "category_id": 3}, {"id": 3, "bbox": [2322.0, 481.0, 102.0, 75.0], "category_id": 3}, {"id": 4, "bbox": [707.0, 298.0, 306.0, 160.0], "category_id": 2}, {"id": 5, "bbox": [20.0, 640.0, 2800.0, 521.0], "category_id": 4}, {"id": 6, "bbox": [1425.0, 0.0, 578.5, 624.1], "category_id": 1}, {"id": 7, "bbox": [793.21, 221.98, 57.42, 48.92], "category_id": 3}, {"id": 8, "bbox": [732.5, 74.2, 200.5, 157.6], "category_id": 1}, {"id": 9, "bbox": [2024.4, 76.0, 569.0, 544.9], "category_id": 1}, {"id": 10, "bbox": [1037.1, 82.5, 465.0, 539.6], "category_id": 1}, {"id": 11, "bbox": [228.4, 85.0, 454.8, 395.7], "category_id": 1}, {"id": 12, "bbox": [303.0, 402.6, 62.0, 74.8], "category_id": 3}], "reactions": [{"reactants": [11], "conditions": [8, 4], "products": [10, 6, 9]}], "corefs": [[11, 12], [10, 1], [6, 2], [9, 3]], "caption": "Table 1. Catalyst and ligand screening for the cross coupling to 13", "pdf": {"Page": 4, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 460, 110], "ImageBB": [82, 116, 787, 428]}, "diagram_type": "single"}, {"id": 994, "width": 1356, "height": 1296, "file_name": "ja3058138-Scheme-c7.png", "license": 0, "bboxes": [{"id": 0, "bbox": [86.78, 521.16, 262.93, 284.72], "category_id": 1}, {"id": 1, "bbox": [306.15, 4.63, 171.14, 164.92], "category_id": 1}, {"id": 2, "bbox": [374.44, 1203.39, 62.41, 48.84], "category_id": 3}, {"id": 3, "bbox": [863.53, 462.63, 200.11, 80.73], "category_id": 2}, {"id": 4, "bbox": [42.74, 350.71, 133.63, 113.28], "category_id": 1}, {"id": 5, "bbox": [901.51, 1203.39, 71.23, 50.2], "category_id": 3}, {"id": 6, "bbox": [896.09, 240.14, 261.83, 191.97], "category_id": 1}, {"id": 7, "bbox": [822.15, 822.84, 209.6, 81.4], "category_id": 2}, {"id": 8, "bbox": [267.27, 820.12, 173.65, 84.12], "category_id": 2}, {"id": 9, "bbox": [592.0, 153.99, 128.4, 58.21], "category_id": 2}, {"id": 10, "bbox": [453.81, 254.38, 165.51, 75.98], "category_id": 2}, {"id": 11, "bbox": [1132.15, 824.19, 79.36, 50.88], "category_id": 3}, {"id": 12, "bbox": [688.51, 262.52, 179.76, 50.2], "category_id": 2}, {"id": 13, "bbox": [582.02, 1029.05, 158.73, 82.76], "category_id": 2}, {"id": 14, "bbox": [822.15, 4.07, 267.94, 166.2], "category_id": 1}, {"id": 15, "bbox": [248.95, 212.32, 233.35, 195.37], "category_id": 1}, {"id": 16, "bbox": [900.16, 404.97, 72.58, 46.13], "category_id": 3}, {"id": 17, "bbox": [997.84, 556.25, 291.0, 288.97], "category_id": 1}, {"id": 18, "bbox": [1178.95, 366.31, 131.6, 116.0], "category_id": 1}, {"id": 19, "bbox": [268.62, 942.23, 308.65, 252.34], "category_id": 1}, {"id": 20, "bbox": [329.67, 402.94, 63.09, 44.77], "category_id": 3}, {"id": 21, "bbox": [268.62, 459.24, 286.26, 80.73], "category_id": 2}, {"id": 22, "bbox": [582.02, 1193.89, 130.24, 59.7], "category_id": 1}, {"id": 23, "bbox": [764.49, 928.66, 319.5, 269.98], "category_id": 1}, {"id": 24, "bbox": [86.78, 917.9, 110.46, 46.67], "category_id": 2}, {"id": 25, "bbox": [74.33, 844.77, 93.35, 52.9], "category_id": 2}, {"id": 26, "bbox": [233.02, 749.87, 60.68, 49.79], "category_id": 3}], "caption": "Scheme 7. Revised Catalytic Cycle", "pdf": {"Page": 4, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 375, 644, 390], "ImageBB": [448, 396, 787, 720]}, "reactions": [{"reactants": [0, 25], "conditions": [8], "products": [24, 19]}, {"reactants": [19, 22], "conditions": [13], "products": [23]}, {"reactants": [23], "conditions": [7], "products": [17]}, {"reactants": [17], "conditions": [], "products": [6, 18]}, {"reactants": [6, 18], "conditions": [3], "products": [17]}, {"reactants": [6], "conditions": [], "products": [9, 14]}, {"reactants": [9, 14], "conditions": [12], "products": [6]}, {"reactants": [9, 1], "conditions": [], "products": [15]}, {"reactants": [15], "conditions": [10], "products": [1, 9]}, {"reactants": [15, 4], "conditions": [], "products": [0]}, {"reactants": [0], "conditions": [21], "products": [15, 4]}], "diagram_type": "graph"}, {"id": 571, "width": 1356, "height": 1052, "file_name": "acs.orglett.5b00805-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [601.0, 91.0, 324.0, 48.8], "category_id": 2}, {"id": 1, "bbox": [48.7, 39.2, 325.3, 219.8], "category_id": 1}, {"id": 2, "bbox": [392.0, 73.6, 193.0, 109.4], "category_id": 1}, {"id": 3, "bbox": [603.19, 161.78, 254.99, 48.86], "category_id": 2}, {"id": 4, "bbox": [463.0, 266.0, 53.0, 43.0], "category_id": 3}, {"id": 5, "bbox": [152.0, 259.0, 100.0, 45.0], "category_id": 3}, {"id": 6, "bbox": [45.0, 331.0, 1279.0, 691.0], "category_id": 4}, {"id": 7, "bbox": [932.0, 6.0, 378.0, 251.0], "category_id": 1}, {"id": 8, "bbox": [1065.0, 260.0, 114.0, 50.0], "category_id": 3}], "reactions": [{"reactants": [1, 2], "conditions": [0, 3], "products": [7]}], "corefs": [[1, 5], [2, 4], [7, 8]], "caption": "Table 2. Enantioselective Addition of Cumene Hydroperoxide 2a to Various Ketimines 1a,d\u2212m Using 4e ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 401, 777, 431], "ImageBB": [448, 437, 787, 700]}, "diagram_type": "single"}, {"id": 488, "width": 1352, "height": 1140, "file_name": "ol060664z-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [366.8, 8.0, 539.8, 147.3], "category_id": 2}, {"id": 1, "bbox": [948.0, 3.1, 313.9, 240.1], "category_id": 1}, {"id": 2, "bbox": [2.0, 266.1, 1350.0, 868.9], "category_id": 4}, {"id": 3, "bbox": [93.8, 6.0, 266.2, 252.0], "category_id": 1}, {"id": 4, "bbox": [114.0, 214.0, 50.0, 44.0], "category_id": 3}, {"id": 5, "bbox": [568.0, 166.0, 142.0, 57.0], "category_id": 2}, {"id": 6, "bbox": [1072.0, 212.0, 59.0, 48.0], "category_id": 3}], "reactions": [{"reactants": [3], "conditions": [0, 5], "products": [1]}], "corefs": [[3, 4], [1, 6]], "caption": "Table 1. Survey of Amines for Pyrrole Synthesisa", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 75, 706, 89], "ImageBB": [439, 95, 777, 380]}, "diagram_type": "single"}, {"id": 1052, "width": 1120, "height": 344, "file_name": "jo015897c-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [703.71, 45.43, 63.87, 53.84], "category_id": 2}, {"id": 1, "bbox": [563.64, 288.84, 54.91, 52.72], "category_id": 3}, {"id": 2, "bbox": [1055.01, 289.96, 49.86, 51.04], "category_id": 3}, {"id": 3, "bbox": [151.84, 59.45, 133.34, 56.65], "category_id": 2}, {"id": 4, "bbox": [294.71, 5.05, 376.51, 326.98], "category_id": 1}, {"id": 5, "bbox": [834.82, 8.97, 278.46, 319.13], "category_id": 1}, {"id": 6, "bbox": [0.0, 136.85, 39.22, 52.16], "category_id": 3}], "caption": "Scheme 1", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [573, 64, 636, 78], "ImageBB": [469, 83, 749, 169]}, "reactions": [{"reactants": [6], "conditions": [3], "products": [4]}, {"reactants": [4], "conditions": [], "products": [6]}, {"reactants": [4], "conditions": [0], "products": [5]}, {"reactants": [5], "conditions": [], "products": [4]}], "diagram_type": "single"}, {"id": 1177, "width": 1344, "height": 1548, "file_name": "ol300353w-Scheme-c6.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1123.18, 432.88, 126.27, 54.21], "category_id": 2}, {"id": 1, "bbox": [234.71, 790.65, 53.45, 46.46], "category_id": 3}, {"id": 2, "bbox": [941.15, 0.0, 250.98, 161.07], "category_id": 1}, {"id": 3, "bbox": [492.65, 744.96, 296.68, 55.76], "category_id": 2}, {"id": 4, "bbox": [492.65, 144.04, 60.42, 45.68], "category_id": 3}, {"id": 5, "bbox": [492.65, 599.38, 251.75, 114.6], "category_id": 2}, {"id": 6, "bbox": [33.31, 625.7, 453.92, 215.28], "category_id": 1}, {"id": 7, "bbox": [1018.61, 430.56, 61.2, 47.24], "category_id": 3}, {"id": 8, "bbox": [490.33, 806.91, 209.92, 53.43], "category_id": 2}, {"id": 9, "bbox": [49.58, 313.63, 336.95, 164.17], "category_id": 1}, {"id": 10, "bbox": [285.83, 0.0, 371.04, 212.18], "category_id": 1}, {"id": 11, "bbox": [276.17, 971.94, 314.06, 286.18], "category_id": 1}, {"id": 12, "bbox": [680.88, 425.91, 59.65, 49.56], "category_id": 3}, {"id": 13, "bbox": [33.31, 1018.32, 193.65, 197.47], "category_id": 2}, {"id": 14, "bbox": [1022.49, 147.13, 67.39, 44.92], "category_id": 3}, {"id": 15, "bbox": [255.62, 424.36, 61.2, 49.56], "category_id": 3}, {"id": 16, "bbox": [1048.05, 667.52, 245.55, 48.79], "category_id": 2}, {"id": 17, "bbox": [684.76, 992.76, 300.54, 243.94], "category_id": 1}, {"id": 18, "bbox": [766.86, 33.3, 117.74, 54.98], "category_id": 2}, {"id": 19, "bbox": [1048.05, 595.5, 247.1, 122.36], "category_id": 2}, {"id": 20, "bbox": [780.81, 626.48, 250.2, 159.52], "category_id": 1}, {"id": 21, "bbox": [484.91, 313.63, 340.05, 165.72], "category_id": 1}, {"id": 22, "bbox": [941.15, 282.65, 254.07, 159.53], "category_id": 1}, {"id": 23, "bbox": [1018.61, 1034.58, 299.0, 194.37], "category_id": 2}, {"id": 24, "bbox": [1169.66, 933.91, 62.74, 48.79], "category_id": 3}, {"id": 25, "bbox": [1076.71, 763.55, 248.65, 215.28], "category_id": 1}, {"id": 26, "bbox": [876.86, 788.33, 64.29, 48.78], "category_id": 3}], "caption": "Scheme 6. Configurational Assignment of the Syn-Selective Aldol Reaction ", "pdf": {"Page": 3, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 89, 753, 116], "ImageBB": [437, 127, 773, 514]}, "reactions": [{"reactants": [10], "conditions": [18], "products": [2]}, {"reactants": [6], "conditions": [5, 3, 8], "products": [20]}, {"reactants": [20], "conditions": [19, 16], "products": [25]}], "diagram_type": "multiple"}, {"id": 677, "width": 1352, "height": 1588, "file_name": "ol4017244-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [197.0, 631.0, 137.0, 43.0], "category_id": 3}, {"id": 1, "bbox": [957.0, 177.0, 359.0, 195.0], "category_id": 1}, {"id": 2, "bbox": [45.0, 227.0, 333.0, 143.0], "category_id": 1}, {"id": 3, "bbox": [578.0, 162.0, 347.0, 153.0], "category_id": 2}, {"id": 4, "bbox": [405.0, 298.0, 137.0, 48.0], "category_id": 2}, {"id": 5, "bbox": [1083.0, 1535.0, 127.0, 46.0], "category_id": 3}, {"id": 6, "bbox": [623.0, 1540.0, 136.0, 39.0], "category_id": 3}, {"id": 7, "bbox": [198.0, 1528.0, 144.0, 46.0], "category_id": 3}, {"id": 8, "bbox": [1083.0, 1235.0, 142.0, 42.0], "category_id": 3}, {"id": 9, "bbox": [617.0, 1235.0, 160.0, 43.0], "category_id": 3}, {"id": 10, "bbox": [195.0, 1225.0, 157.0, 48.0], "category_id": 3}, {"id": 11, "bbox": [1080.0, 934.0, 132.0, 40.0], "category_id": 3}, {"id": 12, "bbox": [620.0, 937.0, 137.0, 42.0], "category_id": 3}, {"id": 13, "bbox": [498.0, 1341.0, 372.0, 174.0], "category_id": 1}, {"id": 14, "bbox": [41.0, 439.0, 374.0, 193.0], "category_id": 1}, {"id": 15, "bbox": [1089.0, 383.0, 34.0, 37.0], "category_id": 3}, {"id": 16, "bbox": [969.0, 1342.0, 346.0, 174.0], "category_id": 1}, {"id": 17, "bbox": [182.0, 385.0, 29.0, 40.0], "category_id": 3}, {"id": 18, "bbox": [436.0, 382.0, 55.0, 43.0], "category_id": 3}, {"id": 19, "bbox": [195.0, 927.0, 139.0, 43.0], "category_id": 3}, {"id": 20, "bbox": [1083.0, 632.0, 137.0, 48.0], "category_id": 3}, {"id": 21, "bbox": [620.0, 636.0, 140.0, 43.0], "category_id": 3}, {"id": 22, "bbox": [931.0, 1041.0, 381.0, 188.0], "category_id": 1}, {"id": 23, "bbox": [544.0, 1041.0, 322.0, 175.0], "category_id": 1}, {"id": 24, "bbox": [69.0, 1040.0, 348.0, 189.0], "category_id": 1}, {"id": 25, "bbox": [947.0, 738.0, 365.0, 196.0], "category_id": 1}, {"id": 26, "bbox": [554.0, 951.0, 5.0, 9.0], "category_id": 1}, {"id": 27, "bbox": [502.0, 742.0, 365.0, 235.0], "category_id": 1}, {"id": 28, "bbox": [139.0, 1342.0, 278.0, 170.0], "category_id": 1}, {"id": 29, "bbox": [65.0, 739.0, 350.0, 188.0], "category_id": 1}, {"id": 30, "bbox": [964.0, 439.0, 349.0, 187.0], "category_id": 1}, {"id": 31, "bbox": [511.0, 440.0, 353.0, 186.0], "category_id": 1}], "reactions": [{"reactants": [2, 4], "conditions": [3], "products": [1]}], "corefs": [[2, 17], [4, 18], [1, 15], [14, 0], [31, 21], [30, 20], [29, 19], [27, 12], [25, 11], [24, 10], [23, 9], [22, 8], [28, 7], [13, 6], [16, 5]], "caption": "Figure 1. Scope of aryl diazonium salts. Reaction conditions: All reactions were performed with 1 (0.2 mmol) and 2a (3 equiv), in 0.4 mL of H2O and 1.0 mL of acetone at 0 \u00b0C, in Ar, for 20 min; isolated yields of 3. aThe reaction was performed with 5 equiv of 2a. ", "pdf": {"Page": 3, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [71, 709, 405, 764], "ImageBB": [71, 300, 409, 697]}, "diagram_type": "single"}, {"id": 64, "width": 1348, "height": 1816, "file_name": "ja312277g-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [938.11, 125.68, 27.62, 35.5], "category_id": 3}, {"id": 1, "bbox": [0.47, 199.1, 1340.33, 1614.65], "category_id": 4}, {"id": 2, "bbox": [394.26, 88.24, 317.27, 86.73], "category_id": 2}, {"id": 3, "bbox": [549.93, 7.45, 135.99, 45.35], "category_id": 2}, {"id": 4, "bbox": [209.03, 127.65, 23.68, 35.5], "category_id": 3}, {"id": 5, "bbox": [802.15, 19.27, 254.22, 100.53], "category_id": 1}, {"id": 6, "bbox": [433.67, 1.54, 94.61, 49.29], "category_id": 1}, {"id": 7, "bbox": [102.62, 23.21, 193.14, 98.56], "category_id": 1}], "reactions": [{"reactants": [7], "conditions": [6, 3, 2], "products": [5]}], "corefs": [[7, 4], [5, 0]], "caption": "Table 1. Alkylation of \u03b3-C(sp3)\u2212H Bonds with EtI", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 405, 735, 425], "ImageBB": [449, 431, 786, 885]}, "diagram_type": "single"}, {"id": 138, "width": 1340, "height": 2044, "file_name": "op800177x-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [266.2, 1424.9, 816.2, 500.1], "category_id": 1}, {"id": 1, "bbox": [124.3, 91.6, 470.0, 383.0], "category_id": 1}, {"id": 2, "bbox": [875.37, 89.2, 457.5, 385.8], "category_id": 1}, {"id": 3, "bbox": [140.9, 734.3, 454.3, 376.0], "category_id": 1}, {"id": 4, "bbox": [341.0, 1125.0, 89.0, 67.0], "category_id": 3}, {"id": 5, "bbox": [870.6, 736.4, 467.8, 375.5], "category_id": 1}, {"id": 6, "bbox": [352.0, 1970.0, 572.0, 74.0], "category_id": 3}, {"id": 7, "bbox": [33.0, 1286.0, 1245.0, 74.0], "category_id": 4}, {"id": 8, "bbox": [341.2, 488.0, 66.8, 58.0], "category_id": 3}, {"id": 9, "bbox": [1091.1, 484.0, 75.4, 64.4], "category_id": 3}, {"id": 10, "bbox": [1088.3, 1129.1, 72.7, 58.9], "category_id": 3}], "reactions": [{"reactants": [1], "conditions": [], "products": [2]}, {"reactants": [3], "conditions": [], "products": [5]}], "corefs": [[1, 8], [2, 9], [3, 4], [5, 10], [0, 6]], "caption": "Figure 1. Structure of the hydrogenation catalyst RuCl2[(S)- Xyl-P-Phos][(S)-DAIPEN] 9. ", "pdf": {"Page": 2, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 559, 393, 586], "ImageBB": [59, 45, 394, 556]}, "diagram_type": "multiple"}, {"id": 469, "width": 1352, "height": 792, "file_name": "op100205s-Table-c5.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1072.0, 290.0, 25.0, 38.0], "category_id": 3}, {"id": 1, "bbox": [1.0, 0.0, 513.0, 335.0], "category_id": 1}, {"id": 2, "bbox": [772.0, 0.0, 580.0, 338.0], "category_id": 1}, {"id": 3, "bbox": [331.0, 415.0, 567.0, 335.0], "category_id": 1}, {"id": 4, "bbox": [270.0, 289.0, 68.0, 44.0], "category_id": 3}, {"id": 5, "bbox": [624.0, 704.0, 45.0, 41.0], "category_id": 3}, {"id": 6, "bbox": [530.3, 95.0, 193.7, 79.0], "category_id": 2}], "reactions": [{"reactants": [1], "conditions": [6], "products": [2]}], "corefs": [[1, 4], [2, 0], [3, 5]], "caption": "Table 5. Solubility of 4 in common solvents at 20 \u00b0C", "pdf": {"Page": 8, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 455, 348, 473], "ImageBB": [58, 249, 396, 447]}, "diagram_type": "multiple"}, {"id": 120, "width": 1412, "height": 2840, "file_name": "op9701245-Table-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [817.0, 1962.0, 42.0, 43.0], "category_id": 3}, {"id": 1, "bbox": [1251.0, 1251.0, 46.0, 37.0], "category_id": 3}, {"id": 2, "bbox": [617.0, 1316.0, 45.0, 44.0], "category_id": 3}, {"id": 3, "bbox": [1252.0, 915.0, 50.0, 48.0], "category_id": 3}, {"id": 4, "bbox": [6.0, 9.0, 1402.0, 506.0], "category_id": 4}, {"id": 5, "bbox": [1010.0, 2211.0, 339.0, 544.0], "category_id": 1}, {"id": 6, "bbox": [1017.0, 1730.0, 226.0, 170.0], "category_id": 2}, {"id": 7, "bbox": [420.0, 2046.0, 96.0, 56.0], "category_id": 2}, {"id": 8, "bbox": [378.0, 1000.0, 418.0, 237.0], "category_id": 1}, {"id": 9, "bbox": [1098.0, 1013.0, 314.0, 227.0], "category_id": 1}, {"id": 10, "bbox": [700.0, 2533.0, 299.0, 44.0], "category_id": 2}, {"id": 11, "bbox": [685.0, 2381.0, 251.0, 55.0], "category_id": 2}, {"id": 12, "bbox": [693.0, 2439.0, 106.0, 39.0], "category_id": 2}, {"id": 13, "bbox": [3.0, 1634.0, 471.0, 85.0], "category_id": 2}, {"id": 14, "bbox": [0.0, 1728.0, 391.0, 219.0], "category_id": 1}, {"id": 15, "bbox": [575.0, 1742.0, 407.0, 210.0], "category_id": 1}, {"id": 16, "bbox": [1031.0, 1905.0, 285.0, 219.0], "category_id": 2}, {"id": 17, "bbox": [420.0, 1905.0, 209.0, 99.0], "category_id": 2}, {"id": 18, "bbox": [382.0, 1794.0, 256.0, 92.0], "category_id": 2}, {"id": 19, "bbox": [1229.0, 2715.0, 28.0, 44.0], "category_id": 3}, {"id": 20, "bbox": [427.0, 2792.0, 42.0, 48.0], "category_id": 3}, {"id": 21, "bbox": [234.0, 1965.0, 38.0, 42.0], "category_id": 3}, {"id": 22, "bbox": [271.3, 2230.0, 310.7, 541.4], "category_id": 1}, {"id": 23, "bbox": [1095.0, 1365.0, 317.0, 238.4], "category_id": 1}, {"id": 24, "bbox": [1022.0, 662.0, 390.0, 239.5], "category_id": 1}], "reactions": [{"reactants": [8], "conditions": [], "products": [24, 9]}, {"reactants": [9], "conditions": [], "products": [23]}, {"reactants": [14], "conditions": [18, 17, 7], "products": [15]}, {"reactants": [15], "conditions": [6, 16], "products": [22]}, {"reactants": [22], "conditions": [11, 12, 10], "products": [5]}], "corefs": [[8, 2], [24, 3], [9, 1], [14, 21], [15, 0], [22, 20], [5, 19]], "caption": "Table 4. Pancreatin resolution screenings", "pdf": {"Page": 5, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 53, 306, 67], "ImageBB": [74, 70, 427, 780]}, "diagram_type": "tree"}, {"id": 145, "width": 1348, "height": 1320, "file_name": "op700249f-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1.0, 709.0, 1347.0, 611.0], "category_id": 4}, {"id": 1, "bbox": [838.4, 111.8, 509.6, 215.7], "category_id": 1}, {"id": 2, "bbox": [875.0, 356.0, 400.3, 112.2], "category_id": 4}, {"id": 3, "bbox": [13.0, 390.4, 810.7, 318.3], "category_id": 4}, {"id": 4, "bbox": [20.3, 109.9, 359.2, 208.4], "category_id": 1}, {"id": 5, "bbox": [383.0, 1.0, 499.0, 203.6], "category_id": 2}, {"id": 6, "bbox": [387.0, 242.0, 458.0, 242.6], "category_id": 2}], "reactions": [{"reactants": [4], "conditions": [5, 6], "products": [1]}], "corefs": [], "caption": "Table 3. Chemical and chemoenzymatic coupling", "pdf": {"Page": 4, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [425, 178, 696, 192], "ImageBB": [425, 193, 762, 523]}, "diagram_type": "single"}, {"id": 14, "width": 1032, "height": 2828, "file_name": "ja980022+-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [101.2, 296.53, 220.21, 223.73], "category_id": 1}, {"id": 1, "bbox": [6.17, 4.41, 348.68, 234.29], "category_id": 1}, {"id": 2, "bbox": [365.81, 161.2, 141.55, 83.13], "category_id": 2}, {"id": 3, "bbox": [391.77, 287.22, 90.17, 40.4], "category_id": 2}, {"id": 4, "bbox": [813.12, 368.35, 55.54, 40.95], "category_id": 3}, {"id": 5, "bbox": [130.53, 477.07, 53.92, 43.11], "category_id": 3}, {"id": 6, "bbox": [6.94, 523.28, 1012.79, 2293.59], "category_id": 4}, {"id": 7, "bbox": [592.17, 87.12, 420.82, 297.64], "category_id": 1}, {"id": 8, "bbox": [187.86, 197.98, 116.67, 49.05], "category_id": 3}], "reactions": [{"reactants": [1, 0], "conditions": [2, 3], "products": [7]}], "corefs": [[1, 8], [0, 5], [7, 4]], "caption": "Table 1. [3 + 4] Annulation of (E)-11 With Ketone Enolates", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 61, 384, 77], "ImageBB": [114, 80, 372, 787]}, "diagram_type": "single"}, {"id": 1352, "width": 900, "height": 1660, "file_name": "op800136f-Scheme-c11.png", "license": 0, "bboxes": [{"id": 0, "bbox": [296.34, 803.84, 303.81, 151.97], "category_id": 2}, {"id": 1, "bbox": [240.34, 855.78, 34.22, 47.06], "category_id": 3}, {"id": 2, "bbox": [454.89, 1605.19, 278.07, 54.81], "category_id": 2}, {"id": 3, "bbox": [553.67, 621.15, 260.64, 87.19], "category_id": 2}, {"id": 4, "bbox": [0.0, 460.88, 553.67, 278.19], "category_id": 1}, {"id": 5, "bbox": [10.79, 0.0, 558.65, 215.91], "category_id": 1}, {"id": 6, "bbox": [791.07, 1074.56, 46.48, 55.64], "category_id": 3}, {"id": 7, "bbox": [10.79, 1376.83, 889.21, 220.06], "category_id": 1}, {"id": 8, "bbox": [0.0, 1655.02, 10.79, 4.98], "category_id": 2}, {"id": 9, "bbox": [575.25, 538.11, 212.5, 58.96], "category_id": 2}, {"id": 10, "bbox": [248.19, 180.2, 56.45, 67.26], "category_id": 3}, {"id": 11, "bbox": [244.87, 1189.98, 98.78, 55.64], "category_id": 3}, {"id": 12, "bbox": [850.01, 584.61, 49.99, 50.66], "category_id": 2}, {"id": 13, "bbox": [10.79, 969.92, 640.83, 262.42], "category_id": 1}, {"id": 14, "bbox": [296.34, 1271.37, 72.22, 58.12], "category_id": 3}, {"id": 15, "bbox": [0.0, 1655.02, 0.83, 4.98], "category_id": 2}, {"id": 16, "bbox": [283.5, 329.67, 199.61, 62.29], "category_id": 2}, {"id": 17, "bbox": [244.87, 726.61, 73.88, 55.64], "category_id": 3}], "caption": "Scheme 11", "pdf": {"Page": 6, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 46, 126, 60], "ImageBB": [186, 65, 411, 480]}, "reactions": [{"reactants": [5], "conditions": [16], "products": [4]}, {"reactants": [4], "conditions": [], "products": [5]}, {"reactants": [4], "conditions": [9, 3], "products": [12]}, {"reactants": [4], "conditions": [1, 0], "products": [13]}, {"reactants": [13, 6], "conditions": [14], "products": [7]}], "diagram_type": "tree"}, {"id": 472, "width": 2232, "height": 1432, "file_name": "op100113j-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [717.0, 411.0, 501.0, 294.0], "category_id": 1}, {"id": 1, "bbox": [963.0, 0.0, 399.0, 306.0], "category_id": 1}, {"id": 2, "bbox": [1650.0, 18.0, 381.0, 303.0], "category_id": 1}, {"id": 3, "bbox": [1524.0, 414.0, 522.0, 288.0], "category_id": 1}, {"id": 4, "bbox": [0.0, 417.0, 510.0, 297.0], "category_id": 1}, {"id": 5, "bbox": [0.0, 819.0, 396.0, 321.0], "category_id": 1}, {"id": 6, "bbox": [417.0, 834.0, 546.0, 213.0], "category_id": 1}, {"id": 7, "bbox": [1089.0, 1230.0, 996.0, 202.0], "category_id": 2}, {"id": 8, "bbox": [750.0, 216.0, 138.0, 49.0], "category_id": 2}, {"id": 9, "bbox": [1394.0, 202.0, 134.0, 50.0], "category_id": 2}, {"id": 10, "bbox": [1307.0, 556.0, 131.0, 59.0], "category_id": 2}, {"id": 11, "bbox": [540.0, 558.0, 133.0, 52.0], "category_id": 2}, {"id": 12, "bbox": [2066.0, 214.0, 126.0, 54.0], "category_id": 2}, {"id": 13, "bbox": [2074.0, 558.0, 121.0, 51.0], "category_id": 2}, {"id": 14, "bbox": [613.0, 1108.0, 127.0, 46.0], "category_id": 2}, {"id": 15, "bbox": [157.0, 298.0, 30.0, 39.0], "category_id": 3}, {"id": 16, "bbox": [136.0, 693.0, 35.0, 42.0], "category_id": 3}, {"id": 17, "bbox": [493.0, 297.0, 38.0, 39.0], "category_id": 3}, {"id": 18, "bbox": [1071.0, 298.0, 34.0, 41.0], "category_id": 3}, {"id": 19, "bbox": [865.0, 697.0, 39.0, 41.0], "category_id": 3}, {"id": 20, "bbox": [1775.0, 288.0, 33.0, 44.0], "category_id": 3}, {"id": 21, "bbox": [147.0, 1131.0, 34.0, 42.0], "category_id": 3}, {"id": 22, "bbox": [685.0, 1020.0, 38.0, 45.0], "category_id": 3}, {"id": 23, "bbox": [1646.0, 688.0, 32.0, 39.0], "category_id": 3}, {"id": 24, "bbox": [1103.0, 840.4, 665.1, 295.2], "category_id": 1}, {"id": 25, "bbox": [440.3, 56.5, 241.8, 217.0], "category_id": 1}, {"id": 26, "bbox": [39.0, 45.0, 252.5, 229.1], "category_id": 1}], "reactions": [{"reactants": [26, 25], "conditions": [8], "products": [1]}, {"reactants": [1], "conditions": [9], "products": [2]}, {"reactants": [2], "conditions": [12], "products": [4]}, {"reactants": [4], "conditions": [11], "products": [0]}, {"reactants": [0], "conditions": [10], "products": [3]}, {"reactants": [3], "conditions": [13], "products": [5]}, {"reactants": [5], "conditions": [6, 14], "products": [24]}], "corefs": [[26, 15], [25, 17], [1, 18], [2, 20], [4, 16], [0, 19], [3, 23], [5, 21], [6, 22]], "caption": "Table 1. Comparison of original and modified reaction conditions and pilot-plant performance", "pdf": {"Page": 2, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 434, 577, 448], "ImageBB": [131, 65, 689, 423]}, "diagram_type": "multiple"}, {"id": 1134, "width": 1352, "height": 940, "file_name": "ol006192k-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [683.78, 455.07, 56.13, 50.04], "category_id": 2}, {"id": 1, "bbox": [1138.95, 355.0, 40.58, 44.63], "category_id": 3}, {"id": 2, "bbox": [1018.57, 0.0, 325.31, 331.33], "category_id": 1}, {"id": 3, "bbox": [611.41, 819.54, 35.17, 40.57], "category_id": 3}, {"id": 4, "bbox": [522.81, 533.51, 305.03, 333.36], "category_id": 1}, {"id": 5, "bbox": [865.04, 107.51, 114.97, 42.6], "category_id": 2}, {"id": 6, "bbox": [522.13, 0.0, 303.0, 332.68], "category_id": 1}, {"id": 7, "bbox": [108.21, 356.35, 38.56, 38.54], "category_id": 3}, {"id": 8, "bbox": [8.12, 529.45, 354.4, 337.42], "category_id": 1}, {"id": 9, "bbox": [376.04, 632.23, 132.57, 48.01], "category_id": 2}, {"id": 10, "bbox": [586.39, 357.7, 165.02, 85.88], "category_id": 3}, {"id": 11, "bbox": [8.79, 0.0, 346.96, 327.95], "category_id": 1}, {"id": 12, "bbox": [865.04, 165.67, 102.8, 39.21], "category_id": 2}, {"id": 13, "bbox": [1100.4, 294.82, 75.08, 45.3], "category_id": 2}, {"id": 14, "bbox": [89.28, 306.31, 80.48, 41.25], "category_id": 2}, {"id": 15, "bbox": [128.5, 817.51, 32.47, 42.6], "category_id": 3}, {"id": 16, "bbox": [966.49, 477.39, 119.03, 52.06], "category_id": 2}, {"id": 17, "bbox": [375.37, 100.08, 138.65, 43.95], "category_id": 2}, {"id": 18, "bbox": [403.1, 160.93, 102.12, 39.22], "category_id": 2}], "caption": "Scheme 1", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [212, 136, 265, 149], "ImageBB": [73, 156, 411, 391]}, "reactions": [{"reactants": [6], "conditions": [17, 18], "products": [11]}, {"reactants": [6], "conditions": [5, 12], "products": [2]}, {"reactants": [6], "conditions": [0], "products": [4]}, {"reactants": [4], "conditions": [9], "products": [8]}, {"reactants": [8], "conditions": [], "products": [11]}, {"reactants": [4], "conditions": [16], "products": [2]}], "diagram_type": "graph"}, {"id": 43, "width": 1352, "height": 1400, "file_name": "ja501560x-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [407.87, 49.12, 393.93, 84.03], "category_id": 2}, {"id": 1, "bbox": [159.95, 16.31, 249.92, 260.85], "category_id": 1}, {"id": 2, "bbox": [808.91, 7.19, 244.45, 279.09], "category_id": 1}, {"id": 3, "bbox": [1200.84, 65.53, 136.89, 160.59], "category_id": 1}, {"id": 4, "bbox": [515.42, 162.14, 127.78, 82.21], "category_id": 2}, {"id": 5, "bbox": [1064.12, 96.5, 109.55, 42.12], "category_id": 2}, {"id": 6, "bbox": [59.69, 280.63, 54.87, 42.1], "category_id": 3}, {"id": 7, "bbox": [259.11, 281.09, 52.55, 40.09], "category_id": 3}, {"id": 8, "bbox": [911.69, 281.95, 49.99, 37.91], "category_id": 3}, {"id": 9, "bbox": [1247.32, 281.65, 52.05, 37.92], "category_id": 3}, {"id": 10, "bbox": [3.18, 344.43, 1343.67, 1052.0], "category_id": 4}, {"id": 11, "bbox": [15.94, 129.33, 98.62, 34.87], "category_id": 1}], "reactions": [{"reactants": [11, 1], "conditions": [0, 4], "products": [2]}, {"reactants": [2], "conditions": [5], "products": [3]}], "corefs": [[11, 6], [1, 7], [2, 8], [3, 9]], "caption": "Table 1. Pd-Catalyzed Arylation of Imine 2aa", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 303, 706, 325], "ImageBB": [448, 330, 786, 680]}, "diagram_type": "single"}, {"id": 693, "width": 1384, "height": 624, "file_name": "ol050791f-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [443.7, 15.3, 144.8, 197.0], "category_id": 1}, {"id": 1, "bbox": [711.0, 142.0, 255.0, 85.0], "category_id": 2}, {"id": 2, "bbox": [744.0, 21.0, 183.0, 91.0], "category_id": 2}, {"id": 3, "bbox": [1152.0, 212.0, 45.0, 44.0], "category_id": 3}, {"id": 4, "bbox": [7.0, 279.0, 1364.0, 345.0], "category_id": 4}, {"id": 5, "bbox": [157.0, 217.0, 73.0, 41.0], "category_id": 3}, {"id": 6, "bbox": [1067.5, 0.0, 315.5, 226.5], "category_id": 1}, {"id": 7, "bbox": [76.4, 26.4, 247.0, 174.1], "category_id": 1}], "reactions": [{"reactants": [7, 0], "conditions": [2, 1], "products": [6]}], "corefs": [[7, 5], [6, 3]], "caption": "Table 2. Preparation of Fluorinated \u03b3-Amino Alcohols 2 from Aldimines 1 and Other Aldehydes ", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 76, 403, 105], "ImageBB": [74, 109, 420, 265]}, "diagram_type": "single"}, {"id": 131, "width": 1352, "height": 1800, "file_name": "op900102a-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [356.0, 24.0, 107.0, 52.0], "category_id": 2}, {"id": 1, "bbox": [88.0, 8.0, 214.0, 155.0], "category_id": 1}, {"id": 2, "bbox": [539.0, 6.0, 194.0, 162.0], "category_id": 1}, {"id": 3, "bbox": [1058.0, 10.0, 195.0, 158.0], "category_id": 1}, {"id": 4, "bbox": [794.0, 26.0, 179.0, 48.0], "category_id": 2}, {"id": 5, "bbox": [768.0, 93.0, 234.0, 46.0], "category_id": 2}, {"id": 6, "bbox": [330.0, 93.0, 163.0, 44.0], "category_id": 2}, {"id": 7, "bbox": [59.0, 1494.0, 1293.0, 306.0], "category_id": 2}, {"id": 8, "bbox": [5.0, 205.0, 1335.0, 1217.0], "category_id": 4}], "reactions": [{"reactants": [1], "conditions": [0, 6], "products": [2]}, {"reactants": [2], "conditions": [4, 5], "products": [3]}], "corefs": [], "caption": "Table 2. Activation and functionalization of silica to S1x", "pdf": {"Page": 2, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 462, 370, 476], "ImageBB": [58, 487, 396, 937]}, "diagram_type": "single"}, {"id": 461, "width": 1264, "height": 1496, "file_name": "op200011x-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [691.0, 58.0, 266.0, 233.9], "category_id": 1}, {"id": 1, "bbox": [998.0, 54.1, 248.0, 262.8], "category_id": 1}, {"id": 2, "bbox": [695.98, 249.0, 44.0, 54.0], "category_id": 3}, {"id": 3, "bbox": [348.99, 161.02, 261.91, 52.98], "category_id": 2}, {"id": 4, "bbox": [370.2, 3.0, 246.7, 131.9], "category_id": 1}, {"id": 5, "bbox": [37.0, 59.0, 246.0, 199.9], "category_id": 1}, {"id": 6, "bbox": [329.0, 101.0, 35.0, 52.0], "category_id": 3}, {"id": 7, "bbox": [1001.0, 244.0, 50.0, 67.0], "category_id": 3}, {"id": 8, "bbox": [6.0, 422.0, 1258.0, 1074.0], "category_id": 4}], "reactions": [{"reactants": [5], "conditions": [4, 3], "products": [0, 1]}], "corefs": [[4, 6], [0, 2], [1, 7]], "caption": "Table 2", "pdf": {"Page": 2, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [437, 92, 481, 107], "ImageBB": [444, 131, 760, 505]}, "diagram_type": "single"}, {"id": 508, "width": 1352, "height": 1116, "file_name": "ol051901l-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1011.5, 1.0, 265.0, 220.5], "category_id": 1}, {"id": 1, "bbox": [435.0, 29.0, 271.5, 67.8], "category_id": 2}, {"id": 2, "bbox": [71.0, 52.5, 269.0, 163.5], "category_id": 1}, {"id": 3, "bbox": [755.0, 153.5, 205.5, 51.5], "category_id": 2}, {"id": 4, "bbox": [532.0, 258.0, 44.0, 44.0], "category_id": 3}, {"id": 5, "bbox": [188.0, 225.0, 38.0, 48.0], "category_id": 3}, {"id": 6, "bbox": [8.0, 368.0, 1344.0, 731.0], "category_id": 4}, {"id": 7, "bbox": [415.0, 196.0, 322.0, 60.0], "category_id": 2}, {"id": 8, "bbox": [530.83, 94.3, 46.37, 46.38], "category_id": 3}, {"id": 9, "bbox": [1037.0, 240.0, 205.0, 93.0], "category_id": 3}], "reactions": [{"reactants": [2, 1], "conditions": [3], "products": [0]}, {"reactants": [2, 7], "conditions": [3], "products": [0]}], "corefs": [[2, 5], [1, 8], [7, 4], [0, 9]], "caption": "Table 2. Cyclization of Amidine 3 with Acetal 5 or 7a", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 210, 364, 224], "ImageBB": [73, 233, 411, 512]}, "diagram_type": "single"}, {"id": 248, "width": 1348, "height": 1128, "file_name": "ol9005079-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [691.0, 118.0, 154.0, 83.0], "category_id": 2}, {"id": 1, "bbox": [717.0, 42.0, 82.0, 50.0], "category_id": 2}, {"id": 2, "bbox": [567.0, 181.0, 60.0, 43.0], "category_id": 3}, {"id": 3, "bbox": [153.0, 181.0, 65.0, 41.0], "category_id": 3}, {"id": 4, "bbox": [1048.0, 179.0, 76.0, 43.0], "category_id": 3}, {"id": 5, "bbox": [22.0, 253.0, 1311.0, 875.0], "category_id": 4}, {"id": 6, "bbox": [860.0, 0.0, 379.0, 199.0], "category_id": 1}, {"id": 7, "bbox": [116.0, 16.0, 199.5, 163.0], "category_id": 1}, {"id": 8, "bbox": [396.3, 0.0, 259.7, 200.0], "category_id": 1}], "reactions": [{"reactants": [7, 8], "conditions": [1, 0], "products": [6]}], "corefs": [[7, 3], [8, 2], [6, 4]], "caption": "Table 1. Optimization of the Reaction Parametersa", "pdf": {"Page": 2, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [425, 73, 688, 88], "ImageBB": [425, 97, 762, 379]}, "diagram_type": "single"}, {"id": 924, "width": 1352, "height": 1008, "file_name": "acs.joc.5b02382-Scheme-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [100.1, 412.5, 65.6, 48.69], "category_id": 3}, {"id": 1, "bbox": [292.18, 757.37, 264.45, 111.58], "category_id": 1}, {"id": 2, "bbox": [406.48, 411.82, 60.19, 48.01], "category_id": 3}, {"id": 3, "bbox": [585.71, 105.49, 240.78, 84.53], "category_id": 2}, {"id": 4, "bbox": [672.28, 690.43, 165.03, 38.54], "category_id": 2}, {"id": 5, "bbox": [909.0, 6.09, 358.46, 116.31], "category_id": 1}, {"id": 6, "bbox": [998.95, 920.34, 165.03, 43.28], "category_id": 2}, {"id": 7, "bbox": [42.61, 259.67, 147.44, 152.83], "category_id": 1}, {"id": 8, "bbox": [401.07, 862.86, 35.84, 42.61], "category_id": 3}, {"id": 9, "bbox": [1038.86, 871.65, 58.16, 39.9], "category_id": 3}, {"id": 10, "bbox": [0.0, 48.69, 214.4, 114.28], "category_id": 1}, {"id": 11, "bbox": [388.89, 111.58, 36.53, 39.89], "category_id": 3}, {"id": 12, "bbox": [100.1, 449.69, 472.08, 244.12], "category_id": 1}, {"id": 13, "bbox": [148.79, 204.9, 197.5, 44.63], "category_id": 2}, {"id": 14, "bbox": [77.78, 891.27, 53.43, 40.57], "category_id": 3}, {"id": 15, "bbox": [601.94, 452.39, 281.36, 242.77], "category_id": 1}, {"id": 16, "bbox": [894.8, 454.42, 290.14, 240.06], "category_id": 1}, {"id": 17, "bbox": [553.24, 29.08, 280.68, 48.01], "category_id": 2}, {"id": 18, "bbox": [568.8, 778.34, 275.95, 53.42], "category_id": 2}, {"id": 19, "bbox": [325.32, 284.69, 212.37, 108.87], "category_id": 1}, {"id": 20, "bbox": [29.08, 600.49, 74.4, 43.95], "category_id": 2}, {"id": 21, "bbox": [710.16, 302.95, 300.97, 46.45], "category_id": 2}, {"id": 22, "bbox": [77.78, 140.65, 39.23, 37.2], "category_id": 3}, {"id": 23, "bbox": [12.85, 797.27, 213.05, 117.66], "category_id": 1}, {"id": 24, "bbox": [440.3, 191.37, 75.07, 48.69], "category_id": 2}, {"id": 25, "bbox": [912.38, 754.67, 366.58, 120.37], "category_id": 1}, {"id": 26, "bbox": [1034.8, 121.04, 50.05, 37.2], "category_id": 3}, {"id": 27, "bbox": [1122.05, 147.42, 202.9, 78.44], "category_id": 2}, {"id": 28, "bbox": [284.06, 12.17, 259.72, 102.79], "category_id": 1}], "caption": "Scheme 2. Unexpected Zn(OTf)2-catalyzed cycloisomerization/allylic alkylation cascade to synthesize oxazoles ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 406, 140], "ImageBB": [82, 146, 420, 398]}, "reactions": [{"reactants": [10, 28], "conditions": [17, 3], "products": [5]}, {"reactants": [10], "conditions": [13], "products": [7]}, {"reactants": [28], "conditions": [24], "products": [19]}, {"reactants": [7, 19], "conditions": [21, 27], "products": [5]}, {"reactants": [23, 1], "conditions": [18], "products": [25]}], "diagram_type": "graph"}, {"id": 1059, "width": 1344, "height": 1092, "file_name": "jo201098c-Scheme-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [412.81, 338.2, 125.73, 157.4], "category_id": 2}, {"id": 1, "bbox": [747.64, 465.28, 387.94, 50.43], "category_id": 3}, {"id": 2, "bbox": [512.99, 175.49, 97.49, 53.12], "category_id": 2}, {"id": 3, "bbox": [172.12, 543.28, 481.39, 447.8], "category_id": 1}, {"id": 4, "bbox": [685.11, 548.66, 480.72, 444.44], "category_id": 1}, {"id": 5, "bbox": [278.35, 355.69, 116.98, 54.46], "category_id": 2}, {"id": 6, "bbox": [907.65, 996.46, 54.46, 46.39], "category_id": 3}, {"id": 7, "bbox": [665.61, 4.03, 508.96, 443.1], "category_id": 1}, {"id": 8, "bbox": [527.78, 316.69, 143.21, 51.77], "category_id": 2}, {"id": 9, "bbox": [394.66, 998.48, 42.36, 44.37], "category_id": 3}, {"id": 10, "bbox": [394.66, 203.73, 40.34, 49.76], "category_id": 3}], "caption": "Scheme 2", "pdf": {"Page": 2, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [71, 417, 127, 432], "ImageBB": [71, 442, 407, 715]}, "reactions": [{"reactants": [10], "conditions": [2], "products": [7]}, {"reactants": [10], "conditions": [8], "products": [4]}, {"reactants": [10], "conditions": [0, 5], "products": [3]}], "diagram_type": "tree"}, {"id": 898, "width": 1348, "height": 448, "file_name": "acs.joc.6b01001-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [511.0, 4.0, 358.0, 147.0], "category_id": 2}, {"id": 1, "bbox": [1090.0, 305.0, 58.0, 48.0], "category_id": 3}, {"id": 2, "bbox": [521.0, 177.0, 335.0, 95.0], "category_id": 2}, {"id": 3, "bbox": [222.0, 305.0, 58.0, 45.0], "category_id": 3}, {"id": 4, "bbox": [95.3, 126.2, 317.7, 77.8], "category_id": 1}, {"id": 5, "bbox": [6.8, 373.0, 1341.2, 75.0], "category_id": 4}, {"id": 6, "bbox": [982.2, 79.1, 269.4, 169.8], "category_id": 1}], "reactions": [{"reactants": [4], "conditions": [0, 2], "products": [6]}], "corefs": [[4, 3], [6, 1]], "caption": "Table 1. Optimization of Reaction Parameters for the Sultone Formationa ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 375, 392, 405], "ImageBB": [82, 412, 419, 524]}, "diagram_type": "single"}, {"id": 765, "width": 1356, "height": 812, "file_name": "jo961049j-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [559.0, 231.0, 213.0, 46.0], "category_id": 2}, {"id": 1, "bbox": [5.0, 472.0, 1331.0, 340.0], "category_id": 4}, {"id": 2, "bbox": [912.0, 66.0, 397.0, 333.0], "category_id": 1}, {"id": 3, "bbox": [40.0, 6.0, 453.0, 402.0], "category_id": 1}, {"id": 4, "bbox": [202.0, 405.0, 129.0, 45.0], "category_id": 3}, {"id": 5, "bbox": [1025.0, 405.0, 131.0, 49.0], "category_id": 3}, {"id": 6, "bbox": [614.0, 110.0, 97.0, 50.0], "category_id": 2}, {"id": 7, "bbox": [512.0, 160.0, 305.0, 48.0], "category_id": 2}, {"id": 8, "bbox": [588.0, 282.0, 155.0, 41.0], "category_id": 2}], "reactions": [{"reactants": [3], "conditions": [6, 7, 0, 8], "products": [2]}], "corefs": [[3, 4], [2, 5]], "caption": "Table 2. Tandem Enyne Allene-Radical Cyclization of                 Substrates 84-88 ", "pdf": {"Page": 11, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [79, 49, 402, 74], "ImageBB": [73, 76, 412, 279]}, "diagram_type": "single"}, {"id": 1265, "width": 1012, "height": 2308, "file_name": "op050193g-Scheme-c5.png", "license": 0, "bboxes": [{"id": 0, "bbox": [489.95, 1711.08, 513.06, 513.79], "category_id": 1}, {"id": 1, "bbox": [511.9, 2249.12, 476.09, 58.88], "category_id": 2}, {"id": 2, "bbox": [62.4, 1070.29, 108.62, 56.58], "category_id": 2}, {"id": 3, "bbox": [82.07, 1812.1, 293.69, 324.17], "category_id": 1}, {"id": 4, "bbox": [0.0, 18.47, 420.62, 424.89], "category_id": 1}, {"id": 5, "bbox": [630.92, 804.74, 287.73, 282.87], "category_id": 1}, {"id": 6, "bbox": [119.02, 810.51, 287.73, 280.57], "category_id": 1}, {"id": 7, "bbox": [340.88, 1371.64, 347.82, 117.76], "category_id": 2}, {"id": 8, "bbox": [734.92, 1481.32, 139.82, 63.5], "category_id": 2}, {"id": 9, "bbox": [852.79, 1067.98, 157.15, 64.66], "category_id": 2}, {"id": 10, "bbox": [84.35, 2161.37, 271.56, 53.11], "category_id": 2}, {"id": 11, "bbox": [157.15, 1480.17, 132.89, 62.35], "category_id": 2}, {"id": 12, "bbox": [581.24, 0.0, 429.86, 447.98], "category_id": 1}], "caption": "Scheme 5", "pdf": {"Page": 9, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 53, 135, 67], "ImageBB": [117, 71, 370, 648]}, "reactions": [{"reactants": [4, 6], "conditions": [], "products": [5, 12]}, {"reactants": [5, 8], "conditions": [7], "products": [6, 11]}], "diagram_type": "graph"}, {"id": 639, "width": 1292, "height": 2572, "file_name": "ol501019y-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [349.0, 14.0, 374.0, 58.0], "category_id": 2}, {"id": 1, "bbox": [143.0, 3.0, 177.0, 125.0], "category_id": 1}, {"id": 2, "bbox": [762.0, 2.0, 389.0, 121.0], "category_id": 1}, {"id": 3, "bbox": [386.0, 83.0, 289.0, 92.0], "category_id": 2}, {"id": 4, "bbox": [14.0, 204.0, 1278.0, 2368.0], "category_id": 4}, {"id": 5, "bbox": [943.0, 125.0, 37.0, 36.0], "category_id": 3}, {"id": 6, "bbox": [207.0, 128.0, 30.0, 47.0], "category_id": 3}], "reactions": [{"reactants": [1], "conditions": [0, 3], "products": [2]}], "corefs": [[1, 6], [2, 5]], "caption": "Table 3. Palladium-Catalyzed Homocoupling of 2- Substituted Thiophenesa ", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 366, 125], "ImageBB": [89, 131, 412, 774]}, "diagram_type": "single"}, {"id": 412, "width": 1352, "height": 1516, "file_name": "op400278d-Table-c11.png", "license": 0, "bboxes": [{"id": 0, "bbox": [739.0, 239.0, 199.0, 53.0], "category_id": 1}, {"id": 1, "bbox": [287.3, 227.0, 174.5, 66.0], "category_id": 1}, {"id": 2, "bbox": [10.1, 630.3, 434.9, 217.7], "category_id": 1}, {"id": 3, "bbox": [896.4, 0.0, 221.6, 323.8], "category_id": 1}, {"id": 4, "bbox": [47.0, 235.03, 121.0, 49.0], "category_id": 1}, {"id": 5, "bbox": [1131.1, 0.0, 200.6, 281.8], "category_id": 1}, {"id": 6, "bbox": [490.0, 220.0, 205.7, 41.1], "category_id": 2}, {"id": 7, "bbox": [6.1, 1106.4, 458.6, 224.1], "category_id": 1}, {"id": 8, "bbox": [492.0, 1099.0, 391.9, 231.6], "category_id": 1}, {"id": 9, "bbox": [887.0, 625.1, 453.0, 226.7], "category_id": 1}, {"id": 10, "bbox": [457.0, 631.0, 391.0, 212.8], "category_id": 1}, {"id": 11, "bbox": [442.32, 916.43, 329.22, 148.35], "category_id": 2}, {"id": 12, "bbox": [7.44, 900.17, 290.6, 148.35], "category_id": 2}, {"id": 13, "bbox": [608.96, 1379.76, 227.6, 136.14], "category_id": 2}, {"id": 14, "bbox": [279.75, 302.71, 186.96, 52.84], "category_id": 2}, {"id": 15, "bbox": [1011.33, 1373.67, 260.12, 142.33], "category_id": 2}, {"id": 16, "bbox": [74.5, 1371.64, 331.24, 140.26], "category_id": 2}, {"id": 17, "bbox": [867.05, 910.33, 335.31, 142.25], "category_id": 2}, {"id": 18, "bbox": [6.0, 394.0, 1065.0, 87.0], "category_id": 2}, {"id": 19, "bbox": [12.0, 305.0, 192.0, 52.0], "category_id": 2}, {"id": 20, "bbox": [208.0, 1326.0, 61.0, 43.0], "category_id": 3}, {"id": 21, "bbox": [686.0, 1330.0, 60.0, 39.0], "category_id": 3}, {"id": 22, "bbox": [1109.0, 1331.0, 58.0, 36.0], "category_id": 3}, {"id": 23, "bbox": [1009.0, 867.0, 56.0, 48.0], "category_id": 3}, {"id": 24, "bbox": [577.0, 872.0, 59.0, 46.0], "category_id": 3}, {"id": 25, "bbox": [123.0, 859.0, 57.0, 43.0], "category_id": 3}, {"id": 26, "bbox": [1211.0, 328.0, 47.0, 43.0], "category_id": 3}, {"id": 27, "bbox": [977.0, 330.0, 49.0, 37.0], "category_id": 3}, {"id": 28, "bbox": [842.0, 1055.0, 504.0, 321.0], "category_id": 1}, {"id": 29, "bbox": [7.0, 492.0, 1301.0, 100.0], "category_id": 2}], "reactions": [{"reactants": [4, 1], "conditions": [6], "products": [0, 3, 5]}], "corefs": [[3, 27], [5, 26], [2, 25], [10, 24], [9, 23], [7, 20], [8, 21], [28, 22]], "caption": "Table 11. Aryl aminations with sensitive functional groups in the presence of optimized alkoxide base 92 ", "pdf": {"Page": 9, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 417, 125], "ImageBB": [82, 131, 420, 510]}, "diagram_type": "single"}, {"id": 1222, "width": 1148, "height": 800, "file_name": "op010068e-Scheme-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [575.44, 286.54, 55.7, 47.67], "category_id": 3}, {"id": 1, "bbox": [0.0, 0.0, 2.3, 7.47], "category_id": 2}, {"id": 2, "bbox": [142.42, 227.97, 60.88, 49.96], "category_id": 3}, {"id": 3, "bbox": [638.03, 392.78, 478.96, 354.88], "category_id": 1}, {"id": 4, "bbox": [905.08, 303.77, 60.87, 46.51], "category_id": 3}, {"id": 5, "bbox": [103.37, 465.71, 353.76, 281.95], "category_id": 1}, {"id": 6, "bbox": [227.99, 751.68, 60.88, 47.66], "category_id": 3}, {"id": 7, "bbox": [420.95, 18.95, 287.72, 258.98], "category_id": 1}, {"id": 8, "bbox": [792.52, 24.69, 252.68, 280.23], "category_id": 1}, {"id": 9, "bbox": [0.0, 3.45, 332.51, 210.17], "category_id": 1}], "caption": "Scheme 2", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 382, 135, 396], "ImageBB": [99, 401, 386, 601]}, "reactions": [{"reactants": [9], "conditions": [], "products": [7]}, {"reactants": [7], "conditions": [], "products": [8]}, {"reactants": [8], "conditions": [], "products": [5]}, {"reactants": [5], "conditions": [], "products": [3]}], "diagram_type": "multiple"}, {"id": 434, "width": 1348, "height": 1024, "file_name": "op300031r-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [506.0, 3.0, 537.3, 397.0], "category_id": 1}, {"id": 1, "bbox": [71.9, 80.1, 361.6, 311.7], "category_id": 1}, {"id": 2, "bbox": [714.0, 347.0, 234.8, 51.0], "category_id": 3}, {"id": 3, "bbox": [228.0, 342.0, 243.3, 53.1], "category_id": 3}, {"id": 4, "bbox": [851.88, 876.0, 73.0, 47.0], "category_id": 3}, {"id": 5, "bbox": [663.0, 408.0, 618.4, 517.3], "category_id": 1}, {"id": 6, "bbox": [7.0, 944.0, 1341.0, 80.0], "category_id": 4}, {"id": 7, "bbox": [307.0, 671.0, 326.0, 125.0], "category_id": 2}, {"id": 8, "bbox": [282.0, 489.0, 383.0, 170.0], "category_id": 2}], "reactions": [{"reactants": [1, 0], "conditions": [8, 7], "products": [5]}], "corefs": [[1, 3], [0, 2], [5, 4]], "caption": "Table 2. Suzuki Coupling Screening", "pdf": {"Page": 6, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 95, 653, 110], "ImageBB": [449, 116, 786, 372]}, "diagram_type": "multiple"}, {"id": 867, "width": 1344, "height": 528, "file_name": "jo2001534-Table-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [641.0, 439.0, 84.0, 41.0], "category_id": 3}, {"id": 1, "bbox": [33.0, 0.0, 347.0, 437.0], "category_id": 1}, {"id": 2, "bbox": [542.0, 6.0, 354.0, 422.0], "category_id": 1}, {"id": 3, "bbox": [1059.0, 2.0, 252.0, 409.0], "category_id": 1}, {"id": 4, "bbox": [343.0, 170.0, 123.0, 42.0], "category_id": 2}, {"id": 5, "bbox": [857.0, 160.0, 159.0, 52.0], "category_id": 2}, {"id": 6, "bbox": [1142.0, 434.0, 83.0, 47.0], "category_id": 3}, {"id": 7, "bbox": [116.0, 437.0, 93.0, 45.0], "category_id": 3}], "reactions": [{"reactants": [1], "conditions": [4], "products": [2]}, {"reactants": [2], "conditions": [5], "products": [3]}], "corefs": [[1, 7], [2, 0], [3, 6]], "caption": "Table 4. Yields and Substitution Pattern of 8a-e", "pdf": {"Page": 5, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [71, 279, 344, 294], "ImageBB": [71, 133, 407, 265]}, "diagram_type": "single"}, {"id": 1080, "width": 2820, "height": 852, "file_name": "jo501180a-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [696.89, 748.59, 59.25, 60.62], "category_id": 3}, {"id": 1, "bbox": [589.67, 0.0, 283.56, 714.76], "category_id": 1}, {"id": 2, "bbox": [2124.52, 369.36, 258.16, 101.51], "category_id": 2}, {"id": 3, "bbox": [0.0, 373.59, 5.64, 97.28], "category_id": 2}, {"id": 4, "bbox": [293.43, 236.84, 248.28, 102.92], "category_id": 2}, {"id": 5, "bbox": [2447.57, 0.0, 372.43, 717.58], "category_id": 1}, {"id": 6, "bbox": [93.11, 631.58, 59.25, 66.26], "category_id": 3}, {"id": 7, "bbox": [912.73, 373.59, 268.03, 62.03], "category_id": 2}, {"id": 8, "bbox": [1867.77, 752.82, 76.18, 62.03], "category_id": 3}, {"id": 9, "bbox": [2606.98, 752.82, 52.2, 59.21], "category_id": 3}, {"id": 10, "bbox": [1393.78, 752.82, 55.01, 59.21], "category_id": 3}, {"id": 11, "bbox": [289.19, 373.59, 244.06, 105.74], "category_id": 2}, {"id": 12, "bbox": [914.14, 232.61, 237.0, 111.38], "category_id": 2}, {"id": 13, "bbox": [2116.06, 287.6, 286.37, 62.03], "category_id": 2}, {"id": 14, "bbox": [1704.13, 0.0, 375.25, 717.58], "category_id": 1}, {"id": 15, "bbox": [1227.31, 0.0, 380.89, 717.58], "category_id": 1}, {"id": 16, "bbox": [0.0, 101.5, 249.69, 506.12], "category_id": 1}], "caption": "Scheme 1. Synthesis of Regioisomerically Pure 1,7-Dibromoperylene-3,4,9,10-tetracarboxy Tetrabutylester 3 from PBA 1", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 343, 760, 358], "ImageBB": [82, 364, 787, 577]}, "reactions": [{"reactants": [16], "conditions": [4, 11], "products": [1]}, {"reactants": [1], "conditions": [12, 7], "products": [15, 14]}, {"reactants": [15, 14], "conditions": [13, 2], "products": [5]}], "diagram_type": "single"}, {"id": 1274, "width": 2032, "height": 932, "file_name": "op100103v-Scheme-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1759.58, 882.9, 53.87, 48.82], "category_id": 3}, {"id": 1, "bbox": [1616.25, 591.99, 311.05, 288.88], "category_id": 1}, {"id": 2, "bbox": [1542.04, 437.38, 227.7, 91.55], "category_id": 2}, {"id": 3, "bbox": [735.95, 90.53, 398.47, 258.36], "category_id": 1}, {"id": 4, "bbox": [83.35, 354.99, 50.83, 48.83], "category_id": 3}, {"id": 5, "bbox": [888.43, 351.94, 59.97, 51.88], "category_id": 3}, {"id": 6, "bbox": [331.38, 214.62, 240.91, 51.88], "category_id": 2}, {"id": 7, "bbox": [1763.64, 351.94, 65.06, 54.93], "category_id": 3}, {"id": 8, "bbox": [1211.68, 206.48, 204.32, 55.95], "category_id": 2}, {"id": 9, "bbox": [331.38, 120.03, 135.2, 55.94], "category_id": 2}, {"id": 10, "bbox": [0.0, 90.53, 243.96, 258.36], "category_id": 1}, {"id": 11, "bbox": [426.93, 0.0, 117.92, 50.86], "category_id": 2}, {"id": 12, "bbox": [355.78, 287.86, 255.14, 140.37], "category_id": 1}, {"id": 13, "bbox": [1335.69, 0.0, 125.03, 50.86], "category_id": 2}, {"id": 14, "bbox": [1210.66, 124.09, 252.1, 57.98], "category_id": 2}, {"id": 15, "bbox": [1609.13, 100.7, 395.42, 254.29], "category_id": 1}], "caption": "Scheme 4. Stage one: telescoped procedure for 3-oxo-1,4-benzoxazine-8-carbaldehyde 16", "pdf": {"Page": 3, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 184, 546, 198], "ImageBB": [156, 203, 664, 436]}, "reactions": [{"reactants": [10, 12], "conditions": [9, 6], "products": [3]}, {"reactants": [3], "conditions": [14, 8], "products": [15]}, {"reactants": [15], "conditions": [2], "products": [1]}], "diagram_type": "tree"}, {"id": 339, "width": 1348, "height": 1092, "file_name": "ol202499g-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [137.4, 55.6, 101.6, 137.4], "category_id": 1}, {"id": 1, "bbox": [884.0, 33.9, 293.5, 200.6], "category_id": 1}, {"id": 2, "bbox": [745.0, 239.0, 46.0, 52.6], "category_id": 3}, {"id": 3, "bbox": [645.2, 143.2, 172.4, 145.4], "category_id": 1}, {"id": 4, "bbox": [322.0, 94.0, 143.0, 62.0], "category_id": 1}, {"id": 5, "bbox": [574.0, 37.0, 88.0, 52.0], "category_id": 2}, {"id": 6, "bbox": [368.0, 193.0, 56.0, 55.0], "category_id": 3}, {"id": 7, "bbox": [184.0, 193.0, 59.0, 60.0], "category_id": 3}, {"id": 8, "bbox": [158.0, 265.0, 242.0, 66.0], "category_id": 2}, {"id": 9, "bbox": [3.0, 450.0, 1345.0, 642.0], "category_id": 4}, {"id": 10, "bbox": [695.0, 62.0, 79.0, 57.0], "category_id": 2}, {"id": 11, "bbox": [1057.0, 193.0, 46.0, 58.0], "category_id": 3}, {"id": 12, "bbox": [500.0, 63.0, 64.0, 59.0], "category_id": 2}], "reactions": [{"reactants": [0, 4], "conditions": [12, 5, 10, 3], "products": [1]}], "corefs": [[0, 7], [4, 6], [3, 2], [1, 11]], "caption": "Table 3. Tandem Cyanation Allylic Alkylation Reaction with MBH Adductsa ", "pdf": {"Page": 3, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 536, 770, 563], "ImageBB": [436, 574, 773, 847]}, "diagram_type": "single"}, {"id": 1125, "width": 960, "height": 1076, "file_name": "jo991524o-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [599.24, 550.65, 131.96, 79.12], "category_id": 1}, {"id": 1, "bbox": [94.76, 631.93, 31.23, 42.52], "category_id": 3}, {"id": 2, "bbox": [664.93, 323.5, 170.13, 179.78], "category_id": 1}, {"id": 3, "bbox": [673.54, 658.84, 135.68, 54.9], "category_id": 2}, {"id": 4, "bbox": [664.93, 198.62, 138.9, 55.44], "category_id": 2}, {"id": 5, "bbox": [534.09, 779.95, 422.65, 296.05], "category_id": 1}, {"id": 6, "bbox": [645.54, 0.0, 189.52, 184.63], "category_id": 1}, {"id": 7, "bbox": [0.0, 410.16, 222.9, 222.84], "category_id": 1}, {"id": 8, "bbox": [768.04, 550.26, 130.47, 80.09], "category_id": 1}], "caption": "Scheme 1", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [207, 64, 270, 78], "ImageBB": [123, 84, 363, 353]}, "reactions": [{"reactants": [7], "conditions": [], "products": [6, 4]}, {"reactants": [7], "conditions": [], "products": [2, 0, 8, 3]}, {"reactants": [7], "conditions": [], "products": [5]}], "diagram_type": "tree"}, {"id": 973, "width": 852, "height": 660, "file_name": "ja052327b-Scheme-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [344.38, 385.15, 81.83, 43.46], "category_id": 2}, {"id": 1, "bbox": [615.6, 20.45, 66.34, 48.57], "category_id": 1}, {"id": 2, "bbox": [290.68, 296.53, 37.08, 43.03], "category_id": 3}, {"id": 3, "bbox": [725.41, 60.5, 126.59, 102.25], "category_id": 1}, {"id": 4, "bbox": [0.0, 367.26, 118.06, 288.43], "category_id": 1}, {"id": 5, "bbox": [449.23, 316.56, 64.36, 51.97], "category_id": 1}, {"id": 6, "bbox": [587.32, 207.49, 42.2, 45.58], "category_id": 2}, {"id": 7, "bbox": [183.27, 193.0, 241.66, 79.67], "category_id": 1}, {"id": 8, "bbox": [362.28, 478.88, 292.81, 83.51], "category_id": 1}, {"id": 9, "bbox": [418.12, 95.86, 34.52, 40.9], "category_id": 3}, {"id": 10, "bbox": [193.5, 384.3, 74.59, 46.44], "category_id": 2}, {"id": 11, "bbox": [334.58, 4.26, 187.1, 75.84], "category_id": 1}], "caption": "Scheme 3. Postulated Mechanisms for the Formation of 1-Octene", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 64, 407, 76], "ImageBB": [214, 80, 427, 245]}, "reactions": [{"reactants": [11], "conditions": [1], "products": [3]}, {"reactants": [3], "conditions": [6], "products": [7]}, {"reactants": [7], "conditions": [10], "products": [4]}, {"reactants": [7], "conditions": [0, 5], "products": [8]}], "diagram_type": "tree"}, {"id": 263, "width": 1348, "height": 1688, "file_name": "ol801498u-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [912.0, 0.0, 303.8, 203.0], "category_id": 1}, {"id": 1, "bbox": [133.1, 8.0, 159.9, 132.0], "category_id": 1}, {"id": 2, "bbox": [615.0, 6.0, 225.0, 100.9], "category_id": 2}, {"id": 3, "bbox": [18.0, 249.0, 1330.0, 1414.0], "category_id": 4}, {"id": 4, "bbox": [648.0, 120.0, 152.0, 64.0], "category_id": 2}, {"id": 5, "bbox": [365.0, 0.0, 201.0, 200.0], "category_id": 1}], "reactions": [{"reactants": [1, 5], "conditions": [2, 4], "products": [0]}], "corefs": [], "caption": "Table 2. Direct Thioester Crossed-Claisen Coupling", "pdf": {"Page": 3, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [425, 75, 695, 88], "ImageBB": [425, 97, 762, 519]}, "diagram_type": "single"}, {"id": 258, "width": 1352, "height": 800, "file_name": "ol802005n-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1086.3, 3.9, 262.7, 201.0], "category_id": 1}, {"id": 1, "bbox": [657.6, 1.9, 265.0, 185.8], "category_id": 1}, {"id": 2, "bbox": [4.0, 269.3, 1339.0, 478.7], "category_id": 4}, {"id": 3, "bbox": [5.2, 4.6, 223.9, 181.7], "category_id": 1}, {"id": 4, "bbox": [250.0, 64.0, 355.0, 53.0], "category_id": 2}, {"id": 5, "bbox": [86.0, 222.0, 42.0, 35.0], "category_id": 3}, {"id": 6, "bbox": [778.0, 220.0, 42.0, 40.0], "category_id": 3}, {"id": 7, "bbox": [1168.0, 218.0, 39.0, 39.0], "category_id": 3}, {"id": 8, "bbox": [272.0, 140.0, 284.0, 44.0], "category_id": 2}], "reactions": [{"reactants": [3], "conditions": [4, 8], "products": [1]}, {"reactants": [1], "conditions": [], "products": [0]}], "corefs": [[3, 5], [1, 6], [0, 7]], "caption": "Table 1. 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Kinetic Model of the Reaction", "pdf": {"Page": 6, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 634, 316, 649], "ImageBB": [82, 655, 420, 796]}, "reactions": [{"reactants": [11, 10, 5], "conditions": [9, 8], "products": [7]}, {"reactants": [7], "conditions": [2, 12, 4], "products": [13]}, {"reactants": [13], "conditions": [6], "products": [16]}, {"reactants": [7], "conditions": [0], "products": [14]}, {"reactants": [14], "conditions": [1], "products": [7]}], "diagram_type": "tree"}, {"id": 175, "width": 1240, "height": 380, "file_name": "op060249m-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1.0, 200.0, 180.0, 129.0], "category_id": 1}, {"id": 1, "bbox": [1061.0, 246.0, 177.0, 52.0], "category_id": 2}, {"id": 2, "bbox": [113.0, 331.0, 24.0, 32.0], "category_id": 3}, {"id": 3, "bbox": [285.0, 290.0, 131.0, 39.0], "category_id": 2}, {"id": 4, "bbox": [293.0, 202.0, 101.0, 36.0], "category_id": 2}, {"id": 5, "bbox": [465.0, 199.0, 326.0, 181.0], "category_id": 1}, {"id": 6, "bbox": [192.0, 3.0, 327.0, 171.0], "category_id": 1}, {"id": 7, "bbox": [828.0, 279.48, 182.93, 39.66], "category_id": 3}, {"id": 8, "bbox": [830.0, 236.0, 188.4, 38.9], "category_id": 3}], "reactions": [{"reactants": [0], "conditions": [6, 4, 3], "products": [5]}, {"reactants": [8], "conditions": [1], "products": [7]}], "corefs": [[5, 8], [5, 7]], "caption": "Figure 1.", "pdf": {"Page": 1, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 308, 495, 322], "ImageBB": [453, 209, 763, 304]}, "diagram_type": "single"}, {"id": 1327, "width": 2820, "height": 1308, "file_name": "op400135y-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1453.03, 196.18, 173.51, 59.28], "category_id": 2}, {"id": 1, "bbox": [1091.89, 625.23, 550.17, 88.92], "category_id": 2}, {"id": 2, "bbox": [1560.24, 128.43, 682.78, 429.06], "category_id": 1}, {"id": 3, "bbox": [1180.76, 899.03, 327.28, 128.44], "category_id": 2}, {"id": 4, "bbox": [1049.56, 114.32, 404.88, 141.14], "category_id": 1}, {"id": 5, "bbox": [560.05, 128.43, 584.03, 379.66], "category_id": 1}, {"id": 6, "bbox": [1934.08, 639.34, 186.21, 70.57], "category_id": 2}, {"id": 7, "bbox": [623.53, 601.24, 228.54, 163.72], "category_id": 1}, {"id": 8, "bbox": [1585.63, 825.64, 684.67, 436.11], "category_id": 1}, {"id": 9, "bbox": [1140.1, 0.0, 439.89, 70.57], "category_id": 2}, {"id": 10, "bbox": [1248.47, 390.95, 191.86, 66.33], "category_id": 2}, {"id": 11, "bbox": [560.05, 832.7, 584.03, 388.12], "category_id": 1}], "caption": "Scheme 1. (A) Enzyme-Catalyzed Acylation of Clindamycin Palmitate in Organic Solvent and (B) Current Chemical Synthesis Process of Clindamycin Palmitate ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 784, 125], "ImageBB": [82, 131, 787, 458]}, "reactions": [{"reactants": [5, 4], "conditions": [10], "products": [0, 2]}, {"reactants": [5, 7], "conditions": [], "products": [11]}, {"reactants": [11], "conditions": [3], "products": [8]}, {"reactants": [8], "conditions": [6], "products": [2]}], "diagram_type": "graph"}, {"id": 1281, "width": 968, "height": 1376, "file_name": "op100210s-Scheme-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [831.99, 454.31, 43.35, 51.62], "category_id": 3}, {"id": 1, "bbox": [723.26, 0.0, 244.74, 450.18], "category_id": 1}, {"id": 2, "bbox": [0.0, 522.45, 118.36, 186.54], "category_id": 1}, {"id": 3, "bbox": [679.9, 842.53, 278.71, 450.87], "category_id": 1}, {"id": 4, "bbox": [720.5, 622.26, 107.36, 53.01], "category_id": 2}, {"id": 5, "bbox": [835.43, 1326.44, 70.88, 49.56], "category_id": 3}, {"id": 6, "bbox": [165.85, 1318.18, 68.12, 53.69], "category_id": 3}, {"id": 7, "bbox": [90.84, 46.12, 225.03, 333.85], "category_id": 1}, {"id": 8, "bbox": [52.3, 809.49, 238.1, 452.93], "category_id": 1}, {"id": 9, "bbox": [165.85, 453.62, 61.24, 50.25], "category_id": 3}], "caption": "Scheme 2. Postulated preparation of imidazolidinone 7", "pdf": {"Page": 2, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 421, 365, 435], "ImageBB": [106, 440, 348, 784]}, "reactions": [{"reactants": [7, 2], "conditions": [], "products": [8]}, {"reactants": [8], "conditions": [], "products": [2, 7]}, {"reactants": [7], "conditions": [], "products": [1]}, {"reactants": [8], "conditions": [], "products": [3]}, {"reactants": [3], "conditions": [], "products": [8]}, {"reactants": [3], "conditions": [4], "products": [1]}, {"reactants": [1], "conditions": [], "products": [3]}], "diagram_type": "graph"}, {"id": 494, "width": 1320, "height": 2384, "file_name": "ol0600584-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [532.0, 35.4, 269.0, 62.2], "category_id": 2}, {"id": 1, "bbox": [529.8, 113.2, 272.0, 66.6], "category_id": 2}, {"id": 2, "bbox": [224.1, 0.0, 257.9, 169.0], "category_id": 1}, {"id": 3, "bbox": [854.4, 0.0, 241.6, 159.0], "category_id": 1}, {"id": 4, "bbox": [17.0, 179.0, 1303.0, 2200.0], "category_id": 4}], "reactions": [{"reactants": [2], "conditions": [0, 1], "products": [3]}], "corefs": [], "caption": "Table 3. Catalytic Asymmetric Reduction of Ketonesa", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 161, 727, 175], "ImageBB": [443, 180, 773, 776]}, "diagram_type": "single"}, {"id": 118, "width": 1280, "height": 232, "file_name": "op980075b-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1022.0, 46.0, 160.0, 52.3], "category_id": 2}, {"id": 1, "bbox": [474.3, 24.5, 56.6, 47.3], "category_id": 2}, {"id": 2, "bbox": [0.0, 5.0, 148.0, 159.0], "category_id": 1}, {"id": 3, "bbox": [194.0, 52.0, 140.0, 54.0], "category_id": 2}, {"id": 4, "bbox": [713.0, 172.0, 563.0, 60.0], "category_id": 2}, {"id": 5, "bbox": [743.8, 22.8, 205.4, 135.1], "category_id": 1}], "reactions": [{"reactants": [2, 3], "conditions": [1], "products": [5, 0]}], "corefs": [], "caption": "Table 1. 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Preliminary Mechanistic Studies", "pdf": {"Page": 4, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 95, 692, 110], "ImageBB": [448, 116, 787, 597]}, "reactions": [{"reactants": [18], "conditions": [6, 20], "products": [25, 3]}, {"reactants": [4], "conditions": [27, 23], "products": [28, 15]}, {"reactants": [24], "conditions": [19, 21], "products": [5, 0]}, {"reactants": [22], "conditions": [2, 29], "products": [13]}], "diagram_type": "multiple"}, {"id": 664, "width": 1348, "height": 772, "file_name": "ol402047d-Table-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1002.02, 296.0, 35.0, 37.0], "category_id": 3}, {"id": 1, "bbox": [8.0, 366.0, 1340.0, 406.0], "category_id": 4}, {"id": 2, "bbox": [882.0, 269.0, 33.0, 34.0], "category_id": 3}, {"id": 3, "bbox": [240.0, 138.0, 306.0, 44.0], "category_id": 2}, {"id": 4, "bbox": [327.0, 61.0, 161.0, 75.0], "category_id": 2}, {"id": 5, "bbox": [624.0, 100.0, 158.0, 39.0], "category_id": 2}, {"id": 6, "bbox": [713.0, 75.0, 33.0, 33.0], "category_id": 3}, {"id": 7, "bbox": [852.0, 12.0, 97.0, 251.0], "category_id": 1}, {"id": 8, "bbox": [584.0, 142.0, 230.0, 156.0], "category_id": 2}, {"id": 9, "bbox": [605.0, 15.0, 200.0, 75.1], "category_id": 1}, {"id": 10, "bbox": [1105.0, 119.0, 153.0, 80.0], "category_id": 2}, {"id": 11, "bbox": [983.0, 0.0, 87.1, 299.0], "category_id": 1}, {"id": 12, "bbox": [125.9, 117.0, 83.6, 39.2], "category_id": 2}, {"id": 13, "bbox": [84.62, 153.53, 162.47, 43.7], "category_id": 2}], "reactions": [{"reactants": [12], "conditions": [4, 3, 9, 5, 8], "products": [7, 11, 10]}], "corefs": [[9, 6], [7, 2], [11, 0]], "caption": "Table 4. Recyclability of Polymer Using the Same Nucleophile", "pdf": {"Page": 4, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 87, 770, 100], "ImageBB": [436, 112, 773, 305]}, "diagram_type": "single"}, {"id": 1, "width": 3396, "height": 1776, "file_name": "jacs.6b00143-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [2390.35, 60.38, 146.74, 112.34], "category_id": 1}, {"id": 1, "bbox": [1262.95, 198.63, 49.38, 36.4], "category_id": 3}, {"id": 2, "bbox": [878.06, 201.87, 81.18, 34.45], "category_id": 3}, {"id": 3, "bbox": [2443.58, 201.87, 28.61, 35.1], "category_id": 3}, {"id": 4, "bbox": [289.0, 259.21, 2816.1, 1237.18], "category_id": 4}, {"id": 5, "bbox": [1486.22, 2.61, 310.95, 118.83], "category_id": 2}, {"id": 6, "bbox": [1908.11, 9.1, 357.68, 188.28], "category_id": 1}, {"id": 7, "bbox": [1127.7, 41.51, 272.44, 171.58], "category_id": 1}, {"id": 8, "bbox": [848.15, 59.84, 146.35, 109.71], "category_id": 1}, {"id": 9, "bbox": [1483.62, 148.0, 319.39, 42.89], "category_id": 2}, {"id": 10, "bbox": [2043.11, 201.87, 27.96, 35.1], "category_id": 3}], "reactions": [{"reactants": [8, 7], "conditions": [5, 9], "products": [6, 0]}], "corefs": [[8, 2], [7, 1], [6, 10], [0, 3]], "caption": "Table 2. Substrate Scope for Kinetic Resolutions of Sulfoximines and a Sulfondiimide with Enal 2ba", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 656, 648, 677], "ImageBB": [10, 683, 859, 1127]}, "diagram_type": "single"}, {"id": 1086, "width": 1340, "height": 512, "file_name": "jo9519672-Scheme-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [687.76, 95.25, 27.49, 33.54], "category_id": 2}, {"id": 1, "bbox": [4.69, 4.02, 187.7, 217.33], "category_id": 1}, {"id": 2, "bbox": [947.85, 340.75, 22.12, 24.15], "category_id": 2}, {"id": 3, "bbox": [811.11, 69.09, 327.12, 191.84], "category_id": 1}, {"id": 4, "bbox": [95.19, 311.23, 327.79, 194.53], "category_id": 1}, {"id": 5, "bbox": [1181.13, 95.25, 40.22, 35.55], "category_id": 2}, {"id": 6, "bbox": [462.53, 326.66, 34.86, 32.87], "category_id": 2}, {"id": 7, "bbox": [217.86, 87.87, 19.44, 35.55], "category_id": 2}, {"id": 8, "bbox": [355.95, 72.44, 282.21, 157.63], "category_id": 1}, {"id": 9, "bbox": [588.55, 310.56, 325.79, 191.84], "category_id": 1}, {"id": 10, "bbox": [1049.74, 319.95, 290.26, 186.48], "category_id": 1}], "caption": "Scheme 3a", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [562, 240, 631, 254], "ImageBB": [430, 261, 765, 389]}, "reactions": [{"reactants": [1], "conditions": [7], "products": [8]}, {"reactants": [8], "conditions": [0], "products": [3]}, {"reactants": [3], "conditions": [5], "products": [4]}, {"reactants": [4], "conditions": [6], "products": [9]}, {"reactants": [9], "conditions": [2], "products": [10]}], "diagram_type": "multiple"}, {"id": 1104, "width": 1228, "height": 692, "file_name": "jo980058k-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [896.27, 643.32, 38.09, 44.24], "category_id": 3}, {"id": 1, "bbox": [565.78, 13.52, 453.36, 235.33], "category_id": 1}, {"id": 2, "bbox": [111.19, 259.91, 42.39, 45.47], "category_id": 3}, {"id": 3, "bbox": [0.0, 391.4, 426.94, 230.42], "category_id": 1}, {"id": 4, "bbox": [109.35, 642.1, 37.47, 44.24], "category_id": 3}, {"id": 5, "bbox": [0.0, 13.52, 369.2, 231.03], "category_id": 1}, {"id": 6, "bbox": [729.8, 265.44, 36.24, 41.78], "category_id": 3}, {"id": 7, "bbox": [783.24, 391.4, 399.92, 232.26], "category_id": 1}], "caption": "Scheme 1", "pdf": {"Page": 1, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [573, 343, 636, 357], "ImageBB": [454, 363, 761, 536]}, "reactions": [{"reactants": [5], "conditions": [], "products": [1]}, {"reactants": [1], "conditions": [], "products": [3]}, {"reactants": [3], "conditions": [], "products": [7]}], "diagram_type": "multiple"}, {"id": 331, "width": 1340, "height": 860, "file_name": "ol300387f-Table-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [129.0, 5.0, 164.0, 197.2], "category_id": 1}, {"id": 1, "bbox": [980.0, 12.0, 236.7, 219.7], "category_id": 4}, {"id": 2, "bbox": [478.0, 6.0, 230.0, 200.1], "category_id": 1}, {"id": 3, "bbox": [522.0, 216.0, 128.0, 33.0], "category_id": 3}, {"id": 4, "bbox": [803.0, 214.0, 83.0, 35.0], "category_id": 3}, {"id": 5, "bbox": [13.0, 286.0, 1287.0, 574.0], "category_id": 4}, {"id": 6, "bbox": [218.97, 210.55, 33.25, 39.89], "category_id": 3}, {"id": 7, "bbox": [319.0, 133.0, 142.0, 35.0], "category_id": 2}, {"id": 8, "bbox": [315.0, 67.0, 151.0, 32.0], "category_id": 2}, {"id": 9, "bbox": [736.0, 5.0, 231.0, 200.0], "category_id": 1}], "reactions": [{"reactants": [0], "conditions": [8, 7], "products": [2, 9]}], "corefs": [[0, 6], [2, 3], [9, 4]], "caption": "Table 4. 1,4-Addition of ArZnCl and PhB(OH)2 to Enones 1e,f", "pdf": {"Page": 4, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [71, 548, 405, 563], "ImageBB": [72, 573, 407, 788]}, "diagram_type": "single"}, {"id": 766, "width": 1344, "height": 1112, "file_name": "jo961049j-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [34.0, 549.0, 1262.0, 102.0], "category_id": 2}, {"id": 1, "bbox": [370.0, 221.0, 35.0, 35.0], "category_id": 2}, {"id": 2, "bbox": [1.0, 669.0, 1343.0, 443.0], "category_id": 4}, {"id": 3, "bbox": [888.0, 214.0, 38.0, 44.0], "category_id": 2}, {"id": 4, "bbox": [19.0, 18.0, 277.0, 444.0], "category_id": 1}, {"id": 5, "bbox": [526.0, 20.0, 257.0, 388.0], "category_id": 1}, {"id": 6, "bbox": [993.0, 2.0, 333.0, 414.0], "category_id": 1}, {"id": 7, "bbox": [64.0, 475.0, 198.0, 44.0], "category_id": 3}, {"id": 8, "bbox": [595.0, 473.0, 125.0, 52.0], "category_id": 3}, {"id": 9, "bbox": [1122.0, 479.0, 125.0, 42.0], "category_id": 3}], "reactions": [{"reactants": [4], "conditions": [1], "products": [5]}, {"reactants": [5], "conditions": [3], "products": [6]}], "corefs": [[4, 7], [5, 8], [6, 9]], "caption": "Table 1. Tandem Enyne Allene-Radical Cyclization of                 Substrates 62-67 ", "pdf": {"Page": 8, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [79, 49, 402, 74], "ImageBB": [73, 76, 409, 354]}, "diagram_type": "single"}, {"id": 1256, "width": 1216, "height": 824, "file_name": "op050040t-Scheme-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [355.86, 110.14, 369.24, 88.23], "category_id": 2}, {"id": 1, "bbox": [911.24, 3.65, 206.21, 136.91], "category_id": 1}, {"id": 2, "bbox": [897.86, 558.6, 318.14, 177.68], "category_id": 1}, {"id": 3, "bbox": [993.36, 153.95, 37.72, 43.81], "category_id": 3}, {"id": 4, "bbox": [55.36, 568.94, 315.1, 172.82], "category_id": 1}, {"id": 5, "bbox": [0.0, 68.15, 236.63, 74.85], "category_id": 1}, {"id": 6, "bbox": [546.87, 632.23, 85.77, 41.37], "category_id": 2}, {"id": 7, "bbox": [775.59, 338.93, 235.41, 77.28], "category_id": 1}, {"id": 8, "bbox": [96.72, 168.55, 32.85, 38.34], "category_id": 3}, {"id": 9, "bbox": [161.2, 780.09, 35.28, 39.55], "category_id": 3}, {"id": 10, "bbox": [870.48, 425.95, 40.76, 41.98], "category_id": 3}, {"id": 11, "bbox": [447.1, 60.24, 153.9, 41.99], "category_id": 2}], "caption": "Scheme 2. Formation of ester 4 in the oxidation of activated alcohols 2 ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 53, 361, 81], "ImageBB": [90, 85, 394, 291]}, "reactions": [{"reactants": [5], "conditions": [11, 0], "products": [1]}, {"reactants": [1, 7], "conditions": [], "products": [2]}, {"reactants": [2], "conditions": [], "products": [1]}, {"reactants": [2], "conditions": [6], "products": [4]}], "diagram_type": "tree"}, {"id": 1356, "width": 1180, "height": 1360, "file_name": "op9000687-Scheme-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [787.54, 759.94, 373.37, 306.15], "category_id": 1}, {"id": 1, "bbox": [899.76, 1016.43, 199.94, 56.47], "category_id": 2}, {"id": 2, "bbox": [141.46, 188.45, 46.92, 51.71], "category_id": 3}, {"id": 3, "bbox": [942.6, 564.68, 59.85, 50.35], "category_id": 3}, {"id": 4, "bbox": [31.28, 1142.29, 189.75, 157.84], "category_id": 1}, {"id": 5, "bbox": [214.23, 917.78, 46.92, 51.7], "category_id": 3}, {"id": 6, "bbox": [306.72, 1150.46, 259.79, 121.78], "category_id": 1}, {"id": 7, "bbox": [397.17, 1305.57, 68.01, 50.35], "category_id": 3}, {"id": 8, "bbox": [448.86, 426.57, 208.11, 108.18], "category_id": 2}, {"id": 9, "bbox": [922.2, 1087.18, 84.33, 52.39], "category_id": 3}, {"id": 10, "bbox": [960.29, 635.44, 219.71, 136.75], "category_id": 2}, {"id": 11, "bbox": [35.36, 0.0, 246.2, 233.36], "category_id": 1}, {"id": 12, "bbox": [60.53, 1313.74, 63.93, 46.26], "category_id": 3}, {"id": 13, "bbox": [0.0, 425.21, 395.81, 219.75], "category_id": 1}, {"id": 14, "bbox": [35.36, 751.1, 397.86, 217.02], "category_id": 1}, {"id": 15, "bbox": [141.46, 594.62, 49.65, 51.02], "category_id": 3}, {"id": 16, "bbox": [760.34, 349.01, 367.93, 270.1], "category_id": 1}], "caption": "Scheme 3. Some strategies for the synthesis of carbonate 12", "pdf": {"Page": 2, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 254, 392, 268], "ImageBB": [79, 273, 374, 613]}, "reactions": [{"reactants": [11], "conditions": [], "products": [13]}, {"reactants": [13], "conditions": [8], "products": [16]}, {"reactants": [16], "conditions": [10], "products": [0]}, {"reactants": [4, 6], "conditions": [], "products": [14]}, {"reactants": [14], "conditions": [], "products": [13]}], "diagram_type": "tree"}, {"id": 1230, "width": 1228, "height": 1432, "file_name": "op010097p-Scheme-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1078.93, 277.23, 68.06, 55.88], "category_id": 3}, {"id": 1, "bbox": [606.81, 899.75, 545.91, 334.55], "category_id": 1}, {"id": 2, "bbox": [781.62, 45.85, 446.38, 305.35], "category_id": 1}, {"id": 3, "bbox": [204.9, 305.88, 53.01, 54.45], "category_id": 3}, {"id": 4, "bbox": [527.29, 473.51, 614.69, 308.75], "category_id": 1}, {"id": 5, "bbox": [148.3, 987.14, 277.26, 71.64], "category_id": 2}, {"id": 6, "bbox": [472.12, 0.0, 288.72, 189.83], "category_id": 2}, {"id": 7, "bbox": [45.85, 520.79, 401.91, 73.79], "category_id": 2}, {"id": 8, "bbox": [148.3, 1371.83, 53.73, 60.17], "category_id": 3}, {"id": 9, "bbox": [739.35, 750.03, 71.64, 55.87], "category_id": 3}, {"id": 10, "bbox": [472.12, 231.38, 213.5, 128.95], "category_id": 2}, {"id": 11, "bbox": [712.12, 1272.25, 70.21, 58.74], "category_id": 3}, {"id": 12, "bbox": [45.85, 624.66, 356.78, 117.49], "category_id": 2}, {"id": 13, "bbox": [0.0, 66.62, 443.47, 305.89], "category_id": 1}, {"id": 14, "bbox": [148.3, 1107.49, 277.26, 315.91], "category_id": 1}], "caption": "Scheme 3", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 441, 501, 455], "ImageBB": [455, 462, 762, 820]}, "reactions": [{"reactants": [13], "conditions": [6, 10], "products": [2]}, {"reactants": [2], "conditions": [7, 12], "products": [4]}, {"reactants": [4, 14], "conditions": [5], "products": [1]}], "diagram_type": "multiple"}, {"id": 612, "width": 3396, "height": 2056, "file_name": "acs.oprd.5b00312-Figure-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1948.0, 624.0, 264.0, 49.0], "category_id": 2}, {"id": 1, "bbox": [1973.0, 315.0, 281.0, 54.0], "category_id": 3}, {"id": 2, "bbox": [1570.0, 624.0, 288.0, 54.0], "category_id": 2}, {"id": 3, "bbox": [1215.0, 319.0, 262.0, 48.0], "category_id": 3}, {"id": 4, "bbox": [1835.0, 380.0, 39.0, 27.0], "category_id": 2}, {"id": 5, "bbox": [1423.0, 392.0, 37.0, 27.0], "category_id": 2}, {"id": 6, "bbox": [678.0, 695.0, 2007.0, 1361.0], "category_id": 4}, {"id": 7, "bbox": [1464.0, 493.0, 97.0, 28.0], "category_id": 2}, {"id": 8, "bbox": [2197.0, 390.0, 41.0, 23.0], "category_id": 2}, {"id": 9, "bbox": [1167.0, 619.0, 295.0, 57.0], "category_id": 2}, {"id": 10, "bbox": [1185.5, 413.2, 198.7, 181.5], "category_id": 1}, {"id": 11, "bbox": [1946.8, 410.5, 201.3, 184.0], "category_id": 1}, {"id": 12, "bbox": [1571.9, 411.1, 219.2, 182.9], "category_id": 1}], "reactions": [{"reactants": [10], "conditions": [7], "products": [12, 11]}], "corefs": [[10, 3], [11, 1], [10, 9], [12, 2], [11, 0]], "caption": "Figure 2. (A\u2212C) UHPLC/UV chromatograms at 254 nm for (A) unreacted compound 6, (B) the HCl control, and (C) the TiCl3/HCl-treated sample. (D\u2212F) MS-selected-ion chromatograms for (D, E) compound 6 with the target mass of m/z 253 and (F) compound 6a with the target mass m/z 223. ", "pdf": {"Page": 4, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 548, 784, 590], "ImageBB": [10, 22, 859, 536]}, "diagram_type": "single"}, {"id": 218, "width": 1348, "height": 784, "file_name": "op0256183-Table-c5.png", "license": 0, "bboxes": [{"id": 0, "bbox": [10.0, 6.0, 382.0, 135.7], "category_id": 1}, {"id": 1, "bbox": [382.0, 10.0, 574.0, 63.9], "category_id": 2}, {"id": 2, "bbox": [512.0, 91.0, 346.0, 102.0], "category_id": 2}, {"id": 3, "bbox": [969.0, 2.0, 377.0, 139.0], "category_id": 1}, {"id": 4, "bbox": [32.0, 228.0, 1300.0, 549.0], "category_id": 4}], "reactions": [{"reactants": [0], "conditions": [1, 2], "products": [3]}], "corefs": [], "caption": "Table 5. Effects of reducing the substrate-to-catalyst ratio", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 656, 759, 670], "ImageBB": [439, 677, 776, 873]}, "diagram_type": "single"}, {"id": 1039, "width": 2236, "height": 1320, "file_name": "jo0056489-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1069.34, 370.21, 33.56, 42.5], "category_id": 3}, {"id": 1, "bbox": [1677.84, 373.56, 99.55, 48.1], "category_id": 3}, {"id": 2, "bbox": [430.65, 555.87, 39.14, 48.09], "category_id": 2}, {"id": 3, "bbox": [961.96, 134.21, 206.93, 172.25], "category_id": 1}, {"id": 4, "bbox": [738.25, 152.11, 167.78, 144.28], "category_id": 1}, {"id": 5, "bbox": [780.75, 975.29, 63.76, 44.74], "category_id": 3}, {"id": 6, "bbox": [168.9, 369.09, 93.96, 44.74], "category_id": 3}, {"id": 7, "bbox": [606.26, 737.06, 369.12, 214.74], "category_id": 1}, {"id": 8, "bbox": [817.67, 705.74, 81.65, 49.21], "category_id": 3}, {"id": 9, "bbox": [1147.64, 1094.96, 163.31, 67.11], "category_id": 2}, {"id": 10, "bbox": [1371.35, 1031.21, 341.16, 213.62], "category_id": 1}, {"id": 11, "bbox": [1977.61, 709.1, 85.01, 45.85], "category_id": 3}, {"id": 12, "bbox": [602.9, 468.63, 446.31, 197.97], "category_id": 1}, {"id": 13, "bbox": [430.65, 1097.2, 32.43, 42.5], "category_id": 2}, {"id": 14, "bbox": [1555.92, 96.19, 329.97, 224.81], "category_id": 1}, {"id": 15, "bbox": [1555.92, 1276.15, 60.4, 41.38], "category_id": 3}, {"id": 16, "bbox": [0.0, 867.92, 197.98, 52.56], "category_id": 3}, {"id": 17, "bbox": [38.8, 432.84, 627.86, 59.28], "category_id": 2}, {"id": 18, "bbox": [1972.02, 131.98, 263.98, 211.62], "category_id": 2}, {"id": 19, "bbox": [1177.84, 468.63, 454.14, 218.1], "category_id": 1}, {"id": 20, "bbox": [431.71, 839.62, 35.41, 47.21], "category_id": 2}, {"id": 21, "bbox": [757.16, 367.46, 106.23, 50.59], "category_id": 3}, {"id": 22, "bbox": [1210.28, 3.36, 303.13, 206.04], "category_id": 2}, {"id": 23, "bbox": [1281.87, 269.55, 144.29, 57.04], "category_id": 2}, {"id": 24, "bbox": [241.61, 782.91, 168.9, 101.78], "category_id": 2}, {"id": 25, "bbox": [1761.73, 470.87, 450.78, 213.62], "category_id": 1}, {"id": 26, "bbox": [58.17, 115.2, 321.02, 194.61], "category_id": 1}, {"id": 27, "bbox": [633.1, 1032.33, 398.21, 210.27], "category_id": 1}, {"id": 28, "bbox": [493.28, 261.72, 147.65, 58.16], "category_id": 2}, {"id": 29, "bbox": [1399.32, 705.74, 87.25, 49.21], "category_id": 3}], "caption": "Scheme 1", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [390, 64, 453, 78], "ImageBB": [146, 85, 705, 415]}, "reactions": [{"reactants": [26], "conditions": [], "products": [4, 3]}, {"reactants": [4, 3], "conditions": [28], "products": [26]}, {"reactants": [4, 3], "conditions": [22], "products": [14, 18]}, {"reactants": [14, 18], "conditions": [23], "products": [4, 3]}, {"reactants": [16], "conditions": [24, 2], "products": [12, 19, 25]}, {"reactants": [16], "conditions": [24, 20], "products": [7]}, {"reactants": [16], "conditions": [24, 13], "products": [27]}, {"reactants": [27], "conditions": [9], "products": [10]}], "diagram_type": "tree"}, {"id": 366, "width": 1160, "height": 1448, "file_name": "ol102784c-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [366.0, 1.0, 366.0, 90.0], "category_id": 2}, {"id": 1, "bbox": [245.0, 74.0, 98.0, 41.0], "category_id": 2}, {"id": 2, "bbox": [41.0, 27.0, 189.0, 118.0], "category_id": 1}, {"id": 3, "bbox": [770.0, 19.0, 350.0, 128.0], "category_id": 1}, {"id": 4, "bbox": [0.0, 193.0, 1160.0, 1255.0], "category_id": 4}, {"id": 5, "bbox": [445.0, 109.0, 191.0, 42.0], "category_id": 2}], "reactions": [{"reactants": [2, 1], "conditions": [0, 5], "products": [3]}], "corefs": [], "caption": "Table 2. Copper-Catalyzed C-S Coupling of Different Aryl Iodides with Potassium Thiocyanatea ", "pdf": {"Page": 2, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [425, 281, 738, 308], "ImageBB": [448, 317, 738, 679]}, "diagram_type": "single"}, {"id": 1025, "width": 1116, "height": 1708, "file_name": "jo000585f-Scheme-c18.png", "license": 0, "bboxes": [{"id": 0, "bbox": [0.0, 116.2, 131.58, 64.08], "category_id": 3}, {"id": 1, "bbox": [703.17, 275.13, 142.69, 61.51], "category_id": 3}, {"id": 2, "bbox": [703.17, 926.2, 275.98, 71.77], "category_id": 3}, {"id": 3, "bbox": [703.17, 1048.38, 351.16, 233.26], "category_id": 1}, {"id": 4, "bbox": [945.83, 84.59, 131.57, 97.4], "category_id": 2}, {"id": 5, "bbox": [706.59, 368.26, 343.47, 185.41], "category_id": 1}, {"id": 6, "bbox": [214.46, 46.99, 357.14, 100.83], "category_id": 2}, {"id": 7, "bbox": [580.14, 0.0, 341.76, 245.22], "category_id": 1}, {"id": 8, "bbox": [680.96, 679.27, 352.01, 215.32], "category_id": 1}, {"id": 9, "bbox": [94.84, 542.56, 140.98, 64.94], "category_id": 3}, {"id": 10, "bbox": [731.37, 572.47, 275.12, 69.2], "category_id": 3}, {"id": 11, "bbox": [69.21, 375.95, 220.43, 141.83], "category_id": 1}, {"id": 12, "bbox": [311.0, 165.76, 102.53, 50.41], "category_id": 2}, {"id": 13, "bbox": [328.09, 464.81, 256.32, 117.91], "category_id": 2}, {"id": 14, "bbox": [140.98, 788.64, 256.32, 53.83], "category_id": 2}, {"id": 15, "bbox": [94.84, 1141.51, 289.64, 109.37], "category_id": 2}, {"id": 16, "bbox": [94.84, 715.16, 468.21, 64.93], "category_id": 2}, {"id": 17, "bbox": [311.0, 393.89, 296.48, 68.36], "category_id": 2}, {"id": 18, "bbox": [730.52, 1296.17, 309.29, 65.79], "category_id": 3}, {"id": 19, "bbox": [58.95, 1412.37, 991.97, 295.63], "category_id": 4}, {"id": 20, "bbox": [94.84, 1073.16, 512.64, 62.37], "category_id": 2}, {"id": 21, "bbox": [214.46, 866.39, 131.57, 58.95], "category_id": 3}], "caption": "Scheme 18", "pdf": {"Page": 6, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [570, 64, 641, 78], "ImageBB": [470, 85, 749, 512]}, "reactions": [{"reactants": [0], "conditions": [6, 12], "products": [7]}, {"reactants": [7], "conditions": [4], "products": [11]}, {"reactants": [11], "conditions": [17, 13], "products": [5]}, {"reactants": [5], "conditions": [16, 14], "products": [8]}, {"reactants": [8], "conditions": [20, 15], "products": [3]}], "diagram_type": "multiple"}, {"id": 540, "width": 1348, "height": 348, "file_name": "acs.orglett.6b00326-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [164.7, 106.45, 35.58, 43.71], "category_id": 2}, {"id": 1, "bbox": [10.0, 271.0, 1336.0, 77.0], "category_id": 4}, {"id": 2, "bbox": [1080.0, 210.0, 70.0, 46.0], "category_id": 3}, {"id": 3, "bbox": [978.0, 6.0, 201.0, 191.0], "category_id": 1}, {"id": 4, "bbox": [257.0, 203.0, 51.0, 38.0], "category_id": 3}, {"id": 5, "bbox": [711.0, 67.1, 205.0, 47.9], "category_id": 2}, {"id": 6, "bbox": [203.6, 43.0, 189.4, 149.0], "category_id": 1}, {"id": 7, "bbox": [481.0, 49.0, 160.0, 142.9], "category_id": 1}, {"id": 8, "bbox": [691.0, 125.0, 249.0, 49.0], "category_id": 2}, {"id": 9, "bbox": [541.0, 205.0, 52.0, 46.0], "category_id": 3}], "reactions": [{"reactants": [6, 7], "conditions": [5, 8], "products": [3]}], "corefs": [[6, 4], [7, 9], [3, 2]], "caption": "Table 1. Optimization of the Reaction Conditionsa", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 135, 366, 156], "ImageBB": [82, 162, 419, 249]}, "diagram_type": "single"}, {"id": 6, "width": 1348, "height": 828, "file_name": "jacs.5b05792-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [391.05, 111.24, 257.35, 87.47], "category_id": 2}, {"id": 1, "bbox": [94.04, 47.14, 252.0, 102.43], "category_id": 1}, {"id": 2, "bbox": [1058.79, 158.25, 50.08, 38.32], "category_id": 3}, {"id": 3, "bbox": [168.83, 206.33, 993.46, 519.1], "category_id": 4}, {"id": 4, "bbox": [998.96, 42.86, 250.94, 114.18], "category_id": 1}, {"id": 5, "bbox": [705.16, 14.02, 259.48, 141.96], "category_id": 1}, {"id": 6, "bbox": [367.55, 4.4, 288.32, 90.68], "category_id": 2}, {"id": 7, "bbox": [771.4, 156.11, 51.14, 40.46], "category_id": 3}, {"id": 8, "bbox": [149.59, 157.18, 50.08, 39.39], "category_id": 3}], "reactions": [{"reactants": [1], "conditions": [6, 0], "products": [5, 4]}], "corefs": [[1, 8], [5, 7], [4, 2]], "caption": "Table 1. 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Huang\u2019s prior synthesis of palau\u2019imide (10).11", "pdf": {"Page": 2, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [71, 970, 364, 986], "ImageBB": [71, 707, 773, 971]}, "diagram_type": "graph"}, {"id": 891, "width": 1352, "height": 368, "file_name": "acs.oprd.5b00137-Table-c9.png", "license": 0, "bboxes": [{"id": 0, "bbox": [439.0, 137.0, 229.0, 56.0], "category_id": 2}, {"id": 1, "bbox": [677.0, 32.0, 277.0, 145.0], "category_id": 1}, {"id": 2, "bbox": [444.0, 4.0, 211.0, 93.0], "category_id": 2}, {"id": 3, "bbox": [984.0, 26.0, 197.0, 129.9], "category_id": 1}, {"id": 4, "bbox": [164.3, 28.0, 273.7, 144.0], "category_id": 1}, {"id": 5, "bbox": [4.4, 214.85, 1340.99, 153.15], "category_id": 4}], "reactions": [{"reactants": [4], "conditions": [2, 0], "products": [1, 3]}], "corefs": [], "caption": "Table 9. Reusability of the SiliaCat Pt0 in the Selective Catalytic Hydrogenation of 4-Chloronitrobenzene [Reproduced with Permission from Ref 55, Copyright 2011 John Wiley and Sons] ", "pdf": {"Page": 10, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 92, 412, 155], "ImageBB": [82, 162, 420, 254]}, "diagram_type": "single"}, {"id": 602, "width": 2816, "height": 588, "file_name": "acs.oprd.6b00011-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1112.0, 444.0, 187.0, 43.0], "category_id": 2}, {"id": 1, "bbox": [1181.13, 391.62, 55.8, 49.0], "category_id": 3}, {"id": 2, "bbox": [737.26, 385.42, 52.5, 54.2], "category_id": 3}, {"id": 3, "bbox": [565.0, 4.0, 356.0, 336.0], "category_id": 1}, {"id": 4, "bbox": [1020.0, 46.0, 380.0, 262.0], "category_id": 1}, {"id": 5, "bbox": [1734.0, 4.0, 514.0, 389.0], "category_id": 1}, {"id": 6, "bbox": [1414.0, 94.0, 319.0, 89.0], "category_id": 2}, {"id": 7, "bbox": [1492.0, 243.0, 163.0, 76.0], "category_id": 2}, {"id": 8, "bbox": [1803.0, 397.0, 300.0, 40.0], "category_id": 3}, {"id": 9, "bbox": [5.0, 511.0, 2811.0, 77.0], "category_id": 4}], "reactions": [{"reactants": [3, 4], "conditions": [6, 7], "products": [5]}], "corefs": [[3, 2], [4, 1], [5, 8]], "caption": "Table 2. 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Conversion of Acid 27 to Akt Inhibitor 1", "pdf": {"Page": 6, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 378, 110], "ImageBB": [82, 116, 420, 612]}, "reactions": [{"reactants": [18], "conditions": [2, 19], "products": [20]}, {"reactants": [20], "conditions": [22, 12], "products": [0, 5]}, {"reactants": [0], "conditions": [6], "products": [5]}, {"reactants": [5], "conditions": [24, 15], "products": [25]}, {"reactants": [25], "conditions": [14, 11], "products": [23]}, {"reactants": [23], "conditions": [26, 17], "products": [21]}, {"reactants": [21], "conditions": [9], "products": [3, 1]}], "diagram_type": "multiple"}, {"id": 1099, "width": 1280, "height": 944, "file_name": "jo962200s-Scheme-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [618.55, 566.73, 459.75, 342.61], "category_id": 1}, {"id": 1, "bbox": [1238.38, 698.01, 41.62, 56.35], "category_id": 3}, {"id": 2, "bbox": [138.31, 132.56, 201.7, 129.35], "category_id": 1}, {"id": 3, "bbox": [851.63, 404.08, 40.98, 45.46], "category_id": 3}, {"id": 4, "bbox": [731.25, 94.78, 304.79, 283.04], "category_id": 1}, {"id": 5, "bbox": [0.0, 235.02, 37.78, 53.15], "category_id": 3}, {"id": 6, "bbox": [0.0, 572.5, 517.38, 302.9], "category_id": 1}, {"id": 7, "bbox": [242.04, 894.61, 51.87, 42.9], "category_id": 3}, {"id": 8, "bbox": [1051.41, 321.47, 188.25, 116.55], "category_id": 1}, {"id": 9, "bbox": [516.74, 407.92, 62.11, 46.11], "category_id": 3}, {"id": 10, "bbox": [413.01, 0.0, 290.7, 384.87], "category_id": 1}, {"id": 11, "bbox": [242.04, 329.15, 94.13, 57.64], "category_id": 2}, {"id": 12, "bbox": [779.27, 895.89, 64.03, 45.46], "category_id": 3}, {"id": 13, "bbox": [1142.06, 838.58, 79.33, 50.99], "category_id": 2}], "caption": "Scheme 3", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [572, 49, 635, 63], "ImageBB": [448, 69, 768, 305]}, "reactions": [{"reactants": [5, 2], "conditions": [], "products": [10, 11]}, {"reactants": [4], "conditions": [], "products": [10]}, {"reactants": [4], "conditions": [], "products": [8, 6]}, {"reactants": [6], "conditions": [], "products": [0]}, {"reactants": [0], "conditions": [], "products": [1, 13]}], "diagram_type": "tree"}, {"id": 235, "width": 1348, "height": 916, "file_name": "op000095p-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [483.86, 140.86, 39.88, 54.5], "category_id": 2}, {"id": 1, "bbox": [16.0, 381.0, 1332.0, 535.0], "category_id": 4}, {"id": 2, "bbox": [950.0, 0.0, 232.0, 343.0], "category_id": 1}, {"id": 3, "bbox": [621.4, 7.0, 239.9, 335.0], "category_id": 1}, {"id": 4, "bbox": [169.0, 1.0, 263.0, 343.0], "category_id": 1}], "reactions": [{"reactants": [4], "conditions": [0], "products": [3, 2]}], "corefs": [], "caption": "Table 2. Results from Oxidation of Benzylic Alcohols with the Modified Alkaline Nitrobenzene Method ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 496, 761, 524], "ImageBB": [439, 534, 776, 763]}, "diagram_type": "single"}, {"id": 23, "width": 1352, "height": 1096, "file_name": "ja905415r-Table-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [200.3, 6.42, 304.6, 238.17], "category_id": 1}, {"id": 1, "bbox": [3.73, 484.41, 1342.66, 605.86], "category_id": 4}, {"id": 2, "bbox": [566.58, 161.98, 229.68, 52.91], "category_id": 2}, {"id": 3, "bbox": [1016.29, 277.94, 88.27, 44.43], "category_id": 3}, {"id": 4, "bbox": [201.72, 286.43, 405.04, 188.67], "category_id": 3}, {"id": 5, "bbox": [540.42, 94.94, 284.83, 50.09], "category_id": 2}, {"id": 6, "bbox": [884.77, 3.59, 260.8, 255.14], "category_id": 1}], "reactions": [{"reactants": [0], "conditions": [5, 2], "products": [6]}], "corefs": [[0, 4]], "caption": "Table 4. Enantioselective Au(I)-Catalyzed Allenediene [4C+2C] Cycloadditions with (S,S,S)-I and (R,R,R)-Ka ", "pdf": {"Page": 6, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 57, 376, 81], "ImageBB": [58, 90, 396, 364]}, "diagram_type": "single"}, {"id": 1133, "width": 1352, "height": 1320, "file_name": "ol0002368-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [476.14, 401.88, 416.63, 332.88], "category_id": 1}, {"id": 1, "bbox": [476.14, 882.93, 421.36, 325.43], "category_id": 1}, {"id": 2, "bbox": [655.37, 1207.68, 50.05, 49.39], "category_id": 3}, {"id": 3, "bbox": [804.17, 2.71, 231.3, 294.98], "category_id": 1}, {"id": 4, "bbox": [37.2, 6.09, 234.01, 291.6], "category_id": 1}, {"id": 5, "bbox": [1114.61, 418.8, 66.28, 54.8], "category_id": 2}, {"id": 6, "bbox": [342.23, 58.19, 275.94, 188.08], "category_id": 1}, {"id": 7, "bbox": [656.05, 730.02, 54.11, 53.45], "category_id": 3}, {"id": 8, "bbox": [131.21, 284.16, 41.26, 50.74], "category_id": 3}, {"id": 9, "bbox": [1083.49, 282.13, 41.94, 52.77], "category_id": 3}, {"id": 10, "bbox": [246.86, 418.8, 70.34, 52.09], "category_id": 2}, {"id": 11, "bbox": [472.76, 283.48, 47.34, 51.42], "category_id": 3}, {"id": 12, "bbox": [1067.26, 2.03, 253.63, 236.8], "category_id": 1}], "caption": "Scheme 1", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [212, 410, 265, 423], "ImageBB": [73, 429, 411, 759]}, "reactions": [{"reactants": [4, 6], "conditions": [], "products": [3, 12]}, {"reactants": [3, 12], "conditions": [], "products": [4, 6]}, {"reactants": [4, 6], "conditions": [], "products": [0]}, {"reactants": [4, 6], "conditions": [], "products": [1]}, {"reactants": [3, 12], "conditions": [], "products": [0]}], "diagram_type": "graph"}, {"id": 515, "width": 1344, "height": 868, "file_name": "jo025987x-Figure-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [341.0, 274.0, 244.0, 106.0], "category_id": 3}, {"id": 1, "bbox": [1039.0, 274.0, 86.0, 52.9], "category_id": 3}, {"id": 2, "bbox": [874.0, 1.0, 252.0, 353.0], "category_id": 1}, {"id": 3, "bbox": [0.0, 403.0, 1344.0, 465.0], "category_id": 4}, {"id": 4, "bbox": [556.0, 30.0, 325.0, 93.0], "category_id": 2}, {"id": 5, "bbox": [446.0, 98.0, 113.0, 56.0], "category_id": 2}, {"id": 6, "bbox": [203.0, 7.0, 193.0, 367.0], "category_id": 1}, {"id": 7, "bbox": [557.0, 130.0, 279.0, 57.0], "category_id": 2}], "reactions": [{"reactants": [6, 5], "conditions": [4, 7], "products": [2]}], "corefs": [[6, 0], [2, 1]], "caption": "Figure 2. d No separation by chiral HPLC.", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [100, 315, 321, 328], "ImageBB": [74, 99, 410, 316]}, "diagram_type": "single"}, {"id": 1083, "width": 1356, "height": 912, "file_name": "jo501785d-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [4.07, 185.77, 232.67, 168.14], "category_id": 1}, {"id": 1, "bbox": [1213.55, 584.42, 51.55, 54.24], "category_id": 3}, {"id": 2, "bbox": [705.47, 31.19, 93.61, 55.59], "category_id": 2}, {"id": 3, "bbox": [752.96, 18.31, 354.09, 246.78], "category_id": 1}, {"id": 4, "bbox": [496.54, 820.36, 59.7, 50.85], "category_id": 3}, {"id": 5, "bbox": [274.73, 565.44, 125.49, 54.92], "category_id": 2}, {"id": 6, "bbox": [802.48, 336.96, 282.86, 94.92], "category_id": 2}, {"id": 7, "bbox": [330.35, 0.0, 346.63, 284.75], "category_id": 1}, {"id": 8, "bbox": [314.75, 528.15, 347.31, 287.47], "category_id": 1}, {"id": 9, "bbox": [515.54, 280.69, 45.45, 51.52], "category_id": 3}, {"id": 10, "bbox": [96.32, 429.84, 44.77, 50.85], "category_id": 2}, {"id": 11, "bbox": [1086.02, 656.29, 184.51, 96.95], "category_id": 2}, {"id": 12, "bbox": [997.16, 346.45, 352.73, 244.75], "category_id": 1}, {"id": 13, "bbox": [847.25, 817.65, 43.41, 50.17], "category_id": 3}, {"id": 14, "bbox": [69.19, 674.59, 44.77, 50.18], "category_id": 3}, {"id": 15, "bbox": [258.73, 289.06, 122.62, 45.98], "category_id": 2}, {"id": 16, "bbox": [953.74, 262.38, 40.71, 48.81], "category_id": 3}, {"id": 17, "bbox": [150.59, 372.89, 301.86, 134.24], "category_id": 1}, {"id": 18, "bbox": [700.72, 625.78, 347.99, 223.73], "category_id": 1}, {"id": 19, "bbox": [4.07, 521.37, 228.6, 158.65], "category_id": 1}, {"id": 20, "bbox": [69.19, 343.06, 44.77, 46.1], "category_id": 3}], "caption": "Scheme 1. Possible Reaction Pathways of Rhodium\u2212 Carbene A with \u03b2-Enamino Ester 2 ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 491, 748, 522], "ImageBB": [448, 527, 787, 755]}, "reactions": [{"reactants": [19], "conditions": [], "products": [0]}, {"reactants": [0], "conditions": [10], "products": [19]}, {"reactants": [0, 17], "conditions": [], "products": [7]}, {"reactants": [19, 17], "conditions": [], "products": [8]}, {"reactants": [7], "conditions": [], "products": [8]}, {"reactants": [8], "conditions": [], "products": [7]}, {"reactants": [7], "conditions": [], "products": [2, 3]}, {"reactants": [3], "conditions": [], "products": [12]}, {"reactants": [12], "conditions": [6], "products": [3]}, {"reactants": [12], "conditions": [11], "products": [18]}], "diagram_type": "graph"}, {"id": 958, "width": 1348, "height": 1320, "file_name": "ja011003u-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1001.39, 897.76, 59.34, 49.24], "category_id": 3}, {"id": 1, "bbox": [267.71, 1264.01, 57.99, 47.89], "category_id": 3}, {"id": 2, "bbox": [215.11, 362.21, 185.45, 47.88], "category_id": 3}, {"id": 3, "bbox": [759.3, 503.18, 584.65, 366.92], "category_id": 1}, {"id": 4, "bbox": [0.0, 6.74, 587.35, 295.44], "category_id": 1}, {"id": 5, "bbox": [54.62, 823.56, 545.54, 396.61], "category_id": 1}], "caption": "Scheme 1. Schematic Representation of the Potential Interconversion from Neutral [Hg(arene)2(AlCl4)2] (cf, 1 and 3) to Cationic [Hg(arene)2(AlCl4)2]+ (cf., 5) via an Asymmetrical Complex (cf, 7) ", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 65, 770, 120], "ImageBB": [440, 125, 777, 455]}, "reactions": [{"reactants": [4], "conditions": [], "products": [3]}, {"reactants": [3], "conditions": [], "products": [5]}], "diagram_type": "tree"}, {"id": 1220, "width": 1224, "height": 1020, "file_name": "op010052o-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [0.0, 116.32, 199.61, 361.21], "category_id": 1}, {"id": 1, "bbox": [947.85, 347.13, 243.09, 109.58], "category_id": 2}, {"id": 2, "bbox": [56.94, 478.75, 37.36, 45.31], "category_id": 3}, {"id": 3, "bbox": [720.07, 576.09, 503.93, 377.13], "category_id": 1}, {"id": 4, "bbox": [204.51, 346.51, 245.54, 64.29], "category_id": 2}, {"id": 5, "bbox": [443.92, 90.61, 504.54, 375.9], "category_id": 1}, {"id": 6, "bbox": [539.44, 784.86, 194.1, 58.77], "category_id": 2}, {"id": 7, "bbox": [309.83, 254.07, 44.7, 48.36], "category_id": 3}, {"id": 8, "bbox": [792.32, 476.91, 41.03, 43.47], "category_id": 3}, {"id": 9, "bbox": [303.09, 966.69, 43.48, 47.14], "category_id": 3}, {"id": 10, "bbox": [947.85, 965.46, 39.8, 46.53], "category_id": 3}, {"id": 11, "bbox": [20.21, 580.99, 505.15, 372.84], "category_id": 1}, {"id": 12, "bbox": [263.9, 2.45, 149.41, 247.95], "category_id": 1}], "caption": "Scheme 1. Reported synthesis of 6", "pdf": {"Page": 1, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 269, 639, 283], "ImageBB": [455, 288, 761, 543]}, "reactions": [{"reactants": [0, 12], "conditions": [4], "products": [5]}, {"reactants": [5], "conditions": [1], "products": [11]}, {"reactants": [11], "conditions": [6], "products": [3]}], "diagram_type": "multiple"}, {"id": 782, "width": 1032, "height": 1784, "file_name": "jo502752u-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [680.0, 0.0, 168.0, 106.0], "category_id": 1}, {"id": 1, "bbox": [387.0, 1544.0, 247.0, 126.0], "category_id": 1}, {"id": 2, "bbox": [723.7, 730.6, 198.3, 155.6], "category_id": 1}, {"id": 3, "bbox": [764.6, 1309.2, 202.4, 154.0], "category_id": 1}, {"id": 4, "bbox": [348.8, 1038.8, 275.2, 159.6], "category_id": 1}, {"id": 5, "bbox": [42.0, 719.0, 215.1, 166.7], "category_id": 1}, {"id": 6, "bbox": [675.0, 394.0, 245.5, 150.5], "category_id": 1}, {"id": 7, "bbox": [64.8, 1546.4, 187.1, 116.4], "category_id": 1}, {"id": 8, "bbox": [648.0, 1568.6, 348.3, 95.1], "category_id": 1}, {"id": 9, "bbox": [373.0, 14.6, 241.0, 44.3], "category_id": 2}, {"id": 10, "bbox": [648.0, 1023.0, 273.3, 181.4], "category_id": 1}, {"id": 11, "bbox": [76.5, 1307.4, 208.8, 153.3], "category_id": 1}, {"id": 12, "bbox": [420.3, 1309.4, 208.4, 153.0], "category_id": 1}, {"id": 13, "bbox": [3.2, 1034.7, 278.6, 161.3], "category_id": 1}, {"id": 14, "bbox": [395.0, 397.0, 228.2, 149.4], "category_id": 1}, {"id": 15, "bbox": [12.0, 394.0, 247.4, 156.8], "category_id": 1}, {"id": 16, "bbox": [716.9, 100.39, 100.44, 40.65], "category_id": 3}, {"id": 17, "bbox": [357.0, 724.4, 269.0, 147.6], "category_id": 1}, {"id": 18, "bbox": [60.2, 170.8, 204.0, 151.2], "category_id": 1}, {"id": 19, "bbox": [681.0, 166.8, 239.4, 161.6], "category_id": 1}, {"id": 20, "bbox": [45.0, 902.0, 201.2, 56.9], "category_id": 3}, {"id": 21, "bbox": [406.01, 62.13, 129.14, 81.31], "category_id": 2}, {"id": 22, "bbox": [352.0, 169.0, 271.5, 155.4], "category_id": 1}, {"id": 23, "bbox": [413.0, 1675.0, 211.0, 48.0], "category_id": 3}, {"id": 24, "bbox": [85.0, 1683.0, 285.0, 86.0], "category_id": 3}, {"id": 25, "bbox": [686.0, 1468.0, 323.0, 73.0], "category_id": 3}, {"id": 26, "bbox": [419.0, 1466.0, 192.0, 45.0], "category_id": 3}, {"id": 27, "bbox": [83.0, 1462.0, 194.0, 49.0], "category_id": 3}, {"id": 28, "bbox": [759.0, 1210.0, 188.0, 41.0], "category_id": 3}, {"id": 29, "bbox": [413.0, 1212.0, 224.0, 43.0], "category_id": 3}, {"id": 30, "bbox": [83.0, 1204.0, 179.0, 45.0], "category_id": 3}, {"id": 31, "bbox": [700.1, 909.0, 218.9, 75.0], "category_id": 3}, {"id": 32, "bbox": [678.0, 603.0, 301.0, 86.0], "category_id": 3}, {"id": 33, "bbox": [344.0, 567.0, 295.0, 150.0], "category_id": 3}, {"id": 34, "bbox": [16.0, 562.0, 276.0, 112.0], "category_id": 3}, {"id": 35, "bbox": [751.0, 338.0, 174.0, 37.0], "category_id": 3}, {"id": 36, "bbox": [417.0, 336.0, 203.0, 39.0], "category_id": 3}, {"id": 37, "bbox": [61.0, 335.0, 194.0, 34.0], "category_id": 3}, {"id": 38, "bbox": [333.0, 876.0, 295.0, 150.6], "category_id": 3}, {"id": 39, "bbox": [153.1, 42.0, 130.9, 40.0], "category_id": 1}, {"id": 40, "bbox": [755.0, 1675.0, 206.3, 52.3], "category_id": 3}], "reactions": [{"reactants": [39], "conditions": [9, 21], "products": [0]}], "corefs": [[0, 16], [18, 37], [22, 36], [19, 35], [15, 34], [14, 33], [6, 32], [5, 20], [17, 38], [2, 31], [13, 30], [4, 29], [10, 28], [11, 27], [12, 26], [3, 25], [7, 24], [1, 23], [8, 40]], "caption": "Table 2. KOtBu-Promoted Hydration of the Nitriles", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 90, 743, 110], "ImageBB": [488, 116, 746, 562]}, "diagram_type": "single"}, {"id": 789, "width": 1352, "height": 2364, "file_name": "jo501910q-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [669.54, 735.13, 129.92, 72.89], "category_id": 3}, {"id": 1, "bbox": [551.0, 1827.0, 408.0, 307.0], "category_id": 1}, {"id": 2, "bbox": [745.59, 224.94, 120.42, 60.21], "category_id": 3}, {"id": 3, "bbox": [311.45, 215.43, 129.93, 57.04], "category_id": 3}, {"id": 4, "bbox": [573.0, 1276.8, 333.2, 365.4], "category_id": 1}, {"id": 5, "bbox": [65.0, 1307.3, 377.7, 306.2], "category_id": 1}, {"id": 6, "bbox": [873.7, 856.2, 338.8, 310.0], "category_id": 1}, {"id": 7, "bbox": [431.5, 858.5, 347.0, 307.5], "category_id": 1}, {"id": 8, "bbox": [81.0, 1615.5, 636.8, 197.5], "category_id": 3}, {"id": 9, "bbox": [108.5, 852.5, 278.1, 311.9], "category_id": 1}, {"id": 10, "bbox": [398.0, 426.6, 387.9, 382.4], "category_id": 1}, {"id": 11, "bbox": [915.0, 1627.0, 404.0, 95.0], "category_id": 3}, {"id": 12, "bbox": [977.0, 2130.0, 229.0, 69.0], "category_id": 3}, {"id": 13, "bbox": [500.0, 1583.0, 199.1, 57.8], "category_id": 3}, {"id": 14, "bbox": [96.2, 1160.18, 340.1, 159.12], "category_id": 3}, {"id": 15, "bbox": [469.34, 1158.34, 343.0, 117.0], "category_id": 3}, {"id": 16, "bbox": [822.32, 1156.83, 383.88, 110.47], "category_id": 3}, {"id": 17, "bbox": [660.0, 2145.14, 233.0, 44.0], "category_id": 3}, {"id": 18, "bbox": [138.2, 2205.5, 739.6, 120.7], "category_id": 3}, {"id": 19, "bbox": [959.49, 1805.2, 331.01, 322.46], "category_id": 1}, {"id": 20, "bbox": [255.4, 65.0, 338.6, 159.6], "category_id": 1}, {"id": 21, "bbox": [634.35, 3.83, 301.25, 229.47], "category_id": 1}, {"id": 22, "bbox": [618.32, 295.83, 473.0, 120.0], "category_id": 2}, {"id": 23, "bbox": [138.4, 1813.8, 411.6, 386.8], "category_id": 1}, {"id": 24, "bbox": [949.5, 1315.7, 333.1, 308.1], "category_id": 1}], "reactions": [{"reactants": [20, 21], "conditions": [22], "products": [10]}], "corefs": [[20, 3], [21, 2], [10, 0], [9, 14], [7, 15], [6, 16], [5, 8], [4, 13], [24, 11], [23, 18], [1, 17], [19, 12]], "caption": "Table 2. Synthesis of Various Substituted 5,6- Dihydrophenanthridines ", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 233, 340, 263], "ImageBB": [82, 269, 420, 860]}, "diagram_type": "tree"}, {"id": 130, "width": 1356, "height": 984, "file_name": "op900102a-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [180.0, 129.0, 273.0, 67.0], "category_id": 1}, {"id": 1, "bbox": [6.0, 226.0, 1350.0, 758.0], "category_id": 4}, {"id": 2, "bbox": [516.0, 5.0, 307.0, 79.0], "category_id": 2}, {"id": 3, "bbox": [515.0, 103.0, 271.0, 84.0], "category_id": 2}, {"id": 4, "bbox": [113.0, 0.0, 351.0, 46.0], "category_id": 1}, {"id": 5, "bbox": [918.4, 10.5, 321.8, 167.5], "category_id": 1}], "reactions": [{"reactants": [4], "conditions": [2, 3], "products": [5]}, {"reactants": [0], "conditions": [2, 3], "products": [5]}], "corefs": [], "caption": "Table 3. Silanation and nucleophilic substitution of (3-bromopropyl)trimethoxysilane or (3-bromopropyl)- trichlorosilane to S3x ", "pdf": {"Page": 2, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [425, 462, 720, 503], "ImageBB": [424, 515, 763, 761]}, "diagram_type": "single"}, {"id": 1221, "width": 1080, "height": 1036, "file_name": "op010052o-Scheme-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [388.21, 567.18, 315.9, 38.55], "category_id": 3}, {"id": 1, "bbox": [499.75, 358.65, 233.4, 45.37], "category_id": 2}, {"id": 2, "bbox": [341.99, 267.37, 170.73, 241.44], "category_id": 1}, {"id": 3, "bbox": [245.28, 649.79, 440.32, 314.9], "category_id": 1}, {"id": 4, "bbox": [102.65, 860.98, 81.04, 39.97], "category_id": 2}, {"id": 5, "bbox": [8.64, 286.81, 116.16, 218.22], "category_id": 1}, {"id": 6, "bbox": [45.92, 522.32, 30.26, 34.02], "category_id": 3}, {"id": 7, "bbox": [571.07, 305.72, 43.22, 34.03], "category_id": 3}, {"id": 8, "bbox": [897.93, 521.78, 24.31, 32.94], "category_id": 3}, {"id": 9, "bbox": [128.04, 278.71, 215.57, 124.23], "category_id": 2}, {"id": 10, "bbox": [555.94, 435.89, 73.47, 36.19], "category_id": 2}, {"id": 11, "bbox": [388.45, 527.18, 32.42, 35.65], "category_id": 3}, {"id": 12, "bbox": [179.37, 436.43, 76.18, 37.81], "category_id": 2}, {"id": 13, "bbox": [24.4, 779.96, 257.08, 51.32], "category_id": 2}, {"id": 14, "bbox": [429.6, 948.1, 32.8, 39.1], "category_id": 3}, {"id": 15, "bbox": [522.98, 3.24, 135.92, 304.96], "category_id": 1}, {"id": 16, "bbox": [429.25, 990.04, 340.78, 37.31], "category_id": 3}, {"id": 17, "bbox": [645.66, 237.6, 429.07, 310.92], "category_id": 1}], "caption": "Scheme 2", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 53, 135, 67], "ImageBB": [107, 72, 377, 331]}, "reactions": [{"reactants": [5], "conditions": [9, 12], "products": [2]}, {"reactants": [2, 15], "conditions": [1, 10], "products": [17]}, {"reactants": [17], "conditions": [13, 4], "products": [3]}], "diagram_type": "multiple"}, {"id": 1366, "width": 1252, "height": 1412, "file_name": "op960008m-Scheme-c7.png", "license": 0, "bboxes": [{"id": 0, "bbox": [91.12, 990.31, 201.3, 100.3], "category_id": 1}, {"id": 1, "bbox": [16.95, 244.4, 40.26, 52.27], "category_id": 3}, {"id": 2, "bbox": [1016.4, 763.57, 113.01, 61.45], "category_id": 2}, {"id": 3, "bbox": [702.09, 1276.38, 237.32, 120.79], "category_id": 1}, {"id": 4, "bbox": [1104.69, 1031.98, 109.48, 61.45], "category_id": 2}, {"id": 5, "bbox": [437.21, 210.49, 110.9, 55.81], "category_id": 2}, {"id": 6, "bbox": [119.37, 206.26, 199.18, 95.35], "category_id": 1}, {"id": 7, "bbox": [466.88, 1285.56, 114.42, 60.75], "category_id": 2}, {"id": 8, "bbox": [692.9, 362.36, 332.68, 199.19], "category_id": 1}, {"id": 9, "bbox": [784.73, 973.35, 226.02, 152.58], "category_id": 1}, {"id": 10, "bbox": [692.9, 0.0, 313.61, 195.66], "category_id": 1}, {"id": 11, "bbox": [394.84, 1080.72, 355.28, 55.8], "category_id": 2}, {"id": 12, "bbox": [0.0, 1038.34, 43.79, 57.21], "category_id": 3}, {"id": 13, "bbox": [489.48, 986.78, 132.09, 60.04], "category_id": 2}, {"id": 14, "bbox": [1017.11, 1323.71, 90.41, 62.86], "category_id": 2}, {"id": 15, "bbox": [0.0, 1335.8, 45.8, 52.89], "category_id": 3}, {"id": 16, "bbox": [1161.9, 765.69, 90.1, 59.33], "category_id": 2}, {"id": 17, "bbox": [445.69, 665.38, 171.64, 70.64], "category_id": 2}, {"id": 18, "bbox": [696.96, 713.34, 216.54, 143.75], "category_id": 1}, {"id": 19, "bbox": [108.07, 1278.5, 198.47, 101.01], "category_id": 1}, {"id": 20, "bbox": [464.06, 1363.97, 115.13, 48.03], "category_id": 2}], "caption": "Scheme 7. Routes to propylene oxide", "pdf": {"Page": 11, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [73, 171, 287, 185], "ImageBB": [85, 190, 398, 543]}, "reactions": [{"reactants": [6], "conditions": [5], "products": [10, 8]}, {"reactants": [10, 8, 17], "conditions": [], "products": [18, 2, 16]}, {"reactants": [0], "conditions": [13, 11], "products": [9, 4]}, {"reactants": [19], "conditions": [7, 20], "products": [3, 14]}], "diagram_type": "multiple"}, {"id": 328, "width": 1480, "height": 3744, "file_name": "ol300842d-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [503.0, 62.0, 194.0, 67.0], "category_id": 2}, {"id": 1, "bbox": [499.0, 133.0, 202.0, 51.0], "category_id": 2}, {"id": 2, "bbox": [274.0, 250.0, 35.0, 49.0], "category_id": 3}, {"id": 3, "bbox": [849.0, 246.0, 88.0, 53.0], "category_id": 3}, {"id": 4, "bbox": [1192.0, 250.0, 101.0, 45.0], "category_id": 3}, {"id": 5, "bbox": [147.0, 382.0, 1310.0, 2932.0], "category_id": 4}, {"id": 6, "bbox": [115.0, 3364.0, 1365.0, 380.0], "category_id": 2}, {"id": 7, "bbox": [1127.0, 0.0, 308.0, 246.0], "category_id": 1}, {"id": 8, "bbox": [163.0, 0.0, 336.0, 233.0], "category_id": 1}, {"id": 9, "bbox": [711.0, 0.0, 383.0, 254.0], "category_id": 1}], "reactions": [{"reactants": [8], "conditions": [0, 1], "products": [9]}, {"reactants": [8], "conditions": [0, 1], "products": [7]}], "corefs": [[8, 2], [9, 3], [7, 4]], "caption": "Table 2. LDA-Mediated Regioselective Thia-Fries Rearrange- ment of Various Oxindole and Pyrazolone Derivatives ", "pdf": {"Page": 3, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 87, 768, 114], "ImageBB": [404, 126, 774, 1062]}, "diagram_type": "single"}, {"id": 314, "width": 1344, "height": 1004, "file_name": "ol3023903-Figure-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [579.0, 287.0, 203.0, 63.0], "category_id": 2}, {"id": 1, "bbox": [589.0, 669.0, 242.0, 30.0], "category_id": 3}, {"id": 2, "bbox": [980.0, 723.0, 338.0, 35.0], "category_id": 3}, {"id": 3, "bbox": [129.0, 916.0, 236.0, 37.0], "category_id": 3}, {"id": 4, "bbox": [338.0, 164.0, 217.0, 179.0], "category_id": 1}, {"id": 5, "bbox": [507.0, 963.0, 336.0, 36.0], "category_id": 3}, {"id": 6, "bbox": [1001.0, 940.0, 229.0, 34.0], "category_id": 3}, {"id": 7, "bbox": [967.0, 410.0, 295.0, 295.0], "category_id": 1}, {"id": 8, "bbox": [384.72, 341.51, 31.05, 36.23], "category_id": 3}, {"id": 9, "bbox": [873.78, 338.92, 40.11, 33.64], "category_id": 3}, {"id": 10, "bbox": [458.3, 743.6, 406.7, 216.8], "category_id": 1}, {"id": 11, "bbox": [839.8, 213.1, 110.6, 125.9], "category_id": 1}, {"id": 12, "bbox": [600.4, 172.1, 150.3, 88.9], "category_id": 1}, {"id": 13, "bbox": [89.0, 723.2, 322.1, 192.8], "category_id": 1}, {"id": 14, "bbox": [983.6, 778.9, 296.1, 146.6], "category_id": 1}, {"id": 15, "bbox": [134.0, 616.0, 272.0, 33.0], "category_id": 3}, {"id": 16, "bbox": [568.6, 428.9, 270.9, 227.8], "category_id": 1}, {"id": 17, "bbox": [81.6, 478.0, 431.4, 142.0], "category_id": 1}], "reactions": [{"reactants": [4], "conditions": [12, 0], "products": [11]}], "corefs": [[4, 8], [11, 9], [17, 15], [16, 1], [7, 2], [13, 3], [10, 5], [14, 6]], "caption": "Figure 4. Scope of the radical olefination for vinyl fluorides. Reaction conditions: olefin (2 equiv), xanthate (1 equiv), lauroyl peroxide was added in 30 mol % portions (with respect to the xanthate) every hour (5 7 h). For 10c, the reaction was run in refluxing DCE. ", "pdf": {"Page": 4, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 322, 771, 391], "ImageBB": [437, 58, 773, 309]}, "diagram_type": "single"}, {"id": 225, "width": 1344, "height": 1132, "file_name": "op0155211-Figure-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [979.0, 398.4, 170.0, 226.6], "category_id": 1}, {"id": 1, "bbox": [19.0, 176.54, 169.0, 147.0], "category_id": 1}, {"id": 2, "bbox": [907.0, 166.6, 250.4, 147.9], "category_id": 1}, {"id": 3, "bbox": [95.0, 458.4, 258.4, 158.6], "category_id": 1}, {"id": 4, "bbox": [376.92, 168.29, 136.0, 148.0], "category_id": 1}, {"id": 5, "bbox": [715.0, 197.0, 75.0, 48.1], "category_id": 2}, {"id": 6, "bbox": [925.2, 841.0, 355.9, 198.6], "category_id": 1}, {"id": 7, "bbox": [506.0, 1083.0, 53.0, 46.0], "category_id": 3}, {"id": 8, "bbox": [166.0, 1074.0, 62.0, 53.0], "category_id": 3}, {"id": 9, "bbox": [435.0, 822.0, 186.0, 211.0], "category_id": 1}, {"id": 10, "bbox": [5.0, 801.0, 282.0, 227.0], "category_id": 1}, {"id": 11, "bbox": [710.0, 263.0, 90.0, 42.0], "category_id": 2}, {"id": 12, "bbox": [707.0, 498.0, 88.0, 41.0], "category_id": 2}, {"id": 13, "bbox": [710.0, 569.0, 80.0, 46.0], "category_id": 2}, {"id": 14, "bbox": [704.0, 870.0, 88.0, 40.0], "category_id": 2}, {"id": 15, "bbox": [704.0, 947.0, 99.0, 41.0], "category_id": 2}, {"id": 16, "bbox": [1060.0, 319.0, 56.0, 52.0], "category_id": 3}, {"id": 17, "bbox": [247.0, 633.0, 58.0, 51.0], "category_id": 3}, {"id": 18, "bbox": [1185.5, 224.62, 81.69, 52.51], "category_id": 1}, {"id": 19, "bbox": [354.01, 530.96, 78.77, 56.89], "category_id": 1}, {"id": 20, "bbox": [1268.65, 897.11, 75.35, 58.35], "category_id": 1}, {"id": 21, "bbox": [1058.0, 639.0, 61.0, 44.0], "category_id": 3}, {"id": 22, "bbox": [1058.0, 1078.0, 62.0, 49.0], "category_id": 3}], "reactions": [{"reactants": [1, 4], "conditions": [5, 11], "products": [2, 18]}, {"reactants": [3, 19], "conditions": [12, 13], "products": [0]}, {"reactants": [10, 9], "conditions": [14, 15], "products": [6, 20]}], "corefs": [[2, 16], [3, 17], [0, 21], [10, 8], [9, 7], [6, 22]], "caption": "Figure 2. Process of kinetic data extraction.", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 528, 687, 542], "ImageBB": [440, 551, 776, 834]}, "diagram_type": "tree"}, {"id": 96, "width": 1476, "height": 2592, "file_name": "ja042849b-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [410.07, 1736.83, 58.52, 27.84], "category_id": 2}, {"id": 1, "bbox": [886.51, 1806.28, 56.91, 27.84], "category_id": 2}, {"id": 2, "bbox": [1227.29, 1950.02, 139.31, 66.6], "category_id": 2}, {"id": 3, "bbox": [1413.02, 1969.4, 56.88, 27.84], "category_id": 2}, {"id": 4, "bbox": [731.46, 2174.52, 237.8, 32.68], "category_id": 2}, {"id": 5, "bbox": [728.23, 2373.17, 363.77, 31.07], "category_id": 2}, {"id": 6, "bbox": [729.85, 2268.19, 26.22, 31.07], "category_id": 2}, {"id": 7, "bbox": [222.72, 1869.27, 18.15, 27.84], "category_id": 3}, {"id": 8, "bbox": [497.28, 1867.65, 19.76, 27.85], "category_id": 3}, {"id": 9, "bbox": [1101.31, 1589.87, 344.39, 255.56], "category_id": 1}, {"id": 10, "bbox": [768.61, 1618.94, 292.71, 76.29], "category_id": 1}, {"id": 11, "bbox": [922.0, 1932.3, 268.52, 100.48], "category_id": 1}, {"id": 12, "bbox": [203.34, 2098.61, 444.53, 331.47], "category_id": 1}, {"id": 13, "bbox": [775.07, 2239.12, 200.65, 118.28], "category_id": 1}, {"id": 14, "bbox": [1099.7, 2096.99, 350.85, 257.18], "category_id": 1}, {"id": 15, "bbox": [361.62, 1601.17, 163.5, 102.13], "category_id": 2}, {"id": 16, "bbox": [130.66, 1589.87, 184.5, 255.56], "category_id": 1}, {"id": 17, "bbox": [557.04, 1589.87, 186.11, 255.56], "category_id": 1}, {"id": 18, "bbox": [196.19, 2446.31, 530.3, 138.89], "category_id": 4}, {"id": 19, "bbox": [879.27, 1426.11, 566.92, 39.14], "category_id": 2}, {"id": 20, "bbox": [135.58, 1427.37, 575.76, 37.88], "category_id": 2}, {"id": 21, "bbox": [799.72, 905.91, 665.41, 500.0], "category_id": 1}, {"id": 22, "bbox": [139.37, 952.63, 546.72, 369.95], "category_id": 1}, {"id": 23, "bbox": [1196.6, 1866.04, 18.15, 27.84], "category_id": 3}, {"id": 24, "bbox": [1256.36, 2378.01, 19.76, 26.23], "category_id": 3}, {"id": 25, "bbox": [859.05, 1725.53, 127.95, 63.37], "category_id": 2}], "reactions": [{"reactants": [16], "conditions": [15, 0], "products": [17]}, {"reactants": [17], "conditions": [10, 25, 1], "products": [9]}, {"reactants": [9], "conditions": [11, 2, 3], "products": [14]}, {"reactants": [14], "conditions": [4, 6, 13, 5], "products": [12]}], "corefs": [[22, 20], [21, 19], [16, 7], [17, 8], [9, 23], [14, 24], [12, 18]], "caption": "Table 1. Turnover Numbers for the Dismutation of H2O2 Catalyzed by Manganese Salophen Complexes ", "pdf": {"Page": 1, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 701, 723, 725], "ImageBB": [408, 42, 777, 690]}, "diagram_type": "multiple"}, {"id": 186, "width": 1232, "height": 636, "file_name": "op0601619-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1000.0, 295.0, 194.0, 81.0], "category_id": 3}, {"id": 1, "bbox": [565.0, 164.0, 364.0, 123.0], "category_id": 2}, {"id": 2, "bbox": [574.0, 7.0, 297.0, 122.0], "category_id": 2}, {"id": 3, "bbox": [429.0, 118.0, 79.0, 62.0], "category_id": 2}, {"id": 4, "bbox": [506.6, 400.9, 475.4, 232.1], "category_id": 2}, {"id": 5, "bbox": [916.4, 0.0, 309.6, 286.4], "category_id": 1}, {"id": 6, "bbox": [3.0, 6.0, 321.1, 281.1], "category_id": 1}, {"id": 7, "bbox": [139.2, 378.5, 340.4, 235.4], "category_id": 1}, {"id": 8, "bbox": [122.0, 306.77, 133.0, 52.0], "category_id": 3}], "reactions": [{"reactants": [6, 3], "conditions": [2, 1], "products": [5]}], "corefs": [[6, 8], [5, 0]], "caption": "Figure 1. Reaction conditions and structure of the phosphine- oxazoline ligands. 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The catalytically active", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [577, 136, 774, 150], "ImageBB": [440, 156, 757, 319]}, "reactions": [{"reactants": [9], "conditions": [], "products": [4]}, {"reactants": [4], "conditions": [2], "products": [6]}, {"reactants": [6], "conditions": [], "products": [1]}, {"reactants": [1], "conditions": [3], "products": [0]}, {"reactants": [0], "conditions": [], "products": [8]}], "diagram_type": "multiple"}, {"id": 1043, "width": 1064, "height": 1372, "file_name": "jo010297z-Scheme-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [85.77, 1008.92, 236.05, 274.54], "category_id": 1}, {"id": 1, "bbox": [733.53, 1059.71, 50.09, 61.77], "category_id": 3}, {"id": 2, "bbox": [0.0, 383.67, 185.95, 179.13], "category_id": 1}, {"id": 3, "bbox": [932.21, 713.15, 126.83, 62.59], "category_id": 2}, {"id": 4, "bbox": [933.86, 167.98, 126.82, 64.23], "category_id": 2}, {"id": 5, "bbox": [271.04, 481.13, 143.41, 58.34], "category_id": 2}, {"id": 6, "bbox": [472.78, 1094.03, 89.89, 72.07], "category_id": 2}, {"id": 7, "bbox": [534.53, 313.66, 54.9, 54.22], "category_id": 3}, {"id": 8, "bbox": [391.81, 0.0, 275.16, 301.99], "category_id": 1}, {"id": 9, "bbox": [380.14, 586.82, 283.4, 291.7], "category_id": 1}, {"id": 10, "bbox": [514.64, 893.62, 46.66, 59.02], "category_id": 3}, {"id": 11, "bbox": [426.8, 1188.06, 210.66, 64.52], "category_id": 2}, {"id": 12, "bbox": [803.52, 1057.65, 127.63, 66.58], "category_id": 2}, {"id": 13, "bbox": [0.0, 1371.31, 8.92, 0.69], "category_id": 3}, {"id": 14, "bbox": [867.33, 713.8, 53.37, 63.8], "category_id": 3}, {"id": 15, "bbox": [733.53, 1227.87, 51.27, 59.02], "category_id": 3}, {"id": 16, "bbox": [867.33, 167.47, 46.77, 65.03], "category_id": 3}, {"id": 17, "bbox": [803.74, 1227.04, 125.18, 60.94], "category_id": 2}, {"id": 18, "bbox": [188.7, 1311.6, 40.48, 54.22], "category_id": 3}, {"id": 19, "bbox": [299.17, 402.88, 76.17, 49.42], "category_id": 2}], "caption": "       Scheme 2. Synthesis of Novel Spiromethanofullerenes from Diazo Compounds ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [449, 64, 765, 92], "ImageBB": [475, 97, 741, 440]}, "reactions": [{"reactants": [2], "conditions": [19, 5, 8], "products": [16]}, {"reactants": [2], "conditions": [19, 5, 9], "products": [14]}, {"reactants": [0], "conditions": [6, 11], "products": [1, 15]}], "diagram_type": "tree"}, {"id": 284, "width": 1352, "height": 1448, "file_name": "ol800086s-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [476.0, 198.0, 34.0, 52.0], "category_id": 3}, {"id": 1, "bbox": [12.0, 254.0, 1340.0, 1194.0], "category_id": 4}, {"id": 2, "bbox": [1084.0, 207.0, 35.0, 40.0], "category_id": 3}, {"id": 3, "bbox": [119.0, 201.0, 51.7, 40.0], "category_id": 3}, {"id": 4, "bbox": [543.0, 24.0, 446.0, 97.0], "category_id": 2}, {"id": 5, "bbox": [174.3, 200.0, 147.7, 49.1], "category_id": 2}, {"id": 6, "bbox": [279.0, 6.0, 225.0, 227.8], "category_id": 1}, {"id": 7, "bbox": [983.3, 1.1, 252.2, 223.7], "category_id": 1}, {"id": 8, "bbox": [579.0, 122.5, 361.0, 95.5], "category_id": 2}, {"id": 9, "bbox": [157.9, 54.0, 66.0, 134.5], "category_id": 1}], "reactions": [{"reactants": [9, 6], "conditions": [4, 8], "products": [7]}], "corefs": [[9, 3], [6, 0], [7, 2]], "caption": "Table 3. Alkenyl Substitution Scope", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 311, 637, 324], "ImageBB": [439, 325, 777, 687]}, "diagram_type": "single"}, {"id": 1291, "width": 2360, "height": 1556, "file_name": "op200112g-Scheme-c5.png", "license": 0, "bboxes": [{"id": 0, "bbox": [466.33, 131.03, 56.67, 75.54], "category_id": 2}, {"id": 1, "bbox": [1846.44, 592.57, 488.77, 408.43], "category_id": 1}, {"id": 2, "bbox": [0.0, 56.66, 427.37, 337.6], "category_id": 1}, {"id": 3, "bbox": [1846.44, 10.62, 488.77, 404.89], "category_id": 1}, {"id": 4, "bbox": [1736.65, 134.57, 48.4, 72.0], "category_id": 2}, {"id": 5, "bbox": [1240.8, 338.78, 276.26, 55.48], "category_id": 2}, {"id": 6, "bbox": [1182.95, 1129.67, 494.67, 407.24], "category_id": 1}, {"id": 7, "bbox": [466.33, 266.78, 108.62, 59.02], "category_id": 2}, {"id": 8, "bbox": [1207.74, 15.35, 486.41, 396.62], "category_id": 1}, {"id": 9, "bbox": [120.42, 744.85, 224.31, 61.38], "category_id": 2}, {"id": 10, "bbox": [599.74, 53.12, 426.19, 334.06], "category_id": 1}, {"id": 11, "bbox": [1846.44, 1129.67, 491.13, 410.78], "category_id": 1}, {"id": 12, "bbox": [146.39, 339.96, 37.78, 46.04], "category_id": 3}, {"id": 13, "bbox": [756.76, 1313.81, 225.49, 57.84], "category_id": 2}, {"id": 14, "bbox": [1370.67, 430.85, 88.54, 80.27], "category_id": 2}, {"id": 15, "bbox": [595.02, 509.94, 417.93, 461.55], "category_id": 1}, {"id": 16, "bbox": [1185.31, 586.67, 469.88, 416.69], "category_id": 1}], "caption": "Scheme 5. Degradation of GLY I (1) and its dehydrated producta", "pdf": {"Page": 5, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [71, 87, 435, 108], "ImageBB": [127, 117, 717, 506]}, "reactions": [{"reactants": [2], "conditions": [0], "products": [7, 10]}, {"reactants": [10], "conditions": [], "products": [8]}, {"reactants": [8], "conditions": [4], "products": [3]}, {"reactants": [8], "conditions": [14], "products": [16]}, {"reactants": [16], "conditions": [], "products": [15]}, {"reactants": [15], "conditions": [], "products": [16]}, {"reactants": [3], "conditions": [], "products": [1]}, {"reactants": [1], "conditions": [], "products": [3]}, {"reactants": [1], "conditions": [], "products": [11]}, {"reactants": [11], "conditions": [], "products": [1]}, {"reactants": [11], "conditions": [], "products": [6]}, {"reactants": [6], "conditions": [], "products": [11]}], "diagram_type": "tree"}, {"id": 742, "width": 1352, "height": 2756, "file_name": "ol006383n-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [776.0, 208.0, 48.0, 55.0], "category_id": 3}, {"id": 1, "bbox": [107.0, 218.0, 42.0, 53.0], "category_id": 3}, {"id": 2, "bbox": [363.0, 10.0, 117.0, 47.0], "category_id": 2}, {"id": 3, "bbox": [20.0, 376.0, 1332.0, 1998.0], "category_id": 4}, {"id": 4, "bbox": [81.0, 2379.0, 1063.0, 231.0], "category_id": 2}, {"id": 5, "bbox": [1034.0, 50.0, 257.0, 188.0], "category_id": 1}, {"id": 6, "bbox": [538.0, 15.0, 318.0, 369.0], "category_id": 1}, {"id": 7, "bbox": [363.0, 138.0, 117.0, 62.0], "category_id": 2}, {"id": 8, "bbox": [1095.0, 258.0, 82.0, 46.0], "category_id": 3}, {"id": 9, "bbox": [29.0, 7.0, 314.0, 364.0], "category_id": 1}, {"id": 10, "bbox": [864.0, 97.0, 178.0, 83.0], "category_id": 2}], "reactions": [{"reactants": [9], "conditions": [7], "products": [6]}, {"reactants": [6], "conditions": [10], "products": [5]}, {"reactants": [2], "conditions": [], "products": [7]}], "corefs": [[9, 1], [6, 0], [5, 8]], "caption": "Table 1. Ureas from Carboxylic Acids", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 348, 648, 361], "ImageBB": [439, 364, 777, 1053]}, "diagram_type": "single"}, {"id": 818, "width": 1348, "height": 1872, "file_name": "jo4014707-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [469.5, 837.0, 253.5, 185.2], "category_id": 1}, {"id": 1, "bbox": [65.0, 396.7, 360.5, 316.3], "category_id": 1}, {"id": 2, "bbox": [547.0, 745.0, 280.0, 49.0], "category_id": 3}, {"id": 3, "bbox": [1051.0, 656.0, 126.0, 39.0], "category_id": 3}, {"id": 4, "bbox": [763.0, 910.0, 456.0, 50.0], "category_id": 3}, {"id": 5, "bbox": [766.0, 1098.0, 490.0, 52.0], "category_id": 3}, {"id": 6, "bbox": [303.0, 162.0, 175.0, 35.0], "category_id": 2}, {"id": 7, "bbox": [112.0, 15.0, 124.0, 194.0], "category_id": 1}, {"id": 8, "bbox": [953.0, 468.0, 330.0, 180.0], "category_id": 1}, {"id": 9, "bbox": [463.32, 1031.44, 258.46, 203.26], "category_id": 1}, {"id": 10, "bbox": [483.0, 405.0, 405.0, 313.0], "category_id": 1}, {"id": 11, "bbox": [63.0, 859.0, 367.0, 310.0], "category_id": 1}, {"id": 12, "bbox": [659.0, 243.0, 247.0, 49.0], "category_id": 2}, {"id": 13, "bbox": [737.0, 196.0, 92.0, 39.0], "category_id": 2}, {"id": 14, "bbox": [733.0, 141.0, 98.0, 50.0], "category_id": 2}, {"id": 15, "bbox": [628.0, 69.0, 311.0, 50.0], "category_id": 2}, {"id": 16, "bbox": [571.0, 0.0, 435.0, 49.0], "category_id": 2}, {"id": 17, "bbox": [354.0, 227.0, 56.0, 44.0], "category_id": 3}, {"id": 18, "bbox": [161.0, 227.0, 36.0, 45.0], "category_id": 3}, {"id": 19, "bbox": [3.0, 1243.0, 1345.0, 629.0], "category_id": 4}, {"id": 20, "bbox": [1067.0, 19.0, 199.0, 208.0], "category_id": 1}, {"id": 21, "bbox": [300.2, 103.0, 192.8, 54.0], "category_id": 2}, {"id": 22, "bbox": [1097.0, 232.0, 104.0, 44.0], "category_id": 3}, {"id": 23, "bbox": [152.0, 745.0, 195.0, 46.0], "category_id": 3}], "reactions": [{"reactants": [7, 21], "conditions": [16, 15, 14, 13, 12], "products": [20]}], "corefs": [[7, 18], [21, 17], [20, 22], [1, 23], [10, 2], [8, 3]], "caption": "Table 1. Asymmetric 1,4-Addition of 2a to 1 at 0 \u00b0Ca", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 89, 386, 111], "ImageBB": [82, 116, 419, 584]}, "diagram_type": "single"}, {"id": 1195, "width": 2816, "height": 836, "file_name": "ol501514b-Scheme-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [245.11, 709.51, 46.49, 39.42], "category_id": 3}, {"id": 1, "bbox": [76.53, 152.1, 90.26, 46.02], "category_id": 2}, {"id": 2, "bbox": [301.29, 431.72, 210.6, 46.01], "category_id": 2}, {"id": 3, "bbox": [755.07, 503.98, 133.82, 50.68], "category_id": 3}, {"id": 4, "bbox": [211.5, 84.47, 277.32, 40.82], "category_id": 2}, {"id": 5, "bbox": [542.35, 211.16, 146.51, 43.64], "category_id": 3}, {"id": 6, "bbox": [30.99, 94.32, 142.28, 43.64], "category_id": 1}, {"id": 7, "bbox": [277.51, 135.14, 166.23, 40.83], "category_id": 2}, {"id": 8, "bbox": [178.91, 580.0, 202.85, 128.1], "category_id": 1}, {"id": 9, "bbox": [277.51, 335.05, 416.98, 83.05], "category_id": 2}, {"id": 10, "bbox": [817.05, 152.04, 240.89, 46.45], "category_id": 2}, {"id": 11, "bbox": [14.09, 242.13, 277.51, 260.44], "category_id": 1}, {"id": 12, "bbox": [709.99, 315.34, 197.22, 187.23], "category_id": 1}, {"id": 13, "bbox": [474.73, 660.24, 264.84, 43.64], "category_id": 2}, {"id": 14, "bbox": [1097.38, 29.56, 239.48, 181.6], "category_id": 1}, {"id": 15, "bbox": [955.1, 423.74, 249.34, 36.6], "category_id": 2}, {"id": 16, "bbox": [478.96, 67.57, 249.34, 132.33], "category_id": 1}, {"id": 17, "bbox": [957.92, 373.06, 246.52, 43.64], "category_id": 2}, {"id": 18, "bbox": [30.99, 512.42, 223.99, 43.64], "category_id": 3}, {"id": 19, "bbox": [755.07, 33.79, 336.68, 95.72], "category_id": 2}, {"id": 20, "bbox": [1128.37, 218.2, 145.1, 46.46], "category_id": 3}], "caption": "Scheme 3. Synthesis of 3-Methyl-4-phenyl-1H-pyrrol-2(5H)- one ", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 562, 416, 592], "ImageBB": [82, 591, 786, 800]}, "reactions": [{"reactants": [6, 1], "conditions": [4, 7], "products": [16]}, {"reactants": [16], "conditions": [19, 10], "products": [14]}, {"reactants": [14], "conditions": [17, 15], "products": [12]}, {"reactants": [12], "conditions": [], "products": [8]}, {"reactants": [12], "conditions": [9, 2], "products": [11]}], "diagram_type": "tree"}, {"id": 878, "width": 1272, "height": 2012, "file_name": "ol7014434-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [0.0, 296.4, 1272.0, 1715.6], "category_id": 4}, {"id": 1, "bbox": [111.1, 0.0, 377.9, 228.2], "category_id": 1}, {"id": 2, "bbox": [799.6, 0.0, 370.5, 219.6], "category_id": 1}, {"id": 3, "bbox": [579.0, 42.0, 106.0, 39.0], "category_id": 2}, {"id": 4, "bbox": [552.0, 110.0, 123.0, 41.0], "category_id": 2}, {"id": 5, "bbox": [251.0, 244.0, 33.0, 38.0], "category_id": 3}, {"id": 6, "bbox": [930.0, 229.0, 63.0, 40.0], "category_id": 3}], "reactions": [{"reactants": [1], "conditions": [3, 4], "products": [2]}], "corefs": [[1, 5], [2, 6]], "caption": "Table 3. Synthesis of Compounds of Type III from Type IIa", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 75, 397, 89], "ImageBB": [83, 90, 401, 593]}, "diagram_type": "single"}, {"id": 1197, "width": 2820, "height": 916, "file_name": "ol502425f-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1801.47, 315.99, 56.43, 50.78], "category_id": 3}, {"id": 1, "bbox": [1145.49, 83.23, 383.71, 290.6], "category_id": 1}, {"id": 2, "bbox": [2353.06, 435.9, 458.48, 416.14], "category_id": 1}, {"id": 3, "bbox": [218.66, 811.13, 49.37, 46.56], "category_id": 3}, {"id": 4, "bbox": [576.98, 499.38, 435.91, 338.56], "category_id": 1}, {"id": 5, "bbox": [1736.58, 12.7, 465.53, 344.2], "category_id": 1}, {"id": 6, "bbox": [2482.84, 792.8, 52.2, 52.19], "category_id": 3}, {"id": 7, "bbox": [482.46, 545.93, 158.0, 90.28], "category_id": 2}, {"id": 8, "bbox": [1509.45, 117.09, 217.25, 98.74], "category_id": 1}, {"id": 9, "bbox": [12.8, 134.7, 179.06, 103.0], "category_id": 1}, {"id": 10, "bbox": [1716.9, 436.7, 432.1, 400.5], "category_id": 1}, {"id": 11, "bbox": [31.9, 314.6, 347.6, 90.9], "category_id": 2}, {"id": 12, "bbox": [2194.71, 546.3, 123.34, 78.69], "category_id": 2}, {"id": 13, "bbox": [1854.43, 786.62, 44.67, 48.91], "category_id": 3}, {"id": 14, "bbox": [1012.89, 538.88, 167.87, 87.46], "category_id": 2}, {"id": 15, "bbox": [1156.78, 499.38, 444.37, 338.56], "category_id": 1}, {"id": 16, "bbox": [2131.58, 373.83, 180.57, 55.01], "category_id": 2}, {"id": 17, "bbox": [355.5, 88.87, 235.59, 176.34], "category_id": 1}, {"id": 18, "bbox": [2355.88, 12.7, 464.12, 409.09], "category_id": 1}, {"id": 19, "bbox": [160.82, 141.07, 215.84, 47.96], "category_id": 2}, {"id": 20, "bbox": [1261.17, 371.01, 146.71, 46.55], "category_id": 3}, {"id": 21, "bbox": [620.71, 88.87, 256.75, 179.16], "category_id": 1}, {"id": 22, "bbox": [26.8, 479.63, 438.73, 362.54], "category_id": 1}, {"id": 23, "bbox": [887.33, 114.26, 237.0, 71.95], "category_id": 2}], "caption": "Scheme 1. Plausible Biogenetic Pathway for 1 and 2 (Red, Newly Formed Rings)", "pdf": {"Page": 4, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 530, 110], "ImageBB": [82, 116, 787, 345]}, "reactions": [{"reactants": [9], "conditions": [19], "products": [17]}, {"reactants": [17], "conditions": [], "products": [21]}, {"reactants": [21], "conditions": [23], "products": [1]}, {"reactants": [1, 8], "conditions": [], "products": [5]}, {"reactants": [5], "conditions": [], "products": [18]}, {"reactants": [18], "conditions": [], "products": [5]}, {"reactants": [18], "conditions": [], "products": [10]}, {"reactants": [10], "conditions": [12], "products": [2]}, {"reactants": [10], "conditions": [], "products": [15]}, {"reactants": [15], "conditions": [], "products": [10]}, {"reactants": [15], "conditions": [14], "products": [4]}, {"reactants": [4], "conditions": [7], "products": [22]}], "diagram_type": "tree"}, {"id": 539, "width": 1352, "height": 1148, "file_name": "acs.orglett.6b00661-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [660.0, 552.0, 586.0, 446.0], "category_id": 1}, {"id": 1, "bbox": [105.0, 114.0, 384.0, 319.0], "category_id": 1}, {"id": 2, "bbox": [1047.0, 117.0, 203.0, 313.0], "category_id": 1}, {"id": 3, "bbox": [148.7, 551.0, 515.3, 439.0], "category_id": 1}, {"id": 4, "bbox": [169.0, 433.0, 229.0, 66.0], "category_id": 2}, {"id": 5, "bbox": [514.0, 301.0, 441.0, 120.0], "category_id": 2}, {"id": 6, "bbox": [505.0, 157.0, 471.0, 114.0], "category_id": 2}, {"id": 7, "bbox": [733.0, 865.2, 392.5, 115.6], "category_id": 3}, {"id": 8, "bbox": [125.0, 856.0, 905.0, 292.0], "category_id": 3}], "reactions": [{"reactants": [1], "conditions": [6, 5], "products": [2]}], "corefs": [[3, 8], [0, 7]], "caption": "Figure 1. Gold(I)-catalyzed 6-exo-dig cyclization reaction and structures of gardnerine (1), hydroxygardnerine (2), hydroxygardnu- tine (3), and (E)-16-epi-normacusine B (4). ", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 852, 417, 894], "ImageBB": [82, 556, 420, 843]}, "diagram_type": "multiple"}, {"id": 1103, "width": 1332, "height": 364, "file_name": "jo9717245-Scheme-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [322.51, 318.08, 92.62, 45.34], "category_id": 3}, {"id": 1, "bbox": [766.95, 0.0, 345.83, 309.5], "category_id": 1}, {"id": 2, "bbox": [0.0, 149.37, 43.31, 52.68], "category_id": 3}, {"id": 3, "bbox": [854.88, 314.14, 90.41, 41.19], "category_id": 3}, {"id": 4, "bbox": [197.23, 0.0, 381.15, 307.2], "category_id": 1}, {"id": 5, "bbox": [1286.69, 149.37, 45.31, 52.68], "category_id": 3}], "caption": "Scheme 2", "pdf": {"Page": 5, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [573, 64, 636, 78], "ImageBB": [442, 85, 775, 176]}, "reactions": [{"reactants": [4], "conditions": [], "products": [2]}, {"reactants": [4], "conditions": [], "products": [1]}, {"reactants": [1], "conditions": [], "products": [4]}, {"reactants": [1], "conditions": [], "products": [5]}], "diagram_type": "single"}, {"id": 1357, "width": 992, "height": 1352, "file_name": "op9000687-Scheme-c5.png", "license": 0, "bboxes": [{"id": 0, "bbox": [470.08, 987.45, 399.74, 52.08], "category_id": 2}, {"id": 1, "bbox": [0.0, 327.35, 411.24, 177.87], "category_id": 1}, {"id": 2, "bbox": [469.41, 1043.59, 429.5, 48.7], "category_id": 2}, {"id": 3, "bbox": [772.42, 124.45, 56.14, 45.31], "category_id": 3}, {"id": 4, "bbox": [124.45, 734.5, 572.9, 202.9], "category_id": 1}, {"id": 5, "bbox": [263.79, 522.13, 373.36, 110.25], "category_id": 2}, {"id": 6, "bbox": [321.96, 1304.66, 62.22, 47.34], "category_id": 3}, {"id": 7, "bbox": [708.17, 190.73, 283.83, 104.83], "category_id": 2}, {"id": 8, "bbox": [319.25, 914.41, 67.64, 54.78], "category_id": 3}, {"id": 9, "bbox": [148.8, 1100.4, 547.19, 202.9], "category_id": 1}, {"id": 10, "bbox": [553.28, 313.14, 381.48, 167.74], "category_id": 1}, {"id": 11, "bbox": [100.1, 473.44, 58.17, 46.66], "category_id": 3}, {"id": 12, "bbox": [567.48, 2.71, 333.46, 117.0], "category_id": 1}, {"id": 13, "bbox": [753.49, 488.99, 60.19, 45.99], "category_id": 3}, {"id": 14, "bbox": [0.0, 1347.94, 0.68, 4.06], "category_id": 3}, {"id": 15, "bbox": [0.0, 1347.94, 8.79, 4.06], "category_id": 3}], "caption": "Scheme 5. First route for the synthesis of biaryl 15", "pdf": {"Page": 3, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [425, 46, 711, 60], "ImageBB": [469, 65, 717, 403]}, "reactions": [{"reactants": [12], "conditions": [7], "products": [10]}, {"reactants": [1, 10], "conditions": [5], "products": [4]}, {"reactants": [4], "conditions": [0, 2], "products": [9]}], "diagram_type": "tree"}, {"id": 506, "width": 1344, "height": 1424, "file_name": "ol051920v-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [648.0, 123.0, 137.0, 47.0], "category_id": 2}, {"id": 1, "bbox": [2.0, 299.0, 1342.0, 1125.0], "category_id": 4}, {"id": 2, "bbox": [148.0, 14.0, 182.0, 172.0], "category_id": 1}, {"id": 3, "bbox": [384.0, 56.0, 158.0, 140.0], "category_id": 1}, {"id": 4, "bbox": [951.0, 1.0, 249.0, 182.0], "category_id": 1}, {"id": 5, "bbox": [1054.0, 195.0, 49.0, 46.0], "category_id": 3}, {"id": 6, "bbox": [418.0, 206.0, 51.0, 40.0], "category_id": 3}, {"id": 7, "bbox": [175.0, 197.0, 51.0, 43.0], "category_id": 3}, {"id": 8, "bbox": [549.0, 59.0, 386.0, 50.0], "category_id": 2}], "reactions": [{"reactants": [2, 3], "conditions": [8, 0], "products": [4]}], "corefs": [[2, 7], [3, 6], [4, 5]], "caption": "Table 1. Reactions of Salicylaldehyde 1a (0.5 mmol) with 3-Methylpenta-3,4-dien-2-one 2a (2.0 mmol) in the Presence of Various Lewis Bases and Solvents ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 76, 402, 120], "ImageBB": [74, 125, 410, 481]}, "diagram_type": "single"}, {"id": 1371, "width": 1080, "height": 1404, "file_name": "op9800717-Scheme-c5.png", "license": 0, "bboxes": [{"id": 0, "bbox": [718.07, 414.39, 331.64, 224.75], "category_id": 1}, {"id": 1, "bbox": [605.65, 271.81, 92.75, 54.08], "category_id": 2}, {"id": 2, "bbox": [751.1, 1250.89, 318.28, 150.3], "category_id": 1}, {"id": 3, "bbox": [49.18, 410.88, 398.39, 229.66], "category_id": 1}, {"id": 4, "bbox": [411.03, 0.0, 423.68, 222.65], "category_id": 1}, {"id": 5, "bbox": [751.1, 828.07, 294.39, 233.88], "category_id": 1}], "caption": "Scheme 5", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 304, 135, 318], "ImageBB": [107, 323, 377, 674]}, "reactions": [{"reactants": [4], "conditions": [1], "products": [3, 0]}, {"reactants": [3, 0], "conditions": [], "products": [4]}, {"reactants": [3], "conditions": [], "products": [0]}, {"reactants": [0], "conditions": [], "products": [3]}, {"reactants": [0], "conditions": [], "products": [5]}, {"reactants": [5], "conditions": [], "products": [2]}], "diagram_type": "tree"}, {"id": 543, "width": 1316, "height": 1164, "file_name": "acs.orglett.5b03590-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [222.2, 2.0, 328.8, 215.0], "category_id": 1}, {"id": 1, "bbox": [778.0, 459.0, 90.4, 64.0], "category_id": 3}, {"id": 2, "bbox": [472.0, 457.0, 76.3, 70.0], "category_id": 3}, {"id": 3, "bbox": [131.0, 457.0, 79.2, 64.4], "category_id": 3}, {"id": 4, "bbox": [66.0, 866.0, 210.5, 205.0], "category_id": 1}, {"id": 5, "bbox": [649.0, 871.0, 344.3, 225.5], "category_id": 1}, {"id": 6, "bbox": [978.0, 863.1, 334.6, 211.5], "category_id": 1}, {"id": 7, "bbox": [1022.1, 561.3, 249.1, 203.2], "category_id": 1}, {"id": 8, "bbox": [721.8, 557.8, 212.5, 205.1], "category_id": 1}, {"id": 9, "bbox": [400.0, 563.0, 206.9, 201.7], "category_id": 1}, {"id": 10, "bbox": [0.0, 539.0, 339.0, 225.6], "category_id": 1}, {"id": 11, "bbox": [686.55, 262.8, 277.85, 203.4], "category_id": 1}, {"id": 12, "bbox": [863.0, 0.0, 228.3, 219.2], "category_id": 1}, {"id": 13, "bbox": [773.0, 1088.0, 107.0, 66.0], "category_id": 3}, {"id": 14, "bbox": [121.0, 774.0, 101.0, 77.0], "category_id": 3}, {"id": 15, "bbox": [558.0, 136.0, 276.0, 54.0], "category_id": 2}, {"id": 16, "bbox": [1100.0, 1085.0, 97.0, 79.0], "category_id": 3}, {"id": 17, "bbox": [0.0, 261.0, 339.0, 205.0], "category_id": 1}, {"id": 18, "bbox": [319.0, 263.0, 386.0, 207.0], "category_id": 1}, {"id": 19, "bbox": [1010.0, 258.0, 273.0, 205.0], "category_id": 1}, {"id": 20, "bbox": [339.0, 854.0, 334.0, 222.0], "category_id": 1}, {"id": 21, "bbox": [349.0, 226.0, 70.0, 35.0], "category_id": 3}, {"id": 22, "bbox": [915.0, 228.0, 85.0, 28.0], "category_id": 3}, {"id": 23, "bbox": [1104.0, 457.0, 86.0, 76.0], "category_id": 3}, {"id": 24, "bbox": [1113.0, 773.0, 78.0, 72.0], "category_id": 3}, {"id": 25, "bbox": [769.0, 765.0, 108.0, 74.0], "category_id": 3}, {"id": 26, "bbox": [448.0, 776.0, 88.0, 62.0], "category_id": 3}, {"id": 27, "bbox": [124.0, 1085.0, 100.0, 79.0], "category_id": 3}, {"id": 28, "bbox": [471.0, 1073.0, 85.0, 73.0], "category_id": 3}, {"id": 29, "bbox": [573.0, 90.0, 227.0, 49.0], "category_id": 2}], "reactions": [{"reactants": [0], "conditions": [29, 15], "products": [12]}], "corefs": [[0, 21], [12, 22], [17, 3], [18, 2], [11, 1], [19, 23], [10, 14], [9, 26], [8, 25], [7, 24], [4, 27], [20, 28], [5, 13], [6, 16]], "caption": "Table 2. Cascade Synthesis of Triazinonesa", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 138, 689, 159], "ImageBB": [453, 165, 782, 456]}, "diagram_type": "single"}, {"id": 293, "width": 1344, "height": 1024, "file_name": "ol400110c-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [8.0, 498.0, 1335.0, 526.0], "category_id": 4}, {"id": 1, "bbox": [1016.0, 325.0, 70.0, 56.0], "category_id": 3}, {"id": 2, "bbox": [596.0, 189.0, 135.0, 54.0], "category_id": 2}, {"id": 3, "bbox": [538.0, 98.9, 236.3, 57.1], "category_id": 2}, {"id": 4, "bbox": [318.0, 330.72, 63.0, 45.0], "category_id": 3}, {"id": 5, "bbox": [156.2, 4.0, 335.5, 324.0], "category_id": 1}, {"id": 6, "bbox": [876.0, 21.0, 312.9, 289.0], "category_id": 1}], "reactions": [{"reactants": [5], "conditions": [3, 2], "products": [6]}], "corefs": [[5, 4], [6, 1]], "caption": "Table 1. Optimization Studies", "pdf": {"Page": 2, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [71, 237, 231, 250], "ImageBB": [71, 261, 407, 517]}, "diagram_type": "single"}, {"id": 939, "width": 1356, "height": 1092, "file_name": "acs.orglett.5b01309-Scheme-c6.png", "license": 0, "bboxes": [{"id": 0, "bbox": [209.61, 1009.14, 37.31, 38.68], "category_id": 3}, {"id": 1, "bbox": [959.17, 416.69, 392.76, 242.27], "category_id": 1}, {"id": 2, "bbox": [495.87, 259.24, 43.41, 46.15], "category_id": 3}, {"id": 3, "bbox": [754.99, 29.18, 395.47, 233.45], "category_id": 1}, {"id": 4, "bbox": [707.51, 662.35, 73.26, 42.76], "category_id": 3}, {"id": 5, "bbox": [231.31, 692.89, 231.32, 73.3], "category_id": 2}, {"id": 6, "bbox": [871.67, 274.85, 202.82, 40.04], "category_id": 3}, {"id": 7, "bbox": [510.79, 394.97, 389.37, 241.6], "category_id": 1}, {"id": 8, "bbox": [1117.22, 682.71, 78.01, 38.01], "category_id": 3}, {"id": 9, "bbox": [175.69, 272.14, 94.29, 44.11], "category_id": 3}, {"id": 10, "bbox": [5.51, 56.37, 381.47, 208.44], "category_id": 1}, {"id": 11, "bbox": [105.14, 634.53, 71.23, 37.32], "category_id": 3}, {"id": 12, "bbox": [439.56, 50.9, 194.69, 168.3], "category_id": 1}, {"id": 13, "bbox": [1016.15, 338.64, 84.12, 49.54], "category_id": 2}, {"id": 14, "bbox": [12.89, 407.86, 391.4, 265.35], "category_id": 1}, {"id": 15, "bbox": [47.48, 785.87, 373.77, 218.52], "category_id": 1}, {"id": 16, "bbox": [16.28, 690.86, 193.33, 72.61], "category_id": 2}], "caption": "Scheme 6. Zwitterion Formation in \u03b2-Lactam Formation", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 170, 768, 190], "ImageBB": [448, 196, 787, 469]}, "reactions": [{"reactants": [10, 12], "conditions": [], "products": [3]}, {"reactants": [3], "conditions": [13], "products": [1]}, {"reactants": [1], "conditions": [], "products": [7]}, {"reactants": [7], "conditions": [], "products": [1]}, {"reactants": [14], "conditions": [], "products": [7]}, {"reactants": [7], "conditions": [], "products": [14]}, {"reactants": [14], "conditions": [16, 5], "products": [15]}], "diagram_type": "tree"}, {"id": 811, "width": 2820, "height": 936, "file_name": "jo4027148-Figure-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [2025.0, 729.0, 213.0, 104.0], "category_id": 2}, {"id": 1, "bbox": [146.0, 884.0, 61.0, 52.0], "category_id": 3}, {"id": 2, "bbox": [422.0, 886.0, 68.0, 50.0], "category_id": 3}, {"id": 3, "bbox": [1842.0, 886.0, 69.0, 50.0], "category_id": 3}, {"id": 4, "bbox": [1000.0, 877.0, 61.0, 59.0], "category_id": 3}, {"id": 5, "bbox": [867.0, 152.0, 283.0, 60.2], "category_id": 2}, {"id": 6, "bbox": [1736.5, 151.6, 270.7, 59.9], "category_id": 2}, {"id": 7, "bbox": [366.8, 41.0, 343.2, 351.0], "category_id": 1}, {"id": 8, "bbox": [1481.0, 881.0, 67.0, 55.0], "category_id": 3}, {"id": 9, "bbox": [1274.3, 118.5, 346.7, 200.7], "category_id": 1}, {"id": 10, "bbox": [2116.0, 391.0, 343.0, 67.1], "category_id": 3}, {"id": 11, "bbox": [353.0, 398.0, 334.0, 57.6], "category_id": 3}, {"id": 12, "bbox": [2479.0, 884.0, 64.0, 52.0], "category_id": 3}, {"id": 13, "bbox": [867.9, 592.5, 328.1, 236.2], "category_id": 1}, {"id": 14, "bbox": [372.0, 619.0, 166.0, 177.7], "category_id": 1}, {"id": 15, "bbox": [2119.1, 46.8, 327.0, 340.2], "category_id": 1}, {"id": 16, "bbox": [52.0, 596.0, 244.0, 233.0], "category_id": 1}, {"id": 17, "bbox": [1331.0, 592.0, 363.0, 241.0], "category_id": 1}, {"id": 18, "bbox": [1753.0, 599.0, 244.0, 221.0], "category_id": 1}, {"id": 19, "bbox": [2272.0, 555.0, 493.0, 315.0], "category_id": 1}, {"id": 20, "bbox": [75.0, 70.0, 52.0, 64.0], "category_id": 3}, {"id": 21, "bbox": [77.0, 537.0, 44.0, 53.0], "category_id": 3}, {"id": 22, "bbox": [2009.0, 585.0, 247.0, 116.0], "category_id": 2}, {"id": 23, "bbox": [566.0, 725.6, 276.0, 132.4], "category_id": 2}, {"id": 24, "bbox": [587.0, 601.0, 246.0, 98.6], "category_id": 2}, {"id": 25, "bbox": [1299.0, 389.0, 310.0, 71.0], "category_id": 3}, {"id": 26, "bbox": [1756.61, 236.23, 231.81, 53.17], "category_id": 2}, {"id": 27, "bbox": [886.79, 238.36, 240.31, 53.16], "category_id": 2}, {"id": 28, "bbox": [395.52, 821.07, 123.35, 57.42], "category_id": 2}], "reactions": [{"reactants": [7], "conditions": [5, 27], "products": [9]}, {"reactants": [9], "conditions": [6, 26], "products": [15]}, {"reactants": [16, 14], "conditions": [24, 23], "products": [13]}, {"reactants": [17, 18], "conditions": [22, 0], "products": [19]}], "corefs": [[7, 11], [9, 25], [15, 10], [16, 1], [14, 2], [13, 4], [17, 8], [18, 3], [19, 12]], "caption": "Figure 3. Examples of (A) solid-state photochemistry and (B) photoredox-catalyzed [2 + 2] cycloadditions.", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 870, 605, 884], "ImageBB": [82, 627, 787, 861]}, "diagram_type": "multiple"}, {"id": 1022, "width": 1024, "height": 556, "file_name": "jo000585f-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [129.09, 196.65, 39.95, 47.62], "category_id": 3}, {"id": 1, "bbox": [809.36, 195.62, 105.53, 53.77], "category_id": 3}, {"id": 2, "bbox": [573.73, 344.13, 69.66, 53.26], "category_id": 2}, {"id": 3, "bbox": [188.0, 297.02, 289.42, 156.19], "category_id": 1}, {"id": 4, "bbox": [300.18, 489.57, 105.01, 56.33], "category_id": 3}, {"id": 5, "bbox": [727.92, 306.75, 261.25, 160.28], "category_id": 1}, {"id": 6, "bbox": [424.15, 121.88, 136.77, 49.16], "category_id": 2}, {"id": 7, "bbox": [675.67, 6.66, 345.26, 151.07], "category_id": 1}, {"id": 8, "bbox": [0.0, 3.07, 345.77, 149.54], "category_id": 1}, {"id": 9, "bbox": [364.5, 51.7, 256.87, 63.01], "category_id": 2}, {"id": 10, "bbox": [832.42, 494.69, 103.98, 55.82], "category_id": 3}], "caption": "Scheme 1", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [207, 64, 270, 78], "ImageBB": [114, 82, 370, 221]}, "reactions": [{"reactants": [8], "conditions": [9, 6], "products": [7]}, {"reactants": [7], "conditions": [], "products": [3]}, {"reactants": [3], "conditions": [2], "products": [5]}], "diagram_type": "multiple"}, {"id": 436, "width": 1352, "height": 792, "file_name": "op3000042-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [596.1, 645.88, 281.9, 140.8], "category_id": 1}, {"id": 1, "bbox": [17.0, 162.0, 217.5, 54.0], "category_id": 2}, {"id": 2, "bbox": [1081.5, 637.1, 249.8, 143.8], "category_id": 1}, {"id": 3, "bbox": [690.0, 532.2, 141.8, 46.8], "category_id": 1}, {"id": 4, "bbox": [588.7, 330.7, 189.5, 130.7], "category_id": 1}, {"id": 5, "bbox": [30.0, 261.0, 150.0, 55.0], "category_id": 2}, {"id": 6, "bbox": [458.0, 334.0, 55.0, 45.0], "category_id": 2}, {"id": 7, "bbox": [875.0, 616.0, 187.0, 84.0], "category_id": 2}, {"id": 8, "bbox": [60.6, 322.9, 287.0, 123.1], "category_id": 1}, {"id": 9, "bbox": [889.1, 322.7, 186.2, 120.7], "category_id": 1}, {"id": 10, "bbox": [588.8, 17.7, 190.4, 133.0], "category_id": 1}], "reactions": [{"reactants": [8], "conditions": [6], "products": [4, 9]}, {"reactants": [4, 9], "conditions": [], "products": [8]}, {"reactants": [4], "conditions": [], "products": [10]}, {"reactants": [10], "conditions": [], "products": [4]}, {"reactants": [4], "conditions": [3], "products": [0]}, {"reactants": [0], "conditions": [], "products": [4]}, {"reactants": [0], "conditions": [7], "products": [2]}], "corefs": [], "caption": "Figure 1. Proposed isobutylene/acetic acid/tert-butyl acetate equili- brium. ", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 550, 784, 578], "ImageBB": [448, 343, 786, 541]}, "diagram_type": "tree"}, {"id": 645, "width": 1352, "height": 384, "file_name": "ol500618w-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [648.86, 135.31, 342.84, 140.19], "category_id": 2}, {"id": 1, "bbox": [475.08, 195.0, 38.12, 40.9], "category_id": 3}, {"id": 2, "bbox": [1168.94, 188.32, 63.46, 54.78], "category_id": 3}, {"id": 3, "bbox": [76.63, 238.55, 136.67, 50.55], "category_id": 2}, {"id": 4, "bbox": [411.58, 238.27, 166.52, 50.63], "category_id": 2}, {"id": 5, "bbox": [3.37, 35.45, 281.33, 140.65], "category_id": 1}, {"id": 6, "bbox": [413.5, 48.2, 157.3, 113.9], "category_id": 1}, {"id": 7, "bbox": [1052.86, 36.59, 295.64, 140.51], "category_id": 1}, {"id": 8, "bbox": [6.0, 312.8, 1346.0, 71.2], "category_id": 4}, {"id": 9, "bbox": [116.5, 194.04, 55.7, 43.46], "category_id": 3}, {"id": 10, "bbox": [638.13, 5.14, 369.0, 88.0], "category_id": 2}], "reactions": [{"reactants": [5, 6], "conditions": [10, 0], "products": [7]}], "corefs": [[5, 9], [6, 1], [7, 2]], "caption": "Table 2. Optimization of the Reaction Conditions for the Cyanation Reaction of Alkenyl Bromide 1a ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 407, 125], "ImageBB": [82, 131, 420, 227]}, "diagram_type": "single"}, {"id": 1161, "width": 1352, "height": 488, "file_name": "ol0604623-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [432.18, 41.27, 270.54, 67.65], "category_id": 1}, {"id": 1, "bbox": [436.91, 156.96, 259.72, 161.69], "category_id": 1}, {"id": 2, "bbox": [246.86, 79.83, 177.2, 150.19], "category_id": 1}, {"id": 3, "bbox": [261.74, 239.49, 122.42, 77.81], "category_id": 2}, {"id": 4, "bbox": [1074.7, 336.24, 156.24, 46.68], "category_id": 3}, {"id": 5, "bbox": [747.35, 4.06, 240.78, 219.2], "category_id": 1}, {"id": 6, "bbox": [0.0, 97.42, 234.01, 225.29], "category_id": 1}, {"id": 7, "bbox": [798.76, 246.26, 125.12, 74.42], "category_id": 2}, {"id": 8, "bbox": [963.78, 110.28, 388.22, 221.22], "category_id": 1}, {"id": 9, "bbox": [503.87, 311.88, 163.0, 121.1], "category_id": 3}, {"id": 10, "bbox": [79.81, 330.83, 156.23, 47.35], "category_id": 3}, {"id": 11, "bbox": [607.69, 153.76, 25.49, 33.64], "category_id": 3}, {"id": 12, "bbox": [587.29, 120.11, 76.47, 38.74], "category_id": 2}, {"id": 13, "bbox": [529.57, 103.51, 36.53, 36.53], "category_id": 3}], "caption": "Scheme 1. Reaction of Huisgen Zwitterion with Cyclic and                  Acyclic 1,2-Diones ", "pdf": {"Page": 1, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [448, 811, 767, 838], "ImageBB": [439, 842, 777, 964]}, "reactions": [{"reactants": [0], "conditions": [12], "products": [1]}, {"reactants": [1, 2], "conditions": [3], "products": [6]}, {"reactants": [1, 5], "conditions": [7], "products": [8]}], "diagram_type": "single"}, {"id": 433, "width": 3396, "height": 2324, "file_name": "op300087r-Figure-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [2289.0, 818.0, 412.0, 110.0], "category_id": 2}, {"id": 1, "bbox": [840.55, 1412.75, 32.0, 51.0], "category_id": 3}, {"id": 2, "bbox": [838.0, 820.0, 40.2, 44.5], "category_id": 3}, {"id": 3, "bbox": [1607.2, 850.0, 158.8, 61.0], "category_id": 2}, {"id": 4, "bbox": [594.0, 1023.0, 589.1, 389.0], "category_id": 1}, {"id": 5, "bbox": [2203.54, 1038.88, 590.0, 341.0], "category_id": 1}, {"id": 6, "bbox": [2211.0, 448.0, 578.8, 341.3], "category_id": 1}, {"id": 7, "bbox": [609.0, 451.0, 568.4, 377.0], "category_id": 1}, {"id": 8, "bbox": [2282.0, 1405.0, 419.0, 100.0], "category_id": 2}, {"id": 9, "bbox": [1286.0, 1208.0, 567.0, 142.0], "category_id": 2}, {"id": 10, "bbox": [1293.0, 1059.0, 794.0, 137.0], "category_id": 2}, {"id": 11, "bbox": [1615.0, 1408.0, 158.0, 56.0], "category_id": 2}, {"id": 12, "bbox": [1283.0, 633.0, 619.0, 200.0], "category_id": 2}, {"id": 13, "bbox": [1291.0, 470.0, 582.0, 156.0], "category_id": 2}], "reactions": [{"reactants": [7], "conditions": [13, 12], "products": [6]}, {"reactants": [4], "conditions": [10, 9], "products": [5]}], "corefs": [[7, 2], [6, 0], [4, 1], [5, 8]], "caption": "Figure 3. Optical micrographs of bosutinib monohydrate isolated from: A) water, and B) MIBK/water.", "pdf": {"Page": 4, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 612, 584, 626], "ImageBB": [10, 22, 859, 603]}, "diagram_type": "multiple"}, {"id": 135, "width": 1188, "height": 1220, "file_name": "op8002486-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1.0, 663.0, 401.0, 141.1], "category_id": 1}, {"id": 1, "bbox": [330.0, 174.0, 114.0, 50.1], "category_id": 2}, {"id": 2, "bbox": [3.0, 987.0, 409.0, 140.0], "category_id": 1}, {"id": 3, "bbox": [167.93, 1168.14, 69.17, 50.31], "category_id": 3}, {"id": 4, "bbox": [171.07, 826.98, 64.46, 55.02], "category_id": 3}, {"id": 5, "bbox": [171.07, 510.97, 64.46, 56.6], "category_id": 3}, {"id": 6, "bbox": [175.79, 166.67, 58.17, 51.88], "category_id": 3}, {"id": 7, "bbox": [1073.0, 525.0, 111.0, 54.0], "category_id": 2}, {"id": 8, "bbox": [325.0, 508.0, 122.0, 53.0], "category_id": 2}, {"id": 9, "bbox": [536.0, 343.0, 111.0, 56.0], "category_id": 2}, {"id": 10, "bbox": [946.0, 241.0, 207.0, 55.0], "category_id": 2}, {"id": 11, "bbox": [1080.0, 169.0, 100.0, 59.0], "category_id": 2}, {"id": 12, "bbox": [526.0, 7.0, 116.0, 69.0], "category_id": 2}, {"id": 13, "bbox": [702.0, 993.0, 426.0, 147.0], "category_id": 1}, {"id": 14, "bbox": [704.0, 663.0, 402.0, 138.0], "category_id": 1}, {"id": 15, "bbox": [704.0, 347.0, 444.0, 174.0], "category_id": 1}, {"id": 16, "bbox": [2.0, 339.0, 462.0, 163.0], "category_id": 1}, {"id": 17, "bbox": [701.0, 12.0, 375.0, 169.0], "category_id": 1}, {"id": 18, "bbox": [2.0, 4.0, 370.0, 164.0], "category_id": 1}, {"id": 19, "bbox": [329.0, 1145.0, 118.0, 55.0], "category_id": 2}, {"id": 20, "bbox": [1076.0, 1150.0, 106.0, 63.0], "category_id": 2}, {"id": 21, "bbox": [538.0, 1000.0, 111.0, 65.0], "category_id": 2}, {"id": 22, "bbox": [950.0, 894.0, 200.0, 62.0], "category_id": 2}, {"id": 23, "bbox": [1073.0, 791.0, 111.0, 50.0], "category_id": 2}, {"id": 24, "bbox": [533.0, 658.0, 114.0, 67.0], "category_id": 2}, {"id": 25, "bbox": [332.0, 829.0, 116.0, 50.0], "category_id": 2}], "reactions": [{"reactants": [18], "conditions": [12], "products": [17]}, {"reactants": [17], "conditions": [], "products": [18]}, {"reactants": [17], "conditions": [10], "products": [15]}, {"reactants": [15], "conditions": [], "products": [17]}, {"reactants": [16], "conditions": [9], "products": [15]}, {"reactants": [15], "conditions": [], "products": [16]}, {"reactants": [0], "conditions": [24], "products": [14]}, {"reactants": [14], "conditions": [], "products": [0]}, {"reactants": [14], "conditions": [22], "products": [13]}, {"reactants": [13], "conditions": [], "products": [14]}, {"reactants": [13], "conditions": [], "products": [2]}, {"reactants": [2], "conditions": [21], "products": [13]}], "corefs": [[18, 6], [16, 5], [0, 4], [2, 3]], "caption": "Table 1. Predicted reaction times for cyanate conversion to reach >95% with KOCN addition times of 0.25 h, 0.5 h, and 1 h (20 \u00b0C, 2 mol % excess of 15) ", "pdf": {"Page": 6, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [425, 382, 760, 424], "ImageBB": [445, 65, 742, 370]}, "diagram_type": "tree"}, {"id": 549, "width": 1348, "height": 496, "file_name": "acs.orglett.5b03104-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [572.0, 235.0, 343.0, 52.9], "category_id": 2}, {"id": 1, "bbox": [624.0, 310.0, 239.0, 89.8], "category_id": 2}, {"id": 2, "bbox": [60.0, 220.3, 284.9, 143.4], "category_id": 1}, {"id": 3, "bbox": [924.1, 199.3, 359.6, 187.2], "category_id": 1}, {"id": 4, "bbox": [629.28, 175.27, 52.86, 45.75], "category_id": 3}, {"id": 5, "bbox": [7.13, 425.35, 1333.77, 70.15], "category_id": 4}, {"id": 6, "bbox": [590.4, 0.0, 309.3, 229.0], "category_id": 1}, {"id": 7, "bbox": [382.0, 243.0, 179.0, 104.0], "category_id": 1}], "reactions": [{"reactants": [2, 7], "conditions": [6, 0, 1], "products": [3]}], "corefs": [[6, 4]], "caption": "Table 1. Selected Entries of Reaction Optimizationa", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 89, 744, 110], "ImageBB": [449, 116, 786, 240]}, "diagram_type": "single"}, {"id": 822, "width": 2820, "height": 1680, "file_name": "jo400755q-Table-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [580.0, 1014.0, 391.0, 427.0], "category_id": 1}, {"id": 1, "bbox": [727.0, 0.0, 330.0, 317.0], "category_id": 1}, {"id": 2, "bbox": [1732.0, 90.0, 359.0, 69.0], "category_id": 2}, {"id": 3, "bbox": [1057.0, 30.0, 316.0, 99.0], "category_id": 2}, {"id": 4, "bbox": [1061.0, 139.0, 325.0, 95.0], "category_id": 2}, {"id": 5, "bbox": [1873.0, 401.0, 412.0, 447.0], "category_id": 1}, {"id": 6, "bbox": [0.0, 1567.0, 2733.0, 113.0], "category_id": 2}, {"id": 7, "bbox": [1441.0, 427.5, 417.0, 420.5], "category_id": 1}, {"id": 8, "bbox": [1384.0, 0.0, 332.2, 311.7], "category_id": 1}, {"id": 9, "bbox": [542.3, 420.3, 355.4, 417.7], "category_id": 1}, {"id": 10, "bbox": [920.3, 416.0, 484.2, 458.0], "category_id": 1}, {"id": 11, "bbox": [1799.0, 1030.8, 481.7, 315.7], "category_id": 1}, {"id": 12, "bbox": [1221.3, 992.0, 298.7, 437.5], "category_id": 1}, {"id": 13, "bbox": [770.0, 304.0, 194.0, 53.0], "category_id": 3}, {"id": 14, "bbox": [1507.0, 304.0, 95.0, 53.0], "category_id": 3}, {"id": 15, "bbox": [1976.0, 867.0, 277.0, 73.0], "category_id": 3}, {"id": 16, "bbox": [1531.0, 863.0, 256.0, 68.0], "category_id": 3}, {"id": 17, "bbox": [1054.0, 874.0, 259.0, 60.0], "category_id": 3}, {"id": 18, "bbox": [603.0, 871.0, 255.0, 60.0], "category_id": 3}, {"id": 19, "bbox": [663.0, 1448.0, 254.0, 70.0], "category_id": 3}, {"id": 20, "bbox": [1223.0, 1450.0, 242.0, 66.0], "category_id": 3}, {"id": 21, "bbox": [1802.0, 1443.0, 263.0, 69.0], "category_id": 3}], "reactions": [{"reactants": [1], "conditions": [3, 4], "products": [8]}], "corefs": [[1, 13], [8, 14], [9, 18], [10, 17], [7, 16], [5, 15], [0, 19], [12, 20], [11, 21]], "caption": "Table 4. Ortho-Iodination of N-Aryl Ring of N,1-Diaryl-1H-tetrazol-5-aminea", "pdf": {"Page": 5, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 89, 517, 111], "ImageBB": [82, 116, 787, 536]}, "diagram_type": "single"}, {"id": 647, "width": 1348, "height": 420, "file_name": "ol500444z-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [984.0, 275.0, 81.0, 43.0], "category_id": 3}, {"id": 1, "bbox": [842.9, 93.6, 346.1, 156.7], "category_id": 1}, {"id": 2, "bbox": [462.3, 2.7, 275.8, 158.7], "category_id": 1}, {"id": 3, "bbox": [164.33, 109.25, 218.37, 142.45], "category_id": 1}, {"id": 4, "bbox": [220.0, 259.0, 78.0, 42.0], "category_id": 3}, {"id": 5, "bbox": [508.0, 195.0, 231.0, 81.0], "category_id": 2}, {"id": 6, "bbox": [32.0, 352.0, 1294.0, 65.0], "category_id": 4}], "reactions": [{"reactants": [3], "conditions": [2, 5], "products": [1]}], "corefs": [[3, 4], [1, 0]], "caption": "Table 1. Synthesis of Quinoxalinesa", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 212, 285, 233], "ImageBB": [82, 239, 419, 344]}, "diagram_type": "single"}, {"id": 1365, "width": 884, "height": 864, "file_name": "op960008m-Scheme-c14.png", "license": 0, "bboxes": [{"id": 0, "bbox": [642.99, 652.2, 218.46, 211.8], "category_id": 1}, {"id": 1, "bbox": [628.4, 313.05, 255.6, 169.8], "category_id": 1}, {"id": 2, "bbox": [256.05, 321.01, 178.65, 108.78], "category_id": 1}, {"id": 3, "bbox": [256.05, 4.5, 175.12, 96.7], "category_id": 1}, {"id": 4, "bbox": [13.71, 38.03, 209.17, 71.37], "category_id": 1}, {"id": 5, "bbox": [636.9, 0.0, 247.1, 131.7], "category_id": 1}, {"id": 6, "bbox": [0.0, 292.71, 210.5, 149.46], "category_id": 1}, {"id": 7, "bbox": [256.05, 694.64, 154.33, 103.03], "category_id": 1}, {"id": 8, "bbox": [15.04, 704.81, 212.7, 84.9], "category_id": 1}], "caption": "Scheme 14. Selected reactions catalysed by KF/alumina", "pdf": {"Page": 14, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [73, 197, 388, 211], "ImageBB": [131, 216, 352, 432]}, "reactions": [{"reactants": [4, 3], "conditions": [], "products": [5]}, {"reactants": [6, 2], "conditions": [], "products": [1]}, {"reactants": [8, 7], "conditions": [], "products": [0]}], "diagram_type": "multiple"}, {"id": 470, "width": 1352, "height": 732, "file_name": "op100205s-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [971.0, 3.0, 377.0, 273.0], "category_id": 1}, {"id": 1, "bbox": [596.0, 11.0, 341.0, 275.0], "category_id": 1}, {"id": 2, "bbox": [2.0, 8.0, 339.0, 278.0], "category_id": 1}, {"id": 3, "bbox": [863.0, 252.0, 66.0, 34.0], "category_id": 3}, {"id": 4, "bbox": [1241.0, 252.0, 66.0, 34.0], "category_id": 3}, {"id": 5, "bbox": [263.0, 250.0, 48.0, 40.0], "category_id": 3}, {"id": 6, "bbox": [5.0, 305.0, 1338.0, 419.0], "category_id": 4}, {"id": 7, "bbox": [348.0, 105.0, 206.0, 40.0], "category_id": 2}], "reactions": [{"reactants": [2], "conditions": [7], "products": [1, 0]}], "corefs": [[2, 5], [1, 3], [0, 4]], "caption": "Table 3. Screen of conditions for pyridine N-methylation of 9b ", "pdf": {"Page": 6, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 46, 386, 73], "ImageBB": [58, 88, 396, 271]}, "diagram_type": "single"}, {"id": 114, "width": 1012, "height": 1472, "file_name": "op990044w-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [831.0, 1019.4, 42.8, 48.6], "category_id": 3}, {"id": 1, "bbox": [709.0, 932.7, 122.0, 196.3], "category_id": 1}, {"id": 2, "bbox": [241.5, 379.6, 123.5, 190.9], "category_id": 1}, {"id": 3, "bbox": [609.1, 628.8, 402.9, 191.5], "category_id": 1}, {"id": 4, "bbox": [650.0, 81.2, 289.2, 226.5], "category_id": 1}, {"id": 5, "bbox": [75.8, 78.5, 288.7, 226.8], "category_id": 1}, {"id": 6, "bbox": [0.0, 999.1, 279.9, 80.9], "category_id": 2}, {"id": 7, "bbox": [757.0, 272.0, 69.0, 53.0], "category_id": 3}, {"id": 8, "bbox": [171.0, 271.0, 66.0, 55.0], "category_id": 3}, {"id": 9, "bbox": [369.0, 464.0, 34.0, 58.0], "category_id": 3}, {"id": 10, "bbox": [410.0, 1419.0, 54.0, 53.0], "category_id": 3}, {"id": 11, "bbox": [293.0, 1149.0, 328.0, 235.0], "category_id": 1}, {"id": 12, "bbox": [777.0, 828.0, 77.0, 60.0], "category_id": 3}, {"id": 13, "bbox": [172.0, 846.0, 51.0, 50.0], "category_id": 3}, {"id": 14, "bbox": [509.0, 411.0, 269.0, 80.0], "category_id": 2}, {"id": 15, "bbox": [136.0, 0.0, 158.0, 47.0], "category_id": 2}, {"id": 16, "bbox": [55.0, 610.0, 330.0, 212.0], "category_id": 1}, {"id": 17, "bbox": [719.0, 0.0, 160.0, 52.0], "category_id": 2}], "reactions": [{"reactants": [5], "conditions": [2], "products": [16]}, {"reactants": [16], "conditions": [6], "products": [11]}, {"reactants": [4], "conditions": [14], "products": [3]}, {"reactants": [3], "conditions": [1], "products": [11]}], "corefs": [[5, 8], [4, 7], [2, 9], [16, 13], [3, 12], [1, 0], [11, 10]], "caption": "Table 1. Horner-Emmons reaction of aldehyde (5b) and triethyl phosphonoacetatea ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 454, 753, 482], "ImageBB": [482, 74, 735, 442]}, "diagram_type": "tree"}, {"id": 665, "width": 1348, "height": 1260, "file_name": "ol402047d-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [837.0, 108.0, 96.1, 248.0], "category_id": 1}, {"id": 1, "bbox": [401.0, 205.0, 145.0, 42.0], "category_id": 2}, {"id": 2, "bbox": [229.0, 0.0, 257.0, 250.0], "category_id": 1}, {"id": 3, "bbox": [1008.0, 392.0, 31.0, 35.0], "category_id": 3}, {"id": 4, "bbox": [1103.0, 226.0, 160.0, 78.0], "category_id": 2}, {"id": 5, "bbox": [0.0, 453.0, 1348.0, 807.0], "category_id": 4}, {"id": 6, "bbox": [654.0, 211.0, 144.0, 38.0], "category_id": 2}, {"id": 7, "bbox": [93.0, 225.0, 152.0, 81.0], "category_id": 2}, {"id": 8, "bbox": [241.0, 251.0, 301.0, 46.0], "category_id": 2}, {"id": 9, "bbox": [864.0, 359.0, 35.0, 42.0], "category_id": 3}, {"id": 10, "bbox": [983.0, 105.0, 93.0, 290.0], "category_id": 1}, {"id": 11, "bbox": [619.0, 113.0, 211.0, 86.0], "category_id": 1}, {"id": 12, "bbox": [738.0, 182.0, 32.0, 31.0], "category_id": 3}, {"id": 13, "bbox": [582.0, 249.0, 230.0, 164.0], "category_id": 2}], "reactions": [{"reactants": [7], "conditions": [2, 1, 8, 11, 6, 13], "products": [0, 10, 4]}], "corefs": [[11, 12], [0, 9], [10, 3]], "caption": "Table 2. Structure Activity Study of Siloxane Polymers in CCRa", "pdf": {"Page": 3, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 85, 771, 101], "ImageBB": [436, 112, 773, 427]}, "diagram_type": "single"}, {"id": 450, "width": 1688, "height": 992, "file_name": "op2001047-Table-c5.png", "license": 0, "bboxes": [{"id": 0, "bbox": [310.0, 551.0, 45.0, 36.0], "category_id": 3}, {"id": 1, "bbox": [43.0, 598.3, 290.4, 177.7], "category_id": 1}, {"id": 2, "bbox": [6.0, 405.6, 364.7, 173.4], "category_id": 1}, {"id": 3, "bbox": [1023.3, 1.3, 238.4, 125.4], "category_id": 1}, {"id": 4, "bbox": [433.0, 2.3, 148.4, 126.7], "category_id": 1}, {"id": 5, "bbox": [1120.0, 152.0, 92.4, 50.0], "category_id": 3}, {"id": 6, "bbox": [727.0, 125.0, 184.7, 44.0], "category_id": 2}, {"id": 7, "bbox": [49.6, 797.6, 275.1, 183.4], "category_id": 1}, {"id": 8, "bbox": [263.0, 756.0, 54.0, 29.0], "category_id": 3}, {"id": 9, "bbox": [274.0, 946.0, 49.0, 46.0], "category_id": 3}, {"id": 10, "bbox": [7.0, 284.0, 1677.0, 708.0], "category_id": 4}, {"id": 11, "bbox": [653.0, 3.0, 337.0, 93.0], "category_id": 2}, {"id": 12, "bbox": [464.0, 165.0, 102.0, 36.0], "category_id": 3}], "reactions": [{"reactants": [4], "conditions": [11, 6], "products": [3]}], "corefs": [[4, 12], [3, 5], [2, 0], [1, 8], [7, 9]], "caption": "Table 5. Reaction optimization for the aldol reaction of acetone with aldehydes 4a c under microwave batch and continuous \ufb02ow conditionsa ", "pdf": {"Page": 6, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [71, 88, 770, 122], "ImageBB": [211, 133, 633, 381]}, "diagram_type": "single"}, {"id": 1140, "width": 1352, "height": 2000, "file_name": "ol016466j-Scheme-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [750.47, 1196.6, 375.23, 66.03], "category_id": 2}, {"id": 1, "bbox": [445.28, 4.0, 45.02, 46.03], "category_id": 3}, {"id": 2, "bbox": [508.32, 556.28, 343.21, 124.06], "category_id": 2}, {"id": 3, "bbox": [750.47, 1269.63, 395.24, 63.04], "category_id": 2}, {"id": 4, "bbox": [486.3, 90.05, 287.18, 111.05], "category_id": 2}, {"id": 5, "bbox": [397.25, 492.25, 51.03, 54.02], "category_id": 3}, {"id": 6, "bbox": [264.16, 1715.86, 422.27, 110.05], "category_id": 3}, {"id": 7, "bbox": [486.3, 1188.59, 55.04, 63.04], "category_id": 3}, {"id": 8, "bbox": [132.08, 1015.51, 582.36, 234.11], "category_id": 1}, {"id": 9, "bbox": [103.06, 92.05, 1013.63, 467.23], "category_id": 1}, {"id": 10, "bbox": [103.06, 517.26, 826.52, 460.04], "category_id": 1}, {"id": 11, "bbox": [103.06, 1238.8, 1144.14, 599.12], "category_id": 1}, {"id": 12, "bbox": [750.47, 1083.54, 422.26, 116.06], "category_id": 2}, {"id": 13, "bbox": [132.08, 941.47, 658.22, 104.05], "category_id": 3}], "caption": "Scheme 2", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [578, 534, 631, 547], "ImageBB": [439, 553, 777, 1053]}, "reactions": [{"reactants": [1], "conditions": [4], "products": [9]}, {"reactants": [9], "conditions": [2], "products": [10]}, {"reactants": [8], "conditions": [12, 0, 3], "products": [11]}], "diagram_type": "tree"}, {"id": 553, "width": 1348, "height": 296, "file_name": "acs.orglett.5b02545-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [861.0, 13.0, 251.0, 144.0], "category_id": 1}, {"id": 1, "bbox": [240.0, 3.0, 252.0, 160.0], "category_id": 1}, {"id": 2, "bbox": [644.0, 48.0, 76.0, 35.0], "category_id": 2}, {"id": 3, "bbox": [542.0, 94.0, 281.0, 73.0], "category_id": 2}, {"id": 4, "bbox": [295.0, 165.0, 38.0, 29.0], "category_id": 3}, {"id": 5, "bbox": [920.0, 162.0, 45.0, 34.0], "category_id": 3}, {"id": 6, "bbox": [8.0, 219.0, 1327.0, 77.0], "category_id": 4}], "reactions": [{"reactants": [1], "conditions": [2, 3], "products": [0]}], "corefs": [[1, 4], [0, 5]], "caption": "Table 1. Reaction Optimizationa", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 89, 632, 110], "ImageBB": [449, 116, 786, 190]}, "diagram_type": "single"}, {"id": 778, "width": 1348, "height": 1224, "file_name": "jo951899j-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [200.0, 52.0, 275.0, 217.0], "category_id": 1}, {"id": 1, "bbox": [553.0, 275.0, 84.0, 35.0], "category_id": 2}, {"id": 2, "bbox": [162.0, 109.0, 27.0, 34.0], "category_id": 3}, {"id": 3, "bbox": [755.0, 559.9, 448.0, 232.1], "category_id": 3}, {"id": 4, "bbox": [1031.0, 703.0, 121.0, 41.0], "category_id": 3}, {"id": 5, "bbox": [529.0, 504.0, 141.0, 180.0], "category_id": 2}, {"id": 6, "bbox": [523.0, 721.0, 148.0, 47.0], "category_id": 2}, {"id": 7, "bbox": [786.0, 866.0, 365.0, 48.0], "category_id": 2}, {"id": 8, "bbox": [153.0, 486.0, 349.0, 185.0], "category_id": 3}, {"id": 9, "bbox": [0.0, 977.0, 1348.0, 247.0], "category_id": 4}, {"id": 10, "bbox": [227.0, 872.0, 101.0, 38.0], "category_id": 3}, {"id": 11, "bbox": [147.0, 526.0, 29.0, 47.0], "category_id": 3}, {"id": 12, "bbox": [252.0, 393.0, 46.0, 34.0], "category_id": 3}, {"id": 13, "bbox": [1018.0, 229.0, 42.0, 36.0], "category_id": 3}, {"id": 14, "bbox": [158.0, 333.0, 339.0, 37.0], "category_id": 1}, {"id": 15, "bbox": [136.0, 763.0, 345.0, 49.0], "category_id": 1}, {"id": 16, "bbox": [747.0, 124.0, 447.0, 230.0], "category_id": 1}, {"id": 17, "bbox": [532.0, 5.0, 150.0, 227.0], "category_id": 2}], "reactions": [{"reactants": [0, 14], "conditions": [17, 1], "products": [16]}, {"reactants": [8, 15], "conditions": [5, 6], "products": [3]}], "corefs": [[0, 2], [14, 12], [16, 13], [8, 11], [15, 10], [3, 4]], "caption": "Table 2. Synthesis of the Azidogalactosyl Compounds", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [72, 55, 390, 67], "ImageBB": [63, 77, 400, 383]}, "diagram_type": "multiple"}, {"id": 946, "width": 1356, "height": 572, "file_name": "acs.orglett.5b02279-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [487.73, 477.8, 210.28, 48.19], "category_id": 3}, {"id": 1, "bbox": [487.73, 312.88, 262.51, 149.99], "category_id": 1}, {"id": 2, "bbox": [487.73, 194.11, 232.67, 52.94], "category_id": 3}, {"id": 3, "bbox": [480.94, 6.79, 276.09, 175.1], "category_id": 1}, {"id": 4, "bbox": [340.53, 351.57, 103.1, 42.08], "category_id": 2}, {"id": 5, "bbox": [330.35, 114.7, 108.54, 46.83], "category_id": 2}, {"id": 6, "bbox": [354.77, 40.04, 73.26, 52.26], "category_id": 2}, {"id": 7, "bbox": [741.42, 223.97, 130.92, 54.98], "category_id": 2}, {"id": 8, "bbox": [912.37, 409.93, 345.95, 51.59], "category_id": 3}, {"id": 9, "bbox": [43.41, 295.23, 288.98, 158.82], "category_id": 1}, {"id": 10, "bbox": [41.38, 0.0, 271.33, 183.25], "category_id": 1}, {"id": 11, "bbox": [56.98, 473.05, 241.49, 51.58], "category_id": 2}, {"id": 12, "bbox": [912.37, 132.35, 401.57, 270.8], "category_id": 1}], "caption": "Scheme 1. Proposed [4 + 3] Cycloadditions of in situ Generated Allylic Ylides and Aza-o-quinone Methides ", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 599, 754, 629], "ImageBB": [448, 636, 787, 779]}, "reactions": [{"reactants": [10], "conditions": [6, 5], "products": [3]}, {"reactants": [9], "conditions": [4], "products": [1]}, {"reactants": [3, 1], "conditions": [7], "products": [12]}], "diagram_type": "tree"}, {"id": 335, "width": 1348, "height": 2060, "file_name": "ol300353w-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [497.0, 126.0, 275.5, 109.1], "category_id": 2}, {"id": 1, "bbox": [140.0, 1811.0, 65.0, 49.0], "category_id": 3}, {"id": 2, "bbox": [436.0, 1603.0, 68.0, 52.0], "category_id": 3}, {"id": 3, "bbox": [893.0, 1804.0, 68.0, 61.0], "category_id": 3}, {"id": 4, "bbox": [410.9, 1447.0, 253.1, 219.0], "category_id": 1}, {"id": 5, "bbox": [775.0, 1544.0, 542.0, 253.0], "category_id": 1}, {"id": 6, "bbox": [432.7, 1680.0, 278.6, 232.9], "category_id": 2}, {"id": 7, "bbox": [802.0, 7.0, 412.0, 221.0], "category_id": 1}, {"id": 8, "bbox": [137.0, 5.0, 306.0, 231.0], "category_id": 1}, {"id": 9, "bbox": [260.0, 246.0, 73.0, 50.0], "category_id": 3}, {"id": 10, "bbox": [4.0, 414.0, 1344.0, 668.0], "category_id": 4}, {"id": 11, "bbox": [544.0, 47.0, 178.0, 56.0], "category_id": 2}, {"id": 12, "bbox": [36.0, 1530.0, 314.0, 260.0], "category_id": 1}, {"id": 13, "bbox": [974.0, 1811.0, 213.0, 56.0], "category_id": 2}, {"id": 14, "bbox": [7.0, 1291.0, 1341.0, 128.0], "category_id": 2}], "reactions": [{"reactants": [8], "conditions": [11, 0], "products": [7]}, {"reactants": [12], "conditions": [4, 6], "products": [5]}], "corefs": [[8, 9], [12, 1], [4, 2], [5, 3]], "caption": "Table 1. Conversion of Aldehydes to Syn-Aldol Products", "pdf": {"Page": 3, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 522, 741, 535], "ImageBB": [436, 547, 773, 1062]}, "diagram_type": "multiple"}, {"id": 1373, "width": 1284, "height": 1172, "file_name": "op990044w-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [88.3, 73.21, 116.1, 190.72], "category_id": 1}, {"id": 1, "bbox": [235.09, 483.56, 330.15, 120.73], "category_id": 1}, {"id": 2, "bbox": [668.01, 1001.8, 82.22, 40.45], "category_id": 2}, {"id": 3, "bbox": [621.77, 90.55, 134.88, 37.24], "category_id": 2}, {"id": 4, "bbox": [621.77, 547.13, 89.28, 40.46], "category_id": 2}, {"id": 5, "bbox": [44.96, 550.99, 84.15, 41.1], "category_id": 2}, {"id": 6, "bbox": [928.15, 663.37, 48.82, 50.09], "category_id": 3}, {"id": 7, "bbox": [654.53, 940.15, 111.12, 42.38], "category_id": 2}, {"id": 8, "bbox": [398.88, 1123.17, 44.32, 46.23], "category_id": 3}, {"id": 9, "bbox": [806.76, 0.0, 328.86, 211.92], "category_id": 1}, {"id": 10, "bbox": [928.15, 289.62, 49.46, 51.38], "category_id": 3}, {"id": 11, "bbox": [283.26, 58.44, 328.87, 224.76], "category_id": 1}, {"id": 12, "bbox": [969.9, 1113.53, 186.92, 50.74], "category_id": 3}, {"id": 13, "bbox": [806.76, 399.43, 332.72, 209.35], "category_id": 1}, {"id": 14, "bbox": [8.35, 927.3, 274.27, 71.28], "category_id": 2}, {"id": 15, "bbox": [657.09, 148.98, 80.29, 41.1], "category_id": 2}, {"id": 16, "bbox": [848.51, 744.92, 435.49, 309.53], "category_id": 1}, {"id": 17, "bbox": [126.54, 296.04, 40.46, 48.17], "category_id": 3}, {"id": 18, "bbox": [0.0, 489.34, 181.13, 44.95], "category_id": 2}, {"id": 19, "bbox": [603.78, 485.49, 156.09, 45.59], "category_id": 2}, {"id": 20, "bbox": [421.36, 294.76, 66.8, 51.37], "category_id": 3}, {"id": 21, "bbox": [350.71, 665.29, 43.68, 48.17], "category_id": 3}, {"id": 22, "bbox": [73.22, 1009.5, 84.15, 41.1], "category_id": 2}, {"id": 23, "bbox": [276.2, 828.41, 333.36, 238.25], "category_id": 1}], "caption": "Scheme 1. Original route to FK453 (1)", "pdf": {"Page": 1, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 580, 663, 594], "ImageBB": [448, 603, 769, 896]}, "reactions": [{"reactants": [0, 11], "conditions": [3, 15], "products": [9]}, {"reactants": [9], "conditions": [18, 5], "products": [1]}, {"reactants": [1], "conditions": [19, 4], "products": [13]}, {"reactants": [13], "conditions": [14, 22], "products": [23]}, {"reactants": [23], "conditions": [7, 2], "products": [16]}], "diagram_type": "multiple"}, {"id": 1093, "width": 1292, "height": 1488, "file_name": "jo961049j-Scheme-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1105.3, 902.92, 115.17, 56.58], "category_id": 2}, {"id": 1, "bbox": [1083.57, 1437.97, 64.31, 50.03], "category_id": 3}, {"id": 2, "bbox": [376.04, 0.0, 293.39, 320.82], "category_id": 1}, {"id": 3, "bbox": [714.85, 1239.38, 205.53, 94.53], "category_id": 2}, {"id": 4, "bbox": [1010.48, 556.79, 274.02, 264.25], "category_id": 1}, {"id": 5, "bbox": [101.27, 1244.59, 188.4, 89.32], "category_id": 2}, {"id": 6, "bbox": [946.44, 2.98, 320.19, 262.76], "category_id": 1}, {"id": 7, "bbox": [930.06, 1004.16, 199.56, 93.04], "category_id": 2}, {"id": 8, "bbox": [84.89, 81.14, 210.73, 89.32], "category_id": 2}, {"id": 9, "bbox": [291.9, 755.54, 256.16, 52.85], "category_id": 2}, {"id": 10, "bbox": [130.31, 852.31, 47.66, 49.12], "category_id": 3}, {"id": 11, "bbox": [84.89, 1347.31, 218.92, 51.37], "category_id": 2}, {"id": 12, "bbox": [711.88, 850.07, 69.25, 52.85], "category_id": 3}, {"id": 13, "bbox": [496.68, 276.91, 69.25, 50.61], "category_id": 3}, {"id": 14, "bbox": [488.48, 1437.38, 61.81, 50.62], "category_id": 3}, {"id": 15, "bbox": [927.82, 384.84, 209.25, 97.51], "category_id": 2}, {"id": 16, "bbox": [968.78, 1149.31, 273.28, 284.35], "category_id": 1}, {"id": 17, "bbox": [327.64, 687.06, 176.48, 59.55], "category_id": 2}, {"id": 18, "bbox": [691.03, 907.39, 128.82, 58.06], "category_id": 2}, {"id": 19, "bbox": [711.88, 78.9, 196.58, 95.28], "category_id": 2}, {"id": 20, "bbox": [84.89, 188.33, 216.69, 54.34], "category_id": 2}, {"id": 21, "bbox": [1061.86, 274.67, 69.99, 52.11], "category_id": 3}, {"id": 22, "bbox": [1112.49, 847.1, 77.45, 54.33], "category_id": 3}, {"id": 23, "bbox": [610.61, 565.72, 344.02, 255.32], "category_id": 1}, {"id": 24, "bbox": [0.0, 525.53, 301.58, 369.95], "category_id": 1}, {"id": 25, "bbox": [374.55, 1173.87, 300.84, 263.63], "category_id": 1}], "caption": "Scheme 3", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [572, 49, 635, 63], "ImageBB": [445, 70, 768, 442]}, "reactions": [{"reactants": [24], "conditions": [8, 20], "products": [2]}, {"reactants": [2], "conditions": [19], "products": [6]}, {"reactants": [24], "conditions": [17, 9], "products": [23]}, {"reactants": [6], "conditions": [15], "products": [23]}, {"reactants": [24], "conditions": [5, 11], "products": [25]}, {"reactants": [25], "conditions": [3], "products": [16]}, {"reactants": [16], "conditions": [7], "products": [4]}], "diagram_type": "graph"}, {"id": 351, "width": 1204, "height": 1232, "file_name": "ol2017438-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [604.0, 280.0, 175.0, 40.0], "category_id": 3}, {"id": 1, "bbox": [628.0, 6.0, 93.0, 38.0], "category_id": 2}, {"id": 2, "bbox": [837.0, 6.0, 60.0, 38.0], "category_id": 2}, {"id": 3, "bbox": [1024.0, 6.0, 180.0, 41.0], "category_id": 2}, {"id": 4, "bbox": [183.0, 11.0, 353.0, 131.0], "category_id": 1}, {"id": 5, "bbox": [0.0, 66.0, 128.0, 176.0], "category_id": 1}, {"id": 6, "bbox": [146.17, 3.32, 146.99, 46.24], "category_id": 2}, {"id": 7, "bbox": [586.0, 35.0, 362.0, 250.0], "category_id": 1}, {"id": 8, "bbox": [4.0, 435.0, 1200.0, 797.0], "category_id": 4}, {"id": 9, "bbox": [1058.0, 277.0, 112.0, 43.0], "category_id": 3}, {"id": 10, "bbox": [151.0, 164.6, 383.1, 52.4], "category_id": 2}, {"id": 11, "bbox": [117.0, 235.0, 454.0, 83.0], "category_id": 2}, {"id": 12, "bbox": [1016.8, 47.0, 187.2, 219.0], "category_id": 1}], "reactions": [{"reactants": [5], "conditions": [6, 4, 10, 11], "products": [7]}, {"reactants": [7], "conditions": [], "products": [12]}], "corefs": [[7, 0], [12, 9]], "caption": "Table 2. Scope of the Asymmetric Aza-Annulationa", "pdf": {"Page": 4, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [71, 85, 346, 101], "ImageBB": [89, 112, 390, 420]}, "diagram_type": "single"}, {"id": 1300, "width": 2820, "height": 512, "file_name": "op200351g-Scheme-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1275.28, 114.28, 221.48, 63.48], "category_id": 2}, {"id": 1, "bbox": [1309.13, 292.04, 135.43, 53.61], "category_id": 2}, {"id": 2, "bbox": [2003.2, 420.42, 53.61, 47.97], "category_id": 3}, {"id": 3, "bbox": [1821.22, 208.8, 371.02, 173.53], "category_id": 1}, {"id": 4, "bbox": [1845.2, 122.74, 331.52, 62.08], "category_id": 2}, {"id": 5, "bbox": [550.18, 417.6, 43.73, 50.79], "category_id": 3}, {"id": 6, "bbox": [740.62, 327.31, 141.07, 62.08], "category_id": 2}, {"id": 7, "bbox": [2278.29, 166.48, 53.61, 50.79], "category_id": 3}, {"id": 8, "bbox": [1532.03, 14.11, 273.67, 363.99], "category_id": 1}, {"id": 9, "bbox": [1654.76, 416.19, 66.3, 55.02], "category_id": 3}, {"id": 10, "bbox": [479.64, 29.63, 253.93, 331.54], "category_id": 1}, {"id": 11, "bbox": [691.25, 115.69, 227.12, 62.07], "category_id": 2}, {"id": 12, "bbox": [1063.67, 417.6, 60.66, 50.79], "category_id": 3}, {"id": 13, "bbox": [734.98, 215.86, 138.25, 49.37], "category_id": 2}, {"id": 14, "bbox": [969.15, 25.39, 259.57, 335.78], "category_id": 1}, {"id": 15, "bbox": [1309.13, 213.03, 152.36, 62.08], "category_id": 2}], "caption": "Scheme 4. Synthesis of ketoamide 11 via azide/Staudinger sequence", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 735, 466, 750], "ImageBB": [82, 756, 787, 884]}, "reactions": [{"reactants": [10], "conditions": [11, 13, 6], "products": [14]}, {"reactants": [14], "conditions": [0, 15, 1], "products": [8]}, {"reactants": [8, 3], "conditions": [4], "products": [7]}], "diagram_type": "single"}, {"id": 1247, "width": 1348, "height": 896, "file_name": "op034064g-Scheme-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [198.93, 550.28, 63.39, 53.95], "category_id": 3}, {"id": 1, "bbox": [427.53, 132.85, 88.34, 45.86], "category_id": 2}, {"id": 2, "bbox": [1086.36, 847.0, 64.73, 49.0], "category_id": 3}, {"id": 3, "bbox": [1145.7, 573.88, 202.3, 61.37], "category_id": 2}, {"id": 4, "bbox": [526.66, 376.97, 251.53, 52.6], "category_id": 2}, {"id": 5, "bbox": [700.64, 178.71, 69.45, 54.62], "category_id": 3}, {"id": 6, "bbox": [1129.51, 259.63, 195.56, 66.76], "category_id": 2}, {"id": 7, "bbox": [529.35, 457.22, 231.98, 55.29], "category_id": 2}, {"id": 8, "bbox": [1082.31, 175.33, 49.23, 47.21], "category_id": 3}, {"id": 9, "bbox": [1085.68, 498.35, 53.28, 50.58], "category_id": 3}, {"id": 10, "bbox": [218.49, 170.61, 54.62, 51.93], "category_id": 3}, {"id": 11, "bbox": [84.97, 16.18, 308.84, 152.41], "category_id": 1}, {"id": 12, "bbox": [427.53, 60.02, 91.04, 44.51], "category_id": 2}, {"id": 13, "bbox": [573.19, 12.14, 320.98, 153.08], "category_id": 1}, {"id": 14, "bbox": [0.0, 400.57, 405.28, 168.59], "category_id": 1}, {"id": 15, "bbox": [885.94, 684.15, 456.06, 155.96], "category_id": 1}, {"id": 16, "bbox": [882.03, 369.55, 386.37, 157.95], "category_id": 1}, {"id": 17, "bbox": [948.79, 2.7, 300.08, 145.3], "category_id": 1}], "caption": "Scheme 3", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 594, 501, 608], "ImageBB": [440, 612, 777, 836]}, "reactions": [{"reactants": [11], "conditions": [], "products": [14]}, {"reactants": [11], "conditions": [12], "products": [13, 17]}, {"reactants": [13, 17], "conditions": [1], "products": [11]}, {"reactants": [17], "conditions": [6], "products": [16]}, {"reactants": [14], "conditions": [4], "products": [16]}, {"reactants": [16], "conditions": [7], "products": [14]}, {"reactants": [16], "conditions": [3], "products": [15]}], "diagram_type": "graph"}, {"id": 146, "width": 1352, "height": 2780, "file_name": "op700249f-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [318.0, 180.0, 465.0, 96.2], "category_id": 2}, {"id": 1, "bbox": [940.0, 241.0, 134.0, 56.0], "category_id": 3}, {"id": 2, "bbox": [8.0, 2546.0, 1344.0, 234.0], "category_id": 2}, {"id": 3, "bbox": [1.0, 317.0, 1351.0, 2183.0], "category_id": 4}, {"id": 4, "bbox": [0.0, 26.0, 359.0, 210.0], "category_id": 1}, {"id": 5, "bbox": [807.0, 26.0, 445.0, 258.0], "category_id": 1}, {"id": 6, "bbox": [97.0, 238.0, 134.0, 59.0], "category_id": 3}, {"id": 7, "bbox": [373.0, 32.0, 343.0, 104.0], "category_id": 2}], "reactions": [{"reactants": [4], "conditions": [7, 0], "products": [5]}], "corefs": [[4, 6], [5, 1]], "caption": "Table 2. Scope of CuAAC to prepare C-triazole-linked glycoamino acids ", "pdf": {"Page": 4, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 178, 361, 205], "ImageBB": [58, 207, 396, 902]}, "diagram_type": "single"}, {"id": 547, "width": 960, "height": 2376, "file_name": "acs.orglett.5b03589-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [753.04, 253.96, 48.0, 37.0], "category_id": 3}, {"id": 1, "bbox": [508.06, 171.13, 36.87, 40.55], "category_id": 3}, {"id": 2, "bbox": [4.0, 433.0, 956.0, 1943.0], "category_id": 4}, {"id": 3, "bbox": [341.14, 136.85, 48.15, 46.66], "category_id": 2}, {"id": 4, "bbox": [82.0, 57.0, 234.0, 127.0], "category_id": 1}, {"id": 5, "bbox": [97.0, 194.0, 214.0, 48.0], "category_id": 3}, {"id": 6, "bbox": [341.0, 0.0, 283.0, 111.0], "category_id": 2}, {"id": 7, "bbox": [647.0, 7.0, 239.0, 224.0], "category_id": 1}, {"id": 8, "bbox": [389.0, 139.0, 231.0, 121.0], "category_id": 1}, {"id": 9, "bbox": [348.6, 333.7, 252.4, 73.3], "category_id": 2}, {"id": 10, "bbox": [395.0, 255.0, 203.9, 73.8], "category_id": 2}], "reactions": [{"reactants": [4], "conditions": [6, 3, 8, 10, 9], "products": [7]}], "corefs": [[4, 5], [8, 1], [7, 0]], "caption": "Table 2. Scope of Tandem Coupling/Cyclization Reactions with Functionalized Benzoic Acids ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 233, 777, 263], "ImageBB": [497, 269, 737, 863]}, "diagram_type": "single"}, {"id": 430, "width": 2820, "height": 808, "file_name": "op300171m-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1193.5, 77.5, 484.8, 683.7], "category_id": 1}, {"id": 1, "bbox": [937.0, 351.0, 38.0, 36.0], "category_id": 3}, {"id": 2, "bbox": [1591.0, 341.0, 274.0, 60.0], "category_id": 2}, {"id": 3, "bbox": [677.5, 166.0, 509.5, 170.0], "category_id": 1}, {"id": 4, "bbox": [325.8, 323.3, 408.8, 244.9], "category_id": 1}, {"id": 5, "bbox": [537.0, 627.0, 40.0, 65.0], "category_id": 3}, {"id": 6, "bbox": [1305.0, 627.0, 48.0, 72.0], "category_id": 3}, {"id": 7, "bbox": [1835.6, 2.1, 475.6, 653.9], "category_id": 1}, {"id": 8, "bbox": [775.0, 442.0, 400.0, 149.0], "category_id": 2}, {"id": 9, "bbox": [1688.0, 444.0, 96.0, 58.0], "category_id": 2}, {"id": 10, "bbox": [1926.0, 658.0, 575.0, 113.8], "category_id": 2}], "reactions": [{"reactants": [4], "conditions": [3, 8], "products": [0]}, {"reactants": [0], "conditions": [2, 9], "products": [7]}], "corefs": [[4, 5], [3, 1], [0, 6]], "caption": "Table 3. Reaction Condition Optimization of Ammonolysis in the Synthesis of Vilazodone", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 636, 592, 651], "ImageBB": [82, 427, 787, 629]}, "diagram_type": "single"}, {"id": 728, "width": 1488, "height": 1812, "file_name": "ol016693l-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [885.0, 1510.0, 315.0, 109.0], "category_id": 2}, {"id": 1, "bbox": [458.0, 1681.0, 206.0, 130.0], "category_id": 1}, {"id": 2, "bbox": [413.0, 1515.0, 269.0, 96.0], "category_id": 2}, {"id": 3, "bbox": [923.0, 1689.0, 253.0, 64.0], "category_id": 2}, {"id": 4, "bbox": [114.0, 80.0, 1374.0, 1035.0], "category_id": 2}, {"id": 5, "bbox": [610.0, 1291.0, 355.1, 192.0], "category_id": 1}], "reactions": [{"reactants": [5], "conditions": [0], "products": [3]}, {"reactants": [5], "conditions": [2], "products": [1]}], "corefs": [], "caption": "Figure 1.", "pdf": {"Page": 1, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 990, 491, 1003], "ImageBB": [408, 525, 780, 978]}, "diagram_type": "tree"}, {"id": 759, "width": 1340, "height": 1760, "file_name": "jo982004g-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [810.55, 559.45, 470.01, 199.24], "category_id": 1}, {"id": 1, "bbox": [225.58, 1318.11, 355.07, 53.65], "category_id": 2}, {"id": 2, "bbox": [601.09, 613.09, 212.01, 56.2], "category_id": 2}, {"id": 3, "bbox": [675.16, 682.06, 58.76, 48.53], "category_id": 2}, {"id": 4, "bbox": [524.0, 818.7, 419.0, 287.3], "category_id": 1}, {"id": 5, "bbox": [369.3, 774.0, 53.2, 46.4], "category_id": 3}, {"id": 6, "bbox": [713.28, 1100.64, 43.0, 58.0], "category_id": 3}, {"id": 7, "bbox": [168.1, 1508.0, 523.3, 209.6], "category_id": 1}, {"id": 8, "bbox": [475.0, 244.6, 358.7, 130.4], "category_id": 1}, {"id": 9, "bbox": [741.9, 1500.4, 507.6, 212.4], "category_id": 1}, {"id": 10, "bbox": [588.0, 1355.0, 158.0, 53.3], "category_id": 2}, {"id": 11, "bbox": [234.7, 610.2, 362.5, 112.7], "category_id": 1}, {"id": 12, "bbox": [962.5, 1368.29, 44.82, 51.9], "category_id": 3}, {"id": 13, "bbox": [358.53, 1712.74, 49.55, 47.26], "category_id": 3}, {"id": 14, "bbox": [924.75, 1710.38, 49.55, 47.19], "category_id": 3}, {"id": 15, "bbox": [123.0, 1317.0, 44.7, 55.0], "category_id": 3}, {"id": 16, "bbox": [588.0, 1280.0, 132.0, 60.0], "category_id": 2}, {"id": 17, "bbox": [885.0, 1427.0, 390.0, 64.3], "category_id": 2}, {"id": 18, "bbox": [1003.0, 780.0, 44.0, 49.0], "category_id": 3}, {"id": 19, "bbox": [565.0, 393.0, 308.0, 147.0], "category_id": 3}, {"id": 20, "bbox": [666.0, 1710.0, 101.0, 50.0], "category_id": 3}, {"id": 21, "bbox": [934.0, 858.0, 364.0, 95.0], "category_id": 2}, {"id": 22, "bbox": [152.0, 667.0, 40.0, 46.0], "category_id": 3}, {"id": 23, "bbox": [784.0, 1272.0, 541.1, 104.8], "category_id": 1}], "reactions": [{"reactants": [22, 11], "conditions": [2, 3], "products": [0]}, {"reactants": [0], "conditions": [21], "products": [4]}, {"reactants": [15, 1], "conditions": [16, 10], "products": [23]}, {"reactants": [23], "conditions": [17], "products": [7, 9]}], "corefs": [[8, 19], [11, 5], [0, 18], [4, 6], [23, 12], [7, 13], [9, 14]], "caption": "Table 1. Diastereomeric Ratio (dr) of Adducts Shown in                       Scheme 2 ", "pdf": {"Page": 1, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [441, 486, 772, 511], "ImageBB": [426, 35, 761, 475]}, "diagram_type": "tree"}, {"id": 334, "width": 1340, "height": 732, "file_name": "ol300387f-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [938.0, 232.0, 154.0, 42.0], "category_id": 3}, {"id": 1, "bbox": [694.0, 230.0, 87.0, 41.0], "category_id": 3}, {"id": 2, "bbox": [251.0, 228.0, 89.0, 44.0], "category_id": 3}, {"id": 3, "bbox": [637.3, 6.9, 181.4, 194.4], "category_id": 1}, {"id": 4, "bbox": [441.7, 141.9, 118.4, 42.3], "category_id": 2}, {"id": 5, "bbox": [907.2, 4.9, 236.2, 212.1], "category_id": 1}, {"id": 6, "bbox": [414.0, 73.23, 174.0, 39.0], "category_id": 2}, {"id": 7, "bbox": [2.0, 307.0, 1338.0, 422.0], "category_id": 4}, {"id": 8, "bbox": [195.1, 3.3, 188.5, 235.6], "category_id": 1}], "reactions": [{"reactants": [8], "conditions": [6, 4], "products": [3]}, {"reactants": [8], "conditions": [6, 4], "products": [5]}], "corefs": [[8, 2], [3, 1], [5, 0]], "caption": "Table 1. Addition to Geminal Dimethylated Cyclohex-2-enones", "pdf": {"Page": 2, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 87, 771, 100], "ImageBB": [437, 112, 772, 295]}, "diagram_type": "single"}, {"id": 748, "width": 1352, "height": 656, "file_name": "jo990938e-Table-c8.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1346.0, 649.0, 6.0, 5.0], "category_id": 4}, {"id": 1, "bbox": [0.0, 266.0, 1351.0, 390.0], "category_id": 4}, {"id": 2, "bbox": [406.0, 130.0, 211.0, 100.0], "category_id": 2}, {"id": 3, "bbox": [127.0, 13.0, 286.0, 222.0], "category_id": 1}, {"id": 4, "bbox": [1035.92, 183.22, 115.22, 48.94], "category_id": 3}, {"id": 5, "bbox": [735.14, 182.2, 120.31, 40.79], "category_id": 3}, {"id": 6, "bbox": [547.53, 46.6, 38.74, 43.84], "category_id": 3}, {"id": 7, "bbox": [471.7, 1.0, 130.3, 113.1], "category_id": 1}, {"id": 8, "bbox": [917.8, 16.0, 305.1, 207.7], "category_id": 1}, {"id": 9, "bbox": [633.0, 13.0, 297.0, 213.8], "category_id": 1}, {"id": 10, "bbox": [446.59, 54.24, 43.84, 39.77], "category_id": 2}, {"id": 11, "bbox": [266.0, 185.0, 47.0, 40.0], "category_id": 3}], "reactions": [{"reactants": [3], "conditions": [10, 7, 2], "products": [9, 8]}], "corefs": [[3, 11], [7, 6], [9, 5], [8, 4]], "caption": "Table 8. Additions of Transient Chiral Allenylindium Reagents from Mesylate 11 to Representative Achiral                      Aldehydes ", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [449, 356, 764, 393], "ImageBB": [439, 403, 777, 567]}, "diagram_type": "single"}, {"id": 1301, "width": 1352, "height": 716, "file_name": "op3000042-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [108.21, 42.61, 168.69, 62.89], "category_id": 1}, {"id": 1, "bbox": [1062.53, 273.89, 147.44, 60.87], "category_id": 2}, {"id": 2, "bbox": [971.22, 158.93, 38.55, 45.98], "category_id": 3}, {"id": 3, "bbox": [686.48, 105.5, 138.65, 55.45], "category_id": 2}, {"id": 4, "bbox": [980.69, 621.5, 38.55, 46.66], "category_id": 3}, {"id": 5, "bbox": [894.8, 0.0, 344.93, 165.69], "category_id": 1}, {"id": 6, "bbox": [837.31, 370.6, 390.92, 231.29], "category_id": 1}, {"id": 7, "bbox": [738.56, 488.95, 97.39, 52.75], "category_id": 2}, {"id": 8, "bbox": [351.7, 451.08, 308.41, 172.45], "category_id": 1}, {"id": 9, "bbox": [178.55, 158.25, 41.94, 47.34], "category_id": 3}, {"id": 10, "bbox": [363.19, 0.0, 242.81, 163.66], "category_id": 1}, {"id": 11, "bbox": [685.81, 10.14, 145.41, 58.16], "category_id": 2}, {"id": 12, "bbox": [487.64, 158.93, 43.29, 45.98], "category_id": 3}, {"id": 13, "bbox": [403.1, 623.53, 39.23, 45.99], "category_id": 3}], "caption": "Scheme 1. Ritter\u2019s originally proposed mechanism", "pdf": {"Page": 5, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 365, 110], "ImageBB": [82, 116, 420, 295]}, "reactions": [{"reactants": [0, 10], "conditions": [11], "products": [5]}, {"reactants": [5], "conditions": [3], "products": [0, 10]}, {"reactants": [5], "conditions": [1], "products": [6]}, {"reactants": [6], "conditions": [], "products": [5]}, {"reactants": [6], "conditions": [7], "products": [8]}], "diagram_type": "tree"}, {"id": 928, "width": 1416, "height": 632, "file_name": "acs.oprd.5b00209-Scheme-c10.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1217.66, 90.66, 55.25, 47.46], "category_id": 3}, {"id": 1, "bbox": [771.4, 0.0, 66.58, 45.33], "category_id": 3}, {"id": 2, "bbox": [1093.7, 163.62, 162.92, 51.0], "category_id": 2}, {"id": 3, "bbox": [1103.62, 534.77, 59.5, 50.29], "category_id": 3}, {"id": 4, "bbox": [769.98, 137.41, 123.25, 94.2], "category_id": 2}, {"id": 5, "bbox": [1070.32, 87.83, 63.76, 54.54], "category_id": 3}, {"id": 6, "bbox": [609.18, 247.2, 51.01, 49.58], "category_id": 3}, {"id": 7, "bbox": [955.57, 366.19, 398.09, 148.04], "category_id": 1}, {"id": 8, "bbox": [794.77, 422.86, 46.75, 53.12], "category_id": 3}, {"id": 9, "bbox": [771.4, 49.58, 147.34, 43.21], "category_id": 2}, {"id": 10, "bbox": [1390.5, 32.0, 25.5, 43.08], "category_id": 2}, {"id": 11, "bbox": [490.89, 393.11, 225.96, 55.95], "category_id": 2}, {"id": 12, "bbox": [489.47, 488.02, 250.76, 97.74], "category_id": 2}, {"id": 13, "bbox": [424.3, 60.91, 294.68, 161.5], "category_id": 1}], "caption": "Scheme 10. Current Sulfamoylation Process", "pdf": {"Page": 6, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 330, 110], "ImageBB": [82, 116, 436, 274]}, "reactions": [{"reactants": [13], "conditions": [1, 9, 4], "products": [5, 0]}, {"reactants": [], "conditions": [11, 12], "products": [8, 7]}], "diagram_type": "multiple"}, {"id": 1344, "width": 1952, "height": 1264, "file_name": "op700160a-Scheme-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [258.77, 94.74, 96.67, 60.55], "category_id": 2}, {"id": 1, "bbox": [111.32, 250.03, 55.66, 58.6], "category_id": 3}, {"id": 2, "bbox": [972.58, 319.38, 52.73, 60.55], "category_id": 3}, {"id": 3, "bbox": [393.52, 52.74, 225.57, 170.92], "category_id": 1}, {"id": 4, "bbox": [1215.73, 88.88, 99.6, 65.44], "category_id": 2}, {"id": 5, "bbox": [600.54, 239.29, 140.61, 138.69], "category_id": 1}, {"id": 6, "bbox": [0.0, 79.11, 232.4, 150.41], "category_id": 1}, {"id": 7, "bbox": [838.8, 30.28, 319.32, 292.03], "category_id": 1}, {"id": 8, "bbox": [1336.81, 49.81, 230.45, 246.12], "category_id": 1}, {"id": 9, "bbox": [1700.07, 319.38, 172.83, 60.55], "category_id": 3}, {"id": 10, "bbox": [1409.07, 319.38, 124.02, 62.5], "category_id": 3}, {"id": 11, "bbox": [738.23, 322.31, 46.87, 57.62], "category_id": 3}, {"id": 12, "bbox": [1647.34, 46.88, 234.35, 249.05], "category_id": 1}], "caption": "Scheme 4. Theoretical lanthanide-catalyst-promoted formation of cis-1 and trans-1 with 3D representation", "pdf": {"Page": 3, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 46, 644, 60], "ImageBB": [166, 65, 654, 381]}, "reactions": [{"reactants": [6], "conditions": [0], "products": [3]}, {"reactants": [3, 5], "conditions": [], "products": [7]}, {"reactants": [7], "conditions": [4], "products": [8, 12]}], "diagram_type": "single"}, {"id": 1338, "width": 1352, "height": 472, "file_name": "op5003165-Scheme-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [686.48, 79.87, 114.98, 33.84], "category_id": 2}, {"id": 1, "bbox": [459.91, 2.71, 206.28, 206.44], "category_id": 1}, {"id": 2, "bbox": [75.75, 223.37, 46.67, 43.32], "category_id": 3}, {"id": 3, "bbox": [18.26, 18.28, 209.67, 182.07], "category_id": 1}, {"id": 4, "bbox": [264.45, 119.81, 133.24, 74.45], "category_id": 2}, {"id": 5, "bbox": [271.89, 20.98, 119.71, 69.72], "category_id": 2}, {"id": 6, "bbox": [660.78, 256.53, 121.07, 71.08], "category_id": 2}, {"id": 7, "bbox": [654.7, 354.68, 135.26, 76.49], "category_id": 2}, {"id": 8, "bbox": [911.03, 227.43, 41.25, 37.23], "category_id": 3}, {"id": 9, "bbox": [863.01, 6.09, 206.28, 207.8], "category_id": 1}, {"id": 10, "bbox": [1166.68, 226.08, 44.64, 38.58], "category_id": 3}, {"id": 11, "bbox": [1123.4, 6.09, 209.66, 207.8], "category_id": 1}, {"id": 12, "bbox": [493.73, 228.11, 41.25, 35.19], "category_id": 3}], "caption": "Scheme 4. Synthesis of intermediate lactam (11)", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 433, 357, 448], "ImageBB": [82, 455, 420, 573]}, "reactions": [{"reactants": [3], "conditions": [5, 4], "products": [1]}, {"reactants": [1], "conditions": [0], "products": [9, 11]}, {"reactants": [9], "conditions": [6, 7], "products": [1]}], "diagram_type": "graph"}, {"id": 207, "width": 1352, "height": 560, "file_name": "op0340964-Figure-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [760.0, 370.0, 82.0, 58.0], "category_id": 2}, {"id": 1, "bbox": [757.0, 474.0, 179.0, 86.0], "category_id": 2}, {"id": 2, "bbox": [333.0, 172.0, 182.0, 91.0], "category_id": 2}, {"id": 3, "bbox": [334.0, 74.0, 77.0, 57.0], "category_id": 2}, {"id": 4, "bbox": [1021.0, 302.0, 325.0, 224.0], "category_id": 1}, {"id": 5, "bbox": [355.0, 302.0, 340.0, 226.0], "category_id": 1}, {"id": 6, "bbox": [6.0, 4.0, 270.0, 224.0], "category_id": 1}], "reactions": [{"reactants": [6], "conditions": [3, 2], "products": [5]}, {"reactants": [5], "conditions": [0, 1], "products": [4]}], "corefs": [], "caption": "Figure 3. Acid-catalyzed stereoretentive hydrolysis of (R)-2- chloromandelonitrile into (R)-2-chloromandelic acid. ", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 751, 409, 779], "ImageBB": [73, 607, 411, 747]}, "diagram_type": "multiple"}, {"id": 1361, "width": 1356, "height": 620, "file_name": "op900197r-Scheme-c9.png", "license": 0, "bboxes": [{"id": 0, "bbox": [753.63, 261.37, 52.24, 44.8], "category_id": 2}, {"id": 1, "bbox": [553.52, 577.73, 48.85, 37.33], "category_id": 3}, {"id": 2, "bbox": [1322.76, 295.99, 33.24, 41.41], "category_id": 3}, {"id": 3, "bbox": [976.13, 500.33, 52.91, 40.74], "category_id": 3}, {"id": 4, "bbox": [326.28, 60.42, 90.22, 46.84], "category_id": 2}, {"id": 5, "bbox": [345.27, 401.9, 52.24, 47.52], "category_id": 2}, {"id": 6, "bbox": [106.5, 577.73, 45.45, 37.33], "category_id": 3}, {"id": 7, "bbox": [4.75, 350.98, 287.61, 197.55], "category_id": 1}, {"id": 8, "bbox": [71.9, 2.04, 188.58, 232.85], "category_id": 1}, {"id": 9, "bbox": [105.14, 242.36, 39.35, 38.7], "category_id": 3}, {"id": 10, "bbox": [521.64, 12.9, 262.52, 209.09], "category_id": 1}, {"id": 11, "bbox": [452.45, 353.02, 326.96, 195.51], "category_id": 1}, {"id": 12, "bbox": [877.09, 147.32, 327.64, 330.61], "category_id": 1}, {"id": 13, "bbox": [1192.52, 262.73, 50.88, 43.44], "category_id": 2}, {"id": 14, "bbox": [555.56, 239.64, 56.3, 41.42], "category_id": 3}], "caption": "Scheme 9. Alternative Hofmann and amine coupling sequencea ", "pdf": {"Page": 4, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [425, 46, 719, 73], "ImageBB": [424, 83, 763, 238]}, "reactions": [{"reactants": [8], "conditions": [4], "products": [10]}, {"reactants": [7], "conditions": [5], "products": [11]}, {"reactants": [10, 11], "conditions": [0], "products": [12]}, {"reactants": [12], "conditions": [13], "products": [2]}], "diagram_type": "tree"}, {"id": 163, "width": 1356, "height": 1184, "file_name": "op7000172-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [15.0, 406.0, 567.0, 247.0], "category_id": 1}, {"id": 1, "bbox": [840.7, 976.9, 481.4, 93.5], "category_id": 2}, {"id": 2, "bbox": [675.0, 479.6, 443.0, 109.4], "category_id": 2}, {"id": 3, "bbox": [829.0, 752.0, 130.0, 48.0], "category_id": 2}, {"id": 4, "bbox": [364.0, 145.0, 132.0, 51.0], "category_id": 2}, {"id": 5, "bbox": [374.0, 211.0, 118.0, 82.0], "category_id": 2}, {"id": 6, "bbox": [970.0, 147.0, 113.0, 51.0], "category_id": 2}, {"id": 7, "bbox": [663.0, 281.0, 57.0, 47.0], "category_id": 3}, {"id": 8, "bbox": [168.0, 295.0, 66.0, 53.0], "category_id": 3}, {"id": 9, "bbox": [211.0, 703.0, 72.0, 53.0], "category_id": 3}, {"id": 10, "bbox": [679.0, 1082.0, 51.0, 68.0], "category_id": 3}, {"id": 11, "bbox": [0.0, 46.0, 369.0, 243.0], "category_id": 1}, {"id": 12, "bbox": [671.05, 419.29, 250.89, 56.71], "category_id": 1}, {"id": 13, "bbox": [1032.59, 352.35, 72.0, 52.0], "category_id": 3}, {"id": 14, "bbox": [670.9, 606.0, 457.1, 119.0], "category_id": 1}, {"id": 15, "bbox": [908.0, 224.2, 329.0, 146.8], "category_id": 1}, {"id": 16, "bbox": [505.3, 59.8, 342.7, 217.8], "category_id": 1}, {"id": 17, "bbox": [855.94, 694.24, 51.0, 53.0], "category_id": 3}, {"id": 18, "bbox": [262.6, 811.7, 566.4, 366.3], "category_id": 1}, {"id": 19, "bbox": [896.9, 7.0, 332.1, 136.0], "category_id": 1}], "reactions": [{"reactants": [11], "conditions": [4, 5], "products": [16]}, {"reactants": [16], "conditions": [19, 6, 15], "products": [0]}, {"reactants": [0], "conditions": [12, 2, 14, 3], "products": [18]}], "corefs": [[11, 8], [16, 7], [15, 13], [0, 9], [14, 17], [18, 10]], "caption": "Table 2. Palladium content of coupling products 17, 21, 31, and 34 before and after scavenging ", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 393, 400, 421], "ImageBB": [73, 85, 412, 381]}, "diagram_type": "multiple"}, {"id": 593, "width": 2816, "height": 740, "file_name": "acs.oprd.6b00128-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1970.5, 178.6, 290.9, 183.2], "category_id": 3}, {"id": 1, "bbox": [1567.9, 0.0, 391.1, 368.9], "category_id": 1}, {"id": 2, "bbox": [1202.0, 189.0, 341.0, 182.0], "category_id": 2}, {"id": 3, "bbox": [591.0, 323.0, 373.0, 84.0], "category_id": 2}, {"id": 4, "bbox": [1269.0, 81.0, 185.0, 80.0], "category_id": 2}, {"id": 5, "bbox": [976.0, 48.0, 193.5, 262.5], "category_id": 1}, {"id": 6, "bbox": [555.2, 6.9, 382.6, 285.1], "category_id": 1}, {"id": 7, "bbox": [0.0, 415.0, 2816.0, 325.0], "category_id": 4}, {"id": 8, "bbox": [739.4, 234.8, 50.6, 50.4], "category_id": 3}], "reactions": [{"reactants": [6, 5], "conditions": [4, 2], "products": [1]}], "corefs": [[6, 8]], "caption": "Table 2. PdCl2(dppf) Facilitates Coupling Reactions on a Small Scalea", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 807, 481, 829], "ImageBB": [82, 834, 786, 1019]}, "diagram_type": "single"}, {"id": 467, "width": 2520, "height": 1704, "file_name": "op100267p-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [407.0, 113.0, 377.0, 242.0], "category_id": 1}, {"id": 1, "bbox": [2.0, 374.0, 2518.0, 1330.0], "category_id": 4}, {"id": 2, "bbox": [1075.0, 234.0, 284.0, 110.0], "category_id": 2}, {"id": 3, "bbox": [1061.0, 1.0, 448.0, 208.0], "category_id": 2}, {"id": 4, "bbox": [1639.0, 40.0, 477.0, 315.0], "category_id": 1}, {"id": 5, "bbox": [879.9, 124.3, 157.5, 180.4], "category_id": 1}], "reactions": [{"reactants": [0, 5], "conditions": [3, 2], "products": [4]}], "corefs": [], "caption": "Table 2. Electron-de\ufb01cient amide-substituted arylboronic acid substrate scopea", "pdf": {"Page": 4, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [71, 87, 509, 108], "ImageBB": [107, 117, 737, 543]}, "diagram_type": "single"}, {"id": 93, "width": 1344, "height": 784, "file_name": "ja053368a-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [667.69, 149.08, 163.11, 35.32], "category_id": 2}, {"id": 1, "bbox": [1023.23, 33.49, 264.72, 152.62], "category_id": 1}, {"id": 2, "bbox": [212.31, 54.5, 261.22, 107.09], "category_id": 1}, {"id": 3, "bbox": [3.89, 215.64, 1334.85, 558.96], "category_id": 4}, {"id": 4, "bbox": [54.7, 66.8, 105.31, 114.06], "category_id": 1}, {"id": 5, "bbox": [494.29, 72.02, 502.92, 40.53], "category_id": 2}], "reactions": [{"reactants": [4, 2], "conditions": [5, 0], "products": [1]}], "corefs": [], "caption": "Table 2. DA Reaction of 2,3-Dimethylbutadiene with R-Acyloxyacroleina ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 64, 338, 86], "ImageBB": [74, 85, 410, 281]}, "diagram_type": "single"}, {"id": 142, "width": 1312, "height": 636, "file_name": "op700292s-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [33.9, 82.9, 154.5, 546.2], "category_id": 1}, {"id": 1, "bbox": [1243.0, 332.9, 69.0, 80.2], "category_id": 2}, {"id": 2, "bbox": [773.8, 77.9, 382.3, 557.1], "category_id": 1}, {"id": 3, "bbox": [264.9, 226.9, 85.5, 284.1], "category_id": 1}, {"id": 4, "bbox": [445.9, 377.9, 251.2, 131.5], "category_id": 2}, {"id": 5, "bbox": [425.9, 172.0, 321.2, 175.1], "category_id": 2}], "reactions": [{"reactants": [0, 3], "conditions": [5, 4], "products": [2, 1]}], "corefs": [], "caption": "Table 2. Chemical yields of 3,6-diphenyl-4-n-butylpyridazine under various experimental conditions ", "pdf": {"Page": 6, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [425, 216, 759, 243], "ImageBB": [425, 45, 753, 204]}, "diagram_type": "single"}, {"id": 394, "width": 1356, "height": 1016, "file_name": "op5001385-Figure-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [78.0, 191.0, 23.0, 39.0], "category_id": 3}, {"id": 1, "bbox": [103.0, 785.0, 85.0, 54.0], "category_id": 3}, {"id": 2, "bbox": [863.0, 766.0, 85.0, 47.0], "category_id": 3}, {"id": 3, "bbox": [691.0, 960.0, 506.0, 56.0], "category_id": 2}, {"id": 4, "bbox": [689.0, 847.0, 532.0, 88.0], "category_id": 2}, {"id": 5, "bbox": [629.0, 31.0, 126.0, 58.0], "category_id": 2}, {"id": 6, "bbox": [0.0, 27.0, 218.0, 151.8], "category_id": 1}, {"id": 7, "bbox": [78.1, 325.1, 430.4, 502.8], "category_id": 1}, {"id": 8, "bbox": [814.0, 208.9, 230.6, 48.1], "category_id": 3}, {"id": 9, "bbox": [1236.55, 80.0, 114.0, 56.0], "category_id": 2}, {"id": 10, "bbox": [621.55, 119.0, 138.0, 57.0], "category_id": 2}, {"id": 11, "bbox": [878.8, 4.55, 267.9, 210.15], "category_id": 1}, {"id": 12, "bbox": [304.5, 8.0, 241.6, 177.0], "category_id": 1}, {"id": 13, "bbox": [795.6, 325.9, 482.4, 430.1], "category_id": 1}, {"id": 14, "bbox": [395.64, 186.91, 126.0, 34.0], "category_id": 2}], "reactions": [{"reactants": [6, 12], "conditions": [5, 10], "products": [11, 9]}], "corefs": [[6, 0], [11, 8], [7, 1], [13, 2]], "caption": "Figure 2. Through-space NOE interactions in 11a\u2212b.", "pdf": {"Page": 4, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 564, 712, 578], "ImageBB": [448, 301, 787, 555]}, "diagram_type": "single"}, {"id": 1182, "width": 1356, "height": 1796, "file_name": "ol4005905-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [850.3, 841.85, 454.81, 244.38], "category_id": 1}, {"id": 1, "bbox": [517.73, 589.38, 313.69, 63.79], "category_id": 2}, {"id": 2, "bbox": [587.53, 8.62, 77.61, 43.13], "category_id": 2}, {"id": 3, "bbox": [600.46, 401.03, 64.68, 40.96], "category_id": 2}, {"id": 4, "bbox": [677.0, 371.96, 394.41, 110.51], "category_id": 1}, {"id": 5, "bbox": [592.33, 67.38, 271.45, 243.48], "category_id": 1}, {"id": 6, "bbox": [1026.47, 434.85, 324.48, 362.07], "category_id": 1}, {"id": 7, "bbox": [219.32, 986.5, 97.97, 53.9], "category_id": 2}, {"id": 8, "bbox": [474.58, 835.56, 306.51, 278.52], "category_id": 1}, {"id": 9, "bbox": [186.96, 774.46, 185.16, 185.98], "category_id": 2}, {"id": 10, "bbox": [581.55, 778.06, 155.49, 50.31], "category_id": 3}, {"id": 11, "bbox": [17.08, 111.41, 343.35, 141.95], "category_id": 1}, {"id": 12, "bbox": [135.72, 579.5, 65.62, 53.01], "category_id": 3}, {"id": 13, "bbox": [671.7, 0.0, 201.97, 57.5], "category_id": 1}, {"id": 14, "bbox": [0.0, 1263.8, 1348.25, 532.2], "category_id": 2}, {"id": 15, "bbox": [0.0, 374.8, 556.38, 378.1], "category_id": 1}, {"id": 16, "bbox": [1122.64, 672.04, 65.62, 53.91], "category_id": 3}, {"id": 17, "bbox": [383.8, 110.51, 146.51, 64.69], "category_id": 2}, {"id": 18, "bbox": [981.53, 53.01, 280.43, 257.85], "category_id": 1}, {"id": 19, "bbox": [520.42, 492.35, 303.81, 59.3], "category_id": 2}, {"id": 20, "bbox": [929.39, 777.16, 136.63, 51.21], "category_id": 3}], "caption": "Scheme 1. Initial Unexpected Observations", "pdf": {"Page": 1, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 549, 666, 562], "ImageBB": [436, 574, 775, 1023]}, "reactions": [{"reactants": [11], "conditions": [17], "products": [5]}, {"reactants": [5], "conditions": [], "products": [18]}, {"reactants": [15], "conditions": [9, 7], "products": [8, 0]}, {"reactants": [15], "conditions": [19, 1], "products": [8, 0]}], "diagram_type": "graph"}, {"id": 741, "width": 1340, "height": 924, "file_name": "ol010283f-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [893.28, 22.19, 443.0, 274.0], "category_id": 1}, {"id": 1, "bbox": [1091.0, 275.81, 83.0, 47.0], "category_id": 3}, {"id": 2, "bbox": [631.9, 94.0, 218.2, 50.5], "category_id": 2}, {"id": 3, "bbox": [610.53, 175.9, 262.58, 49.55], "category_id": 2}, {"id": 4, "bbox": [195.0, 409.0, 1037.0, 515.0], "category_id": 4}, {"id": 5, "bbox": [239.0, 279.0, 86.0, 58.0], "category_id": 3}, {"id": 6, "bbox": [0.0, 0.0, 548.0, 274.0], "category_id": 1}], "reactions": [{"reactants": [6], "conditions": [2, 3], "products": [0]}], "corefs": [[6, 5], [0, 1]], "caption": "Table 2. Effect of Ruthenium Porphyrin Catalysts on Cyclization of (-)-Menthyl-\u03b3-benzyloxy-R-diazo-\u03b2-ketoesterd ", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 702, 757, 730], "ImageBB": [440, 733, 775, 964]}, "diagram_type": "single"}, {"id": 1266, "width": 2136, "height": 320, "file_name": "op060099f-Scheme-c5.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1318.57, 249.66, 98.31, 66.15], "category_id": 3}, {"id": 1, "bbox": [1807.96, 3.2, 328.04, 243.26], "category_id": 1}, {"id": 2, "bbox": [1860.32, 257.13, 255.38, 62.87], "category_id": 3}, {"id": 3, "bbox": [0.0, 4.27, 329.11, 242.19], "category_id": 1}, {"id": 4, "bbox": [1197.83, 13.87, 329.11, 213.39], "category_id": 1}, {"id": 5, "bbox": [589.83, 4.27, 330.18, 242.19], "category_id": 1}, {"id": 6, "bbox": [1597.46, 81.09, 154.94, 52.28], "category_id": 2}], "caption": "Scheme 5. Oxidation of 2,3-substituted indoles as reported by Hino et al.", "pdf": {"Page": 6, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 464, 483, 478], "ImageBB": [158, 482, 692, 562]}, "reactions": [{"reactants": [3], "conditions": [], "products": [5]}, {"reactants": [5], "conditions": [], "products": [4]}, {"reactants": [4], "conditions": [], "products": [5]}, {"reactants": [4], "conditions": [6], "products": [1]}], "diagram_type": "single"}, {"id": 1287, "width": 2808, "height": 696, "file_name": "op200086t-Scheme-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1694.07, 39.38, 118.0, 52.04], "category_id": 2}, {"id": 1, "bbox": [2160.43, 464.12, 99.74, 66.1], "category_id": 2}, {"id": 2, "bbox": [1689.86, 431.77, 108.16, 50.63], "category_id": 2}, {"id": 3, "bbox": [2015.75, 569.6, 264.08, 57.66], "category_id": 2}, {"id": 4, "bbox": [1796.61, 232.06, 144.69, 53.44], "category_id": 2}, {"id": 5, "bbox": [817.54, 225.03, 168.56, 60.47], "category_id": 2}, {"id": 6, "bbox": [515.53, 4.22, 259.87, 187.05], "category_id": 1}, {"id": 7, "bbox": [1976.42, 8.44, 283.75, 185.64], "category_id": 1}, {"id": 8, "bbox": [2052.27, 194.08, 112.38, 60.48], "category_id": 3}, {"id": 9, "bbox": [950.98, 40.79, 75.86, 50.63], "category_id": 2}, {"id": 10, "bbox": [547.7, 382.54, 210.84, 52.04], "category_id": 2}, {"id": 11, "bbox": [581.55, 195.49, 112.37, 59.07], "category_id": 3}, {"id": 12, "bbox": [1293.6, 382.54, 153.24, 56.26], "category_id": 2}, {"id": 13, "bbox": [2011.84, 380.82, 279.52, 48.71], "category_id": 2}, {"id": 14, "bbox": [849.84, 427.55, 325.9, 137.83], "category_id": 2}, {"id": 15, "bbox": [1017.0, 227.84, 188.23, 57.66], "category_id": 2}, {"id": 16, "bbox": [1224.9, 0.0, 293.58, 188.46], "category_id": 1}, {"id": 17, "bbox": [1310.59, 194.08, 110.97, 60.48], "category_id": 3}, {"id": 18, "bbox": [1569.05, 232.06, 160.14, 53.44], "category_id": 2}], "caption": "Scheme 2. Biocatalysed reduction of (E)- and (Z)-1 mediated by BY and OYE1 3", "pdf": {"Page": 3, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [71, 276, 529, 291], "ImageBB": [71, 301, 773, 475]}, "reactions": [{"reactants": [16, 15], "conditions": [9], "products": [6, 5]}, {"reactants": [16, 18], "conditions": [0], "products": [4, 7]}, {"reactants": [12, 5], "conditions": [14], "products": [10, 15]}, {"reactants": [12, 4], "conditions": [2], "products": [18, 13]}, {"reactants": [13], "conditions": [1], "products": [3]}], "diagram_type": "graph"}, {"id": 601, "width": 2816, "height": 708, "file_name": "acs.oprd.6b00011-Table-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1545.6, 169.1, 522.4, 393.9], "category_id": 1}, {"id": 1, "bbox": [1184.0, 404.0, 195.6, 68.3], "category_id": 2}, {"id": 2, "bbox": [1126.75, 314.0, 329.0, 70.0], "category_id": 2}, {"id": 3, "bbox": [1090.1, 0.0, 394.5, 258.5], "category_id": 1}, {"id": 4, "bbox": [1.0, 619.0, 2815.0, 89.0], "category_id": 4}, {"id": 5, "bbox": [1622.0, 569.0, 295.0, 44.0], "category_id": 3}, {"id": 6, "bbox": [1270.0, 278.0, 34.0, 35.0], "category_id": 3}, {"id": 7, "bbox": [935.0, 551.0, 63.0, 67.0], "category_id": 3}, {"id": 8, "bbox": [744.0, 188.2, 355.4, 346.6], "category_id": 1}], "reactions": [{"reactants": [8], "conditions": [3, 2, 1], "products": [0]}], "corefs": [[8, 7], [3, 6], [0, 5]], "caption": "Table 4. Pd Catalyst Screen for the Stage 2 Suzuki Cross-Coupling Reaction", "pdf": {"Page": 6, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 513, 110], "ImageBB": [82, 116, 786, 293]}, "diagram_type": "single"}, {"id": 1130, "width": 1176, "height": 1240, "file_name": "jo991681n-Scheme-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [490.12, 262.39, 58.94, 50.25], "category_id": 3}, {"id": 1, "bbox": [327.8, 995.6, 818.71, 244.4], "category_id": 3}, {"id": 2, "bbox": [0.0, 91.81, 312.07, 74.43], "category_id": 1}, {"id": 3, "bbox": [389.0, 729.48, 455.38, 236.96], "category_id": 1}, {"id": 4, "bbox": [389.0, 658.77, 65.14, 51.49], "category_id": 3}, {"id": 5, "bbox": [671.28, 155.08, 111.05, 52.1], "category_id": 2}, {"id": 6, "bbox": [837.55, 251.23, 322.61, 50.24], "category_id": 3}, {"id": 7, "bbox": [711.61, 84.36, 39.7, 45.28], "category_id": 2}, {"id": 8, "bbox": [389.0, 14.89, 280.42, 233.85], "category_id": 1}, {"id": 9, "bbox": [210.94, 401.96, 408.23, 235.72], "category_id": 1}, {"id": 10, "bbox": [608.62, 471.44, 86.24, 47.76], "category_id": 2}, {"id": 11, "bbox": [44.67, 544.63, 114.15, 54.59], "category_id": 2}, {"id": 12, "bbox": [348.67, 91.81, 41.57, 39.08], "category_id": 2}, {"id": 13, "bbox": [302.14, 156.94, 114.77, 59.55], "category_id": 2}, {"id": 14, "bbox": [951.71, 673.66, 55.83, 48.38], "category_id": 3}, {"id": 15, "bbox": [806.53, 3.72, 342.47, 230.14], "category_id": 1}, {"id": 16, "bbox": [671.28, 346.75, 504.72, 321.94], "category_id": 1}, {"id": 17, "bbox": [201.01, 887.66, 117.26, 55.83], "category_id": 2}, {"id": 18, "bbox": [244.44, 811.37, 33.5, 46.52], "category_id": 2}, {"id": 19, "bbox": [105.47, 204.7, 55.84, 50.25], "category_id": 3}, {"id": 20, "bbox": [85.62, 477.02, 39.08, 39.08], "category_id": 2}], "caption": "Scheme 3a", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [207, 63, 276, 77], "ImageBB": [96, 84, 390, 394]}, "reactions": [{"reactants": [2], "conditions": [12, 13], "products": [8]}, {"reactants": [8], "conditions": [7, 5], "products": [15]}, {"reactants": [15], "conditions": [20, 11], "products": [9]}, {"reactants": [9], "conditions": [10], "products": [16]}, {"reactants": [16], "conditions": [18, 17], "products": [3]}], "diagram_type": "multiple"}, {"id": 161, "width": 1356, "height": 208, "file_name": "op700060e-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [305.0, 25.0, 79.0, 45.0], "category_id": 2}, {"id": 1, "bbox": [542.0, 6.0, 334.0, 145.3], "category_id": 1}, {"id": 2, "bbox": [1162.2, 4.0, 190.8, 152.7], "category_id": 1}, {"id": 3, "bbox": [295.0, 80.0, 98.0, 46.0], "category_id": 2}, {"id": 4, "bbox": [645.0, 132.0, 43.0, 44.0], "category_id": 3}, {"id": 5, "bbox": [922.0, 161.0, 118.0, 45.0], "category_id": 2}, {"id": 6, "bbox": [916.0, 0.0, 196.0, 45.0], "category_id": 2}, {"id": 7, "bbox": [3.0, 0.0, 195.0, 151.0], "category_id": 1}, {"id": 8, "bbox": [923.0, 116.0, 225.0, 47.0], "category_id": 2}], "reactions": [{"reactants": [7], "conditions": [0, 3], "products": [1]}], "corefs": [[1, 4]], "caption": "Figure 1. Approaches to 2-benzenethiopyridine, 2.", "pdf": {"Page": 1, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [425, 311, 702, 325], "ImageBB": [424, 256, 763, 308]}, "diagram_type": "single"}, {"id": 776, "width": 1348, "height": 800, "file_name": "jo951899j-Table-c5.png", "license": 0, "bboxes": [{"id": 0, "bbox": [156.0, 97.7, 377.0, 311.3], "category_id": 1}, {"id": 1, "bbox": [851.4, 94.2, 345.3, 308.8], "category_id": 1}, {"id": 2, "bbox": [360.07, 455.15, 87.0, 38.0], "category_id": 3}, {"id": 3, "bbox": [578.0, 129.86, 242.0, 133.5], "category_id": 2}, {"id": 4, "bbox": [180.0, 10.0, 989.0, 47.0], "category_id": 2}, {"id": 5, "bbox": [92.0, 564.0, 1155.0, 236.0], "category_id": 4}, {"id": 6, "bbox": [1061.0, 454.0, 108.0, 45.0], "category_id": 3}, {"id": 7, "bbox": [585.0, 311.0, 155.0, 47.0], "category_id": 2}], "reactions": [{"reactants": [0], "conditions": [3, 7], "products": [1]}], "corefs": [[0, 2], [1, 6]], "caption": "Table 5. Removal of the MEE Ester Protecting Group", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [438, 55, 755, 67], "ImageBB": [429, 66, 766, 266]}, "diagram_type": "single"}, {"id": 256, "width": 1348, "height": 1584, "file_name": "ol802073q-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [313.1, 47.3, 368.9, 110.7], "category_id": 1}, {"id": 1, "bbox": [1039.0, 170.0, 39.0, 46.0], "category_id": 3}, {"id": 2, "bbox": [882.0, 41.0, 102.0, 55.0], "category_id": 2}, {"id": 3, "bbox": [769.0, 75.0, 64.0, 56.0], "category_id": 2}, {"id": 4, "bbox": [435.0, 166.0, 46.0, 51.0], "category_id": 3}, {"id": 5, "bbox": [1.0, 220.0, 1347.0, 1364.0], "category_id": 4}, {"id": 6, "bbox": [902.0, 118.0, 47.0, 45.0], "category_id": 2}, {"id": 7, "bbox": [67.0, 32.0, 162.0, 146.0], "category_id": 1}, {"id": 8, "bbox": [1035.0, 1.0, 243.0, 210.0], "category_id": 1}, {"id": 9, "bbox": [117.0, 167.0, 39.0, 48.0], "category_id": 3}], "reactions": [{"reactants": [7, 0, 3], "conditions": [2, 6], "products": [8]}], "corefs": [[7, 9], [0, 4], [8, 1]], "caption": "Table 2. Reactions of Carbonyl Compounds with Indium and 1-Bromopent-4-en-2-ynea ", "pdf": {"Page": 3, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [425, 75, 743, 102], "ImageBB": [425, 111, 762, 507]}, "diagram_type": "single"}, {"id": 1098, "width": 1152, "height": 608, "file_name": "jo961365y-Scheme-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [674.83, 550.56, 108.35, 54.14], "category_id": 3}, {"id": 1, "bbox": [5.19, 437.69, 102.0, 56.43], "category_id": 3}, {"id": 2, "bbox": [214.96, 416.38, 306.0, 48.95], "category_id": 2}, {"id": 3, "bbox": [182.11, 143.98, 414.92, 51.83], "category_id": 2}, {"id": 4, "bbox": [710.56, 3.46, 427.61, 205.02], "category_id": 1}, {"id": 5, "bbox": [182.11, 73.14, 404.55, 65.08], "category_id": 2}, {"id": 6, "bbox": [0.0, 0.0, 2.31, 3.46], "category_id": 3}, {"id": 7, "bbox": [0.0, 0.0, 2.31, 7.49], "category_id": 3}, {"id": 8, "bbox": [269.13, 478.0, 189.6, 48.95], "category_id": 2}, {"id": 9, "bbox": [874.23, 347.84, 274.31, 99.06], "category_id": 2}, {"id": 10, "bbox": [905.35, 207.9, 110.07, 51.83], "category_id": 3}, {"id": 11, "bbox": [0.0, 0.0, 2.31, 7.49], "category_id": 3}, {"id": 12, "bbox": [566.49, 320.2, 294.48, 232.67], "category_id": 1}, {"id": 13, "bbox": [3.46, 113.45, 112.37, 57.02], "category_id": 3}], "caption": "Scheme 3", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [206, 49, 269, 63], "ImageBB": [97, 69, 385, 221]}, "reactions": [{"reactants": [13], "conditions": [5, 3], "products": [4]}, {"reactants": [4], "conditions": [9], "products": [12]}, {"reactants": [12], "conditions": [2, 8], "products": [1]}], "diagram_type": "tree"}, {"id": 940, "width": 1356, "height": 1492, "file_name": "acs.orglett.5b01692-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [384.19, 1237.65, 293.74, 46.57], "category_id": 2}, {"id": 1, "bbox": [702.62, 811.31, 92.59, 44.03], "category_id": 2}, {"id": 2, "bbox": [16.43, 1192.7, 333.01, 188.84], "category_id": 1}, {"id": 3, "bbox": [53.76, 1391.99, 215.04, 39.55], "category_id": 2}, {"id": 4, "bbox": [1072.23, 1115.08, 188.91, 44.78], "category_id": 2}, {"id": 5, "bbox": [1027.43, 276.16, 266.56, 247.79], "category_id": 1}, {"id": 6, "bbox": [817.61, 11.94, 123.95, 164.95], "category_id": 1}, {"id": 7, "bbox": [16.43, 659.79, 344.96, 50.76], "category_id": 2}, {"id": 8, "bbox": [1050.7, 529.18, 191.77, 41.8], "category_id": 2}, {"id": 9, "bbox": [487.58, 525.45, 435.31, 48.51], "category_id": 2}, {"id": 10, "bbox": [369.61, 765.78, 182.49, 254.72], "category_id": 1}, {"id": 11, "bbox": [516.7, 325.42, 380.06, 178.38], "category_id": 1}, {"id": 12, "bbox": [487.58, 29.11, 220.27, 115.69], "category_id": 1}, {"id": 13, "bbox": [155.31, 1100.15, 91.09, 45.53], "category_id": 2}, {"id": 14, "bbox": [992.33, 744.13, 246.41, 258.25], "category_id": 1}, {"id": 15, "bbox": [53.76, 338.85, 342.73, 170.92], "category_id": 1}, {"id": 16, "bbox": [0.0, 524.7, 450.99, 49.26], "category_id": 2}, {"id": 17, "bbox": [685.45, 882.96, 132.16, 43.29], "category_id": 2}, {"id": 18, "bbox": [935.59, 1194.94, 330.77, 204.51], "category_id": 1}, {"id": 19, "bbox": [1025.19, 1406.91, 126.93, 40.31], "category_id": 2}, {"id": 20, "bbox": [607.8, 222.42, 90.34, 46.27], "category_id": 2}, {"id": 21, "bbox": [278.51, 47.02, 90.35, 50.01], "category_id": 2}, {"id": 22, "bbox": [1036.15, 37.61, 238.22, 48.36], "category_id": 2}, {"id": 23, "bbox": [1208.1, 161.19, 82.39, 48.36], "category_id": 2}, {"id": 24, "bbox": [1134.67, 143.28, 51.94, 73.44], "category_id": 2}, {"id": 25, "bbox": [34.92, 814.95, 207.77, 111.05], "category_id": 1}, {"id": 26, "bbox": [642.11, 1022.72, 297.32, 42.99], "category_id": 2}], "caption": "Scheme 1. Strategies for NHC-Catalyzed Reactions of Enals with Nitroalkenes ", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 462, 780, 492], "ImageBB": [448, 498, 787, 871]}, "reactions": [{"reactants": [12, 6], "conditions": [21], "products": [15]}, {"reactants": [12, 6], "conditions": [20], "products": [11]}, {"reactants": [12, 6], "conditions": [22, 23, 24], "products": [5]}, {"reactants": [25, 10], "conditions": [1, 17], "products": [14]}, {"reactants": [25], "conditions": [13], "products": [2]}, {"reactants": [2], "conditions": [0], "products": [18]}, {"reactants": [18], "conditions": [4], "products": [14]}], "diagram_type": "graph"}, {"id": 88, "width": 1348, "height": 800, "file_name": "ja0547477-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [471.74, 6.1, 706.46, 280.6], "category_id": 1}, {"id": 1, "bbox": [738.09, 275.54, 44.69, 32.5], "category_id": 3}, {"id": 2, "bbox": [171.85, 126.1, 42.66, 33.51], "category_id": 3}, {"id": 3, "bbox": [7.16, 375.17, 1335.74, 414.73], "category_id": 4}, {"id": 4, "bbox": [272.49, 101.7, 177.87, 34.53], "category_id": 2}], "reactions": [{"reactants": [2], "conditions": [4], "products": [0]}], "corefs": [[0, 1]], "caption": "Table 1. Conditions for the Cyclization of Sulfoxide 15 to Tetracycle 42 ", "pdf": {"Page": 5, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 64, 727, 88], "ImageBB": [439, 88, 776, 288]}, "diagram_type": "single"}, {"id": 542, "width": 1348, "height": 380, "file_name": "acs.orglett.6b00233-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [358.0, 239.0, 74.0, 45.0], "category_id": 3}, {"id": 1, "bbox": [1077.1, 213.0, 73.9, 50.0], "category_id": 3}, {"id": 2, "bbox": [912.2, 13.1, 398.7, 223.9], "category_id": 1}, {"id": 3, "bbox": [576.1, 173.2, 204.4, 52.5], "category_id": 2}, {"id": 4, "bbox": [518.3, 66.1, 343.7, 64.9], "category_id": 2}, {"id": 5, "bbox": [36.1, 4.0, 399.7, 230.0], "category_id": 1}], "reactions": [{"reactants": [5], "conditions": [4, 3], "products": [2]}], "corefs": [[5, 0], [2, 1]], "caption": "Table 1. Study of Reaction Conditionsa", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 506, 302, 527], "ImageBB": [82, 533, 419, 628]}, "diagram_type": "single"}, {"id": 1236, "width": 1352, "height": 1200, "file_name": "op020211j-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [488.99, 591.19, 513.34, 608.77], "category_id": 1}, {"id": 1, "bbox": [29.08, 710.24, 458.56, 62.23], "category_id": 2}, {"id": 2, "bbox": [28.8, 831.99, 298.55, 67.64], "category_id": 2}, {"id": 3, "bbox": [0.0, 280.04, 409.86, 215.1], "category_id": 1}, {"id": 4, "bbox": [411.21, 401.79, 485.61, 56.14], "category_id": 2}, {"id": 5, "bbox": [384.16, 0.0, 386.87, 58.85], "category_id": 2}, {"id": 6, "bbox": [411.21, 304.39, 493.73, 63.58], "category_id": 2}, {"id": 7, "bbox": [789.96, 12.85, 545.81, 127.17], "category_id": 1}, {"id": 8, "bbox": [879.24, 932.1, 110.92, 58.17], "category_id": 2}, {"id": 9, "bbox": [942.82, 292.21, 409.18, 340.24], "category_id": 1}, {"id": 10, "bbox": [177.2, 175.87, 41.26, 47.35], "category_id": 3}, {"id": 11, "bbox": [912.38, 179.25, 51.4, 50.73], "category_id": 3}, {"id": 12, "bbox": [200.2, 540.46, 45.99, 50.73], "category_id": 3}, {"id": 13, "bbox": [0.0, 10.15, 336.14, 125.81], "category_id": 1}, {"id": 14, "bbox": [384.16, 107.55, 282.71, 58.17], "category_id": 2}, {"id": 15, "bbox": [570.15, 1095.79, 215.75, 57.5], "category_id": 2}, {"id": 16, "bbox": [507.25, 180.6, 97.4, 49.38], "category_id": 2}, {"id": 17, "bbox": [588.12, 482.52, 84.99, 46.1], "category_id": 2}, {"id": 18, "bbox": [150.18, 913.25, 93.64, 54.89], "category_id": 2}, {"id": 19, "bbox": [1025.33, 540.46, 42.61, 50.73], "category_id": 3}], "caption": "Scheme 1", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 53, 135, 67], "ImageBB": [74, 72, 412, 372]}, "reactions": [{"reactants": [13], "conditions": [5, 14, 16], "products": [7]}, {"reactants": [3], "conditions": [6, 2, 17], "products": [9]}, {"reactants": [9], "conditions": [1, 2, 18], "products": [0, 8]}], "diagram_type": "multiple"}, {"id": 705, "width": 2816, "height": 2984, "file_name": "ol035681s-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [810.0, 164.0, 329.0, 131.0], "category_id": 3}, {"id": 1, "bbox": [1158.0, 14.0, 517.0, 110.0], "category_id": 2}, {"id": 2, "bbox": [1900.0, 176.0, 36.0, 46.0], "category_id": 3}, {"id": 3, "bbox": [1168.0, 153.0, 449.0, 61.0], "category_id": 2}, {"id": 4, "bbox": [19.0, 327.0, 1320.0, 2487.0], "category_id": 4}, {"id": 5, "bbox": [1464.0, 327.0, 1352.0, 2482.0], "category_id": 4}, {"id": 6, "bbox": [8.0, 2814.0, 2808.0, 170.0], "category_id": 2}, {"id": 7, "bbox": [850.0, 5.0, 249.0, 162.0], "category_id": 1}, {"id": 8, "bbox": [1765.0, 8.0, 251.0, 200.0], "category_id": 1}], "reactions": [{"reactants": [7], "conditions": [1, 3], "products": [8]}], "corefs": [[7, 0], [8, 2]], "caption": "Table 1. Cu(II)-Catalyzed N-Phenylation of Aliphatic Amines, Ammonium Salts, and Anilinesa", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 75, 573, 89], "ImageBB": [73, 96, 777, 842]}, "diagram_type": "single"}, {"id": 736, "width": 1348, "height": 2104, "file_name": "ol015948s-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [6.0, 324.0, 1336.0, 1780.0], "category_id": 4}, {"id": 1, "bbox": [1034.0, 5.0, 286.0, 287.0], "category_id": 1}, {"id": 2, "bbox": [690.0, 185.0, 266.0, 49.0], "category_id": 2}, {"id": 3, "bbox": [637.0, 108.0, 362.0, 53.0], "category_id": 2}, {"id": 4, "bbox": [662.0, 58.0, 312.0, 53.0], "category_id": 2}, {"id": 5, "bbox": [308.0, 30.0, 286.0, 232.0], "category_id": 1}, {"id": 6, "bbox": [52.0, 75.0, 179.0, 137.0], "category_id": 1}], "reactions": [{"reactants": [6, 5], "conditions": [4, 3, 2], "products": [1]}], "corefs": [], "caption": "Table 2. Direct Reductive Aminations of Carbonyl Compounds with Anilines ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 76, 711, 104], "ImageBB": [440, 107, 777, 633]}, "diagram_type": "single"}, {"id": 199, "width": 1348, "height": 884, "file_name": "op049899l-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [8.0, 8.0, 1333.0, 442.0], "category_id": 4}, {"id": 1, "bbox": [1053.0, 841.0, 48.0, 37.0], "category_id": 3}, {"id": 2, "bbox": [327.0, 818.0, 47.0, 35.0], "category_id": 3}, {"id": 3, "bbox": [832.0, 597.0, 410.0, 210.0], "category_id": 1}, {"id": 4, "bbox": [643.0, 576.0, 153.0, 128.0], "category_id": 1}, {"id": 5, "bbox": [111.0, 590.0, 428.0, 204.0], "category_id": 1}, {"id": 6, "bbox": [649.0, 734.0, 91.0, 41.0], "category_id": 2}], "reactions": [{"reactants": [5], "conditions": [4, 6], "products": [3]}], "corefs": [[5, 2], [3, 1]], "caption": "Table 1. DOE results for alkylation of 6 to give 17 (% yield)", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 53, 773, 67], "ImageBB": [439, 70, 776, 291]}, "diagram_type": "single"}, {"id": 779, "width": 1348, "height": 804, "file_name": "jo951899j-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [20.0, 318.0, 184.7, 73.5], "category_id": 3}, {"id": 1, "bbox": [446.0, 313.0, 199.9, 81.1], "category_id": 3}, {"id": 2, "bbox": [841.77, 134.77, 122.0, 78.0], "category_id": 2}, {"id": 3, "bbox": [844.0, 71.2, 134.1, 43.1], "category_id": 2}, {"id": 4, "bbox": [1016.6, 0.0, 327.4, 176.8], "category_id": 1}, {"id": 5, "bbox": [482.0, 5.8, 328.0, 169.0], "category_id": 1}, {"id": 6, "bbox": [0.0, 8.0, 289.4, 167.1], "category_id": 1}, {"id": 7, "bbox": [521.22, 224.84, 76.38, 43.06], "category_id": 2}, {"id": 8, "bbox": [323.0, 82.0, 130.0, 35.0], "category_id": 2}, {"id": 9, "bbox": [7.0, 406.0, 1341.0, 398.0], "category_id": 4}, {"id": 10, "bbox": [128.0, 207.0, 81.0, 47.0], "category_id": 3}, {"id": 11, "bbox": [665.0, 209.0, 79.0, 42.0], "category_id": 3}, {"id": 12, "bbox": [1150.0, 212.0, 73.0, 44.0], "category_id": 3}, {"id": 13, "bbox": [312.0, 183.0, 144.0, 96.0], "category_id": 2}], "reactions": [{"reactants": [6], "conditions": [8, 13], "products": [5]}, {"reactants": [5], "conditions": [3, 2], "products": [4]}], "corefs": [[6, 10], [5, 11], [4, 12], [6, 0], [5, 1]], "caption": "Table 1. Synthesis of N-Protected Serine and Threonine                       MEE Esters ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [430, 370, 763, 395], "ImageBB": [429, 404, 766, 605]}, "diagram_type": "single"}, {"id": 189, "width": 824, "height": 128, "file_name": "op060155c-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [613.0, 6.0, 211.0, 122.0], "category_id": 1}, {"id": 1, "bbox": [2.0, 1.0, 222.0, 124.0], "category_id": 1}, {"id": 2, "bbox": [317.0, 0.0, 214.0, 123.0], "category_id": 1}], "reactions": [{"reactants": [1], "conditions": [], "products": [2]}, {"reactants": [2], "conditions": [], "products": [0]}], "corefs": [], "caption": "Figure 1. MeTHF production process.", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 88, 290, 102], "ImageBB": [139, 53, 345, 85]}, "diagram_type": "single"}, {"id": 1370, "width": 2748, "height": 1800, "file_name": "op970113b-Scheme-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1231.72, 0.0, 395.38, 395.98], "category_id": 1}, {"id": 1, "bbox": [2015.7, 1311.67, 618.6, 488.33], "category_id": 4}, {"id": 2, "bbox": [771.2, 562.34, 177.33, 77.0], "category_id": 2}, {"id": 3, "bbox": [1360.94, 1057.31, 549.88, 247.48], "category_id": 1}, {"id": 4, "bbox": [1164.36, 439.97, 171.84, 71.5], "category_id": 2}, {"id": 5, "bbox": [0.0, 455.1, 640.6, 329.98], "category_id": 1}, {"id": 6, "bbox": [2101.9, 59.12, 551.25, 269.48], "category_id": 1}, {"id": 7, "bbox": [1234.47, 661.33, 570.49, 298.67], "category_id": 1}, {"id": 8, "bbox": [2199.5, 874.45, 548.5, 269.48], "category_id": 1}, {"id": 9, "bbox": [970.53, 793.33, 180.08, 74.24], "category_id": 2}, {"id": 10, "bbox": [2099.15, 367.1, 591.11, 266.74], "category_id": 4}], "caption": "Scheme 3. Reaction pathways which can lead to relocation of the benzoyl moiety", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [73, 49, 521, 63], "ImageBB": [82, 68, 769, 518]}, "reactions": [{"reactants": [5], "conditions": [2], "products": [0]}, {"reactants": [0], "conditions": [], "products": [6]}, {"reactants": [5], "conditions": [2], "products": [3]}, {"reactants": [3, 7], "conditions": [], "products": [8]}], "diagram_type": "tree"}, {"id": 690, "width": 1348, "height": 600, "file_name": "ol401042b-Table-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [90.77, 288.56, 194.63, 45.84], "category_id": 2}, {"id": 1, "bbox": [757.61, 164.39, 153.99, 54.01], "category_id": 2}, {"id": 2, "bbox": [1119.58, 242.83, 81.0, 43.0], "category_id": 3}, {"id": 3, "bbox": [26.3, 56.7, 323.2, 181.3], "category_id": 1}, {"id": 4, "bbox": [510.0, 242.28, 127.5, 43.3], "category_id": 2}, {"id": 5, "bbox": [472.7, 105.1, 201.8, 114.8], "category_id": 1}, {"id": 6, "bbox": [1000.91, 6.03, 324.09, 240.67], "category_id": 1}, {"id": 7, "bbox": [144.58, 239.72, 80.0, 47.0], "category_id": 3}, {"id": 8, "bbox": [709.0, 80.0, 278.0, 59.0], "category_id": 2}, {"id": 9, "bbox": [7.0, 376.0, 1341.0, 224.0], "category_id": 4}], "reactions": [{"reactants": [3, 5], "conditions": [8, 1], "products": [6]}], "corefs": [[3, 7], [6, 2]], "caption": "Table 4. Scope of Substrate for Organocatalytic Annulationa", "pdf": {"Page": 3, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 533, 760, 549], "ImageBB": [436, 559, 773, 709]}, "diagram_type": "single"}, {"id": 441, "width": 2820, "height": 784, "file_name": "op200312m-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1532.0, 304.0, 40.0, 42.0], "category_id": 3}, {"id": 1, "bbox": [2.0, 358.0, 2816.0, 426.0], "category_id": 4}, {"id": 2, "bbox": [1202.0, 163.0, 81.0, 50.0], "category_id": 2}, {"id": 3, "bbox": [734.5, 0.0, 414.5, 295.0], "category_id": 1}, {"id": 4, "bbox": [1364.5, 58.1, 397.4, 194.9], "category_id": 1}, {"id": 5, "bbox": [2033.08, 138.83, 55.29, 53.17], "category_id": 3}, {"id": 6, "bbox": [1931.0, 138.83, 51.04, 53.17], "category_id": 3}, {"id": 7, "bbox": [903.0, 305.0, 39.5, 43.0], "category_id": 3}, {"id": 8, "bbox": [1825.5, 140.0, 55.6, 52.7], "category_id": 3}, {"id": 9, "bbox": [1168.6, 8.0, 158.1, 143.0], "category_id": 2}], "reactions": [{"reactants": [3], "conditions": [9, 2], "products": [4, 8, 6, 5]}], "corefs": [[3, 7], [4, 0]], "caption": "Table 3. Levels of the five factors in the 25\u20111 fractional factorial design", "pdf": {"Page": 4, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 92, 479, 109], "ImageBB": [82, 116, 787, 312]}, "diagram_type": "single"}, {"id": 319, "width": 1196, "height": 2264, "file_name": "ol3023177-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [774.5, 0.0, 270.4, 161.2], "category_id": 1}, {"id": 1, "bbox": [155.0, 39.0, 241.0, 107.0], "category_id": 1}, {"id": 2, "bbox": [891.0, 147.0, 43.0, 47.0], "category_id": 3}, {"id": 3, "bbox": [536.0, 146.0, 47.0, 49.0], "category_id": 3}, {"id": 4, "bbox": [15.0, 249.0, 1181.0, 2015.0], "category_id": 4}, {"id": 5, "bbox": [267.0, 147.0, 39.0, 48.0], "category_id": 3}, {"id": 6, "bbox": [482.0, 44.0, 169.0, 110.0], "category_id": 1}], "reactions": [{"reactants": [1, 6], "conditions": [], "products": [0]}], "corefs": [[1, 5], [6, 3], [0, 2]], "caption": "Table 2. Scope of H-Bonding Directed Hydroaminationa", "pdf": {"Page": 3, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 85, 740, 101], "ImageBB": [455, 112, 754, 678]}, "diagram_type": "single"}, {"id": 1349, "width": 1348, "height": 440, "file_name": "op700253t-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [0.0, 178.74, 186.79, 37.77], "category_id": 3}, {"id": 1, "bbox": [179.37, 109.94, 154.43, 68.8], "category_id": 2}, {"id": 2, "bbox": [192.86, 259.68, 140.26, 44.52], "category_id": 2}, {"id": 3, "bbox": [872.59, 250.91, 132.85, 109.27], "category_id": 1}, {"id": 4, "bbox": [722.89, 109.27, 93.73, 70.82], "category_id": 2}, {"id": 5, "bbox": [564.42, 250.91, 129.47, 109.27], "category_id": 1}, {"id": 6, "bbox": [839.55, 0.0, 209.04, 151.09], "category_id": 1}, {"id": 7, "bbox": [179.37, 51.26, 138.92, 40.47], "category_id": 2}, {"id": 8, "bbox": [726.94, 259.68, 95.75, 44.52], "category_id": 2}, {"id": 9, "bbox": [366.84, 251.59, 125.43, 108.59], "category_id": 1}, {"id": 10, "bbox": [1021.62, 317.01, 118.68, 44.52], "category_id": 2}, {"id": 11, "bbox": [1150.42, 0.0, 197.58, 151.09], "category_id": 1}, {"id": 12, "bbox": [1192.23, 249.56, 119.36, 110.62], "category_id": 1}, {"id": 13, "bbox": [335.82, 0.0, 194.21, 151.09], "category_id": 1}, {"id": 14, "bbox": [24.95, 0.0, 195.56, 151.09], "category_id": 1}, {"id": 15, "bbox": [192.86, 319.71, 159.14, 69.48], "category_id": 2}, {"id": 16, "bbox": [1026.34, 248.89, 96.43, 47.89], "category_id": 2}, {"id": 17, "bbox": [1007.46, 105.22, 119.36, 45.87], "category_id": 2}, {"id": 18, "bbox": [720.87, 48.56, 90.36, 45.87], "category_id": 2}, {"id": 19, "bbox": [64.74, 252.26, 117.33, 107.92], "category_id": 1}, {"id": 20, "bbox": [1020.27, 42.49, 82.95, 42.5], "category_id": 2}, {"id": 21, "bbox": [730.31, 319.71, 101.82, 68.8], "category_id": 2}, {"id": 22, "bbox": [0.0, 397.95, 204.32, 39.8], "category_id": 3}, {"id": 23, "bbox": [533.4, 0.0, 203.6, 151.09], "category_id": 1}], "caption": "Scheme 1. Preparation of chiral secondary alcohols by chemoenzymatic deracemization ", "pdf": {"Page": 2, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 46, 363, 73], "ImageBB": [58, 79, 395, 189]}, "reactions": [{"reactants": [14], "conditions": [7, 1], "products": [13, 23]}, {"reactants": [13, 23], "conditions": [18, 4], "products": [6]}, {"reactants": [6], "conditions": [20, 17], "products": [11]}, {"reactants": [19], "conditions": [2, 15], "products": [9, 5]}, {"reactants": [9, 5], "conditions": [8, 21], "products": [3]}, {"reactants": [3], "conditions": [16, 10], "products": [12]}], "diagram_type": "multiple"}, {"id": 697, "width": 1352, "height": 1152, "file_name": "ol0480731-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1036.0, 68.0, 248.6, 202.0], "category_id": 1}, {"id": 1, "bbox": [597.7, 75.0, 158.0, 133.0], "category_id": 1}, {"id": 2, "bbox": [809.0, 92.0, 136.0, 55.0], "category_id": 2}, {"id": 3, "bbox": [58.0, 0.0, 445.0, 302.0], "category_id": 1}, {"id": 4, "bbox": [96.0, 254.0, 135.0, 48.0], "category_id": 3}, {"id": 5, "bbox": [12.0, 431.0, 1331.0, 667.0], "category_id": 4}, {"id": 6, "bbox": [791.0, 160.0, 188.0, 51.0], "category_id": 2}, {"id": 7, "bbox": [181.0, 302.0, 184.0, 59.0], "category_id": 2}], "reactions": [{"reactants": [3, 1], "conditions": [2, 6], "products": [0]}], "corefs": [[3, 4]], "caption": "Table 1. Syn-Selective Aldehyde Crotylation with (R,R)-2", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 547, 380, 560], "ImageBB": [73, 561, 411, 849]}, "diagram_type": "single"}, {"id": 866, "width": 1356, "height": 908, "file_name": "jo2001534-Table-c5.png", "license": 0, "bboxes": [{"id": 0, "bbox": [356.0, 133.0, 99.0, 33.0], "category_id": 2}, {"id": 1, "bbox": [1014.0, 7.0, 337.0, 333.0], "category_id": 1}, {"id": 2, "bbox": [491.0, 21.0, 335.0, 301.0], "category_id": 1}, {"id": 3, "bbox": [1.0, 25.0, 339.0, 293.0], "category_id": 1}, {"id": 4, "bbox": [0.0, 440.0, 1356.0, 468.0], "category_id": 4}, {"id": 5, "bbox": [1141.0, 341.0, 86.0, 38.0], "category_id": 3}, {"id": 6, "bbox": [614.0, 340.0, 71.0, 38.0], "category_id": 3}, {"id": 7, "bbox": [135.0, 343.0, 71.0, 34.0], "category_id": 3}, {"id": 8, "bbox": [845.0, 133.0, 133.0, 34.0], "category_id": 2}], "reactions": [{"reactants": [3], "conditions": [0], "products": [2]}, {"reactants": [2], "conditions": [8], "products": [1]}], "corefs": [[3, 7], [2, 6], [1, 5]], "caption": "Table 5. Yields and Substitution Patterns for Compounds 10a-e ", "pdf": {"Page": 6, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [71, 672, 392, 702], "ImageBB": [71, 709, 410, 936]}, "diagram_type": "single"}, {"id": 327, "width": 1344, "height": 1948, "file_name": "ol301114z-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [508.0, 345.0, 61.0, 51.0], "category_id": 3}, {"id": 1, "bbox": [398.0, 701.0, 141.0, 57.0], "category_id": 3}, {"id": 2, "bbox": [653.0, 600.0, 194.0, 44.0], "category_id": 2}, {"id": 3, "bbox": [7.0, 787.0, 1337.0, 1161.0], "category_id": 4}, {"id": 4, "bbox": [120.0, 695.0, 61.0, 57.0], "category_id": 3}, {"id": 5, "bbox": [1022.0, 699.0, 57.0, 57.0], "category_id": 3}, {"id": 6, "bbox": [1094.0, 320.0, 59.0, 67.0], "category_id": 3}, {"id": 7, "bbox": [820.0, 334.0, 59.0, 51.0], "category_id": 3}, {"id": 8, "bbox": [139.0, 345.0, 43.0, 46.0], "category_id": 3}, {"id": 9, "bbox": [750.6, 67.0, 213.4, 183.4], "category_id": 1}, {"id": 10, "bbox": [632.0, 471.0, 251.0, 90.7], "category_id": 2}, {"id": 11, "bbox": [1003.5, 426.6, 321.0, 331.3], "category_id": 1}, {"id": 12, "bbox": [399.1, 534.1, 160.4, 111.9], "category_id": 1}, {"id": 13, "bbox": [25.1, 477.0, 258.8, 195.5], "category_id": 1}, {"id": 14, "bbox": [1000.1, 54.6, 264.9, 186.8], "category_id": 1}, {"id": 15, "bbox": [25.5, 3.0, 312.5, 311.4], "category_id": 1}, {"id": 16, "bbox": [374.0, 3.0, 316.0, 310.0], "category_id": 1}], "reactions": [{"reactants": [13, 12], "conditions": [10, 2], "products": [11]}], "corefs": [[15, 8], [16, 0], [9, 7], [14, 6], [13, 4], [12, 1], [11, 5]], "caption": "Table 1. Optimization of the Reaction Conditions for the [4 \u00fe 2] Annulation ", "pdf": {"Page": 3, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [71, 85, 405, 115], "ImageBB": [71, 126, 407, 613]}, "diagram_type": "single"}, {"id": 13, "width": 1344, "height": 624, "file_name": "ja9810742-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [942.06, 132.75, 30.33, 37.18], "category_id": 3}, {"id": 1, "bbox": [251.18, 55.5, 111.86, 38.05], "category_id": 2}, {"id": 2, "bbox": [299.24, 135.32, 25.18, 37.19], "category_id": 3}, {"id": 3, "bbox": [594.48, 89.83, 169.35, 44.06], "category_id": 2}, {"id": 4, "bbox": [601.34, 4.87, 153.05, 43.19], "category_id": 2}, {"id": 5, "bbox": [839.93, 11.74, 251.75, 118.72], "category_id": 1}, {"id": 6, "bbox": [2.29, 207.41, 1338.31, 408.81], "category_id": 4}, {"id": 7, "bbox": [484.62, 51.21, 50.92, 38.91], "category_id": 3}], "reactions": [{"reactants": [1, 7], "conditions": [4, 3], "products": [5]}], "corefs": [[1, 2], [5, 0]], "caption": "Table 2. Allylation of Aldehydes 1 with 2,3-Dimethyl-4-penten-2-ol 2ba ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 262, 283, 287], "ImageBB": [74, 288, 410, 444]}, "diagram_type": "single"}, {"id": 570, "width": 1348, "height": 356, "file_name": "acs.orglett.5b01044-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [656.0, 24.0, 156.0, 77.0], "category_id": 2}, {"id": 1, "bbox": [8.0, 286.0, 1334.0, 66.0], "category_id": 4}, {"id": 2, "bbox": [654.0, 119.0, 162.0, 76.0], "category_id": 2}, {"id": 3, "bbox": [74.0, 0.0, 305.0, 210.0], "category_id": 1}, {"id": 4, "bbox": [508.0, 208.9, 50.0, 41.1], "category_id": 3}, {"id": 5, "bbox": [987.9, 211.0, 124.1, 43.0], "category_id": 3}, {"id": 6, "bbox": [433.2, 17.1, 206.8, 191.9], "category_id": 1}, {"id": 7, "bbox": [205.9, 208.9, 52.1, 40.1], "category_id": 3}, {"id": 8, "bbox": [837.9, 16.1, 434.7, 193.9], "category_id": 1}], "reactions": [{"reactants": [3, 6], "conditions": [0, 2], "products": [8]}], "corefs": [[3, 7], [6, 4], [8, 5]], "caption": "Table 1. Enantioselective Addition of o-tBu-Phenol to Ethyl(p-tolyl)ketene Catalyzed by (S)-1a ", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 90, 746, 125], "ImageBB": [449, 131, 786, 220]}, "diagram_type": "single"}, {"id": 1206, "width": 1348, "height": 792, "file_name": "ol800418m-Scheme-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [904.29, 12.14, 341.89, 233.38], "category_id": 1}, {"id": 1, "bbox": [662.87, 685.29, 56.65, 49.91], "category_id": 3}, {"id": 2, "bbox": [249.5, 682.59, 56.65, 49.92], "category_id": 3}, {"id": 3, "bbox": [1064.1, 679.89, 58.0, 49.24], "category_id": 3}, {"id": 4, "bbox": [103.85, 0.0, 339.19, 245.52], "category_id": 1}, {"id": 5, "bbox": [504.4, 435.73, 337.85, 244.84], "category_id": 1}, {"id": 6, "bbox": [487.55, 29.0, 327.72, 95.11], "category_id": 2}, {"id": 7, "bbox": [267.71, 257.66, 36.42, 44.52], "category_id": 3}, {"id": 8, "bbox": [103.85, 433.03, 338.52, 245.52], "category_id": 1}, {"id": 9, "bbox": [1061.41, 250.91, 37.76, 45.87], "category_id": 3}, {"id": 10, "bbox": [902.26, 430.33, 338.52, 240.12], "category_id": 1}], "caption": "Scheme 3. Attempted Ring-Closing Metathesis of Enyne 5", "pdf": {"Page": 2, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [440, 463, 744, 478], "ImageBB": [425, 485, 762, 683]}, "reactions": [{"reactants": [4], "conditions": [], "products": [8]}, {"reactants": [8], "conditions": [], "products": [5]}, {"reactants": [5], "conditions": [], "products": [10]}, {"reactants": [10], "conditions": [], "products": [0]}], "diagram_type": "graph"}, {"id": 919, "width": 1356, "height": 1248, "file_name": "acs.joc.5b02057-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [16.28, 330.31, 636.96, 48.83], "category_id": 2}, {"id": 1, "bbox": [663.07, 567.78, 43.44, 37.46], "category_id": 2}, {"id": 2, "bbox": [214.0, 1153.02, 75.65, 52.22], "category_id": 2}, {"id": 3, "bbox": [16.28, 692.49, 192.65, 49.51], "category_id": 2}, {"id": 4, "bbox": [276.1, 874.94, 90.88, 49.76], "category_id": 2}, {"id": 5, "bbox": [619.32, 250.95, 47.49, 47.48], "category_id": 2}, {"id": 6, "bbox": [0.0, 417.8, 259.13, 250.95], "category_id": 1}, {"id": 7, "bbox": [0.0, 80.03, 223.85, 235.35], "category_id": 1}, {"id": 8, "bbox": [717.0, 86.14, 163.48, 212.29], "category_id": 1}, {"id": 9, "bbox": [16.28, 0.0, 223.17, 47.48], "category_id": 2}, {"id": 10, "bbox": [408.36, 911.56, 246.92, 52.23], "category_id": 2}, {"id": 11, "bbox": [438.21, 785.41, 181.79, 124.12], "category_id": 1}, {"id": 12, "bbox": [205.54, 1094.01, 98.36, 46.8], "category_id": 2}, {"id": 13, "bbox": [1095.52, 425.26, 260.48, 193.3], "category_id": 1}, {"id": 14, "bbox": [1009.37, 487.66, 87.5, 45.44], "category_id": 2}, {"id": 15, "bbox": [14.92, 760.31, 213.68, 191.95], "category_id": 1}, {"id": 16, "bbox": [987.66, 97.67, 189.26, 212.97], "category_id": 1}, {"id": 17, "bbox": [335.78, 89.53, 241.49, 211.61], "category_id": 1}, {"id": 18, "bbox": [363.59, 419.83, 256.41, 218.4], "category_id": 1}, {"id": 19, "bbox": [704.79, 1077.73, 188.58, 114.63], "category_id": 1}, {"id": 20, "bbox": [743.46, 419.83, 259.13, 191.95], "category_id": 1}, {"id": 21, "bbox": [438.21, 1094.01, 175.01, 108.52], "category_id": 1}, {"id": 22, "bbox": [704.79, 798.97, 191.97, 118.02], "category_id": 1}], "caption": "Scheme 1. Gold-Catalyzed Reactions of Organic Azides with Alkynes ", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 535, 784, 565], "ImageBB": [448, 572, 787, 884]}, "reactions": [{"reactants": [7], "conditions": [], "products": [17]}, {"reactants": [17], "conditions": [], "products": [5, 8]}, {"reactants": [8], "conditions": [], "products": [16]}, {"reactants": [6], "conditions": [], "products": [18]}, {"reactants": [18], "conditions": [], "products": [1, 20]}, {"reactants": [20], "conditions": [14], "products": [13]}, {"reactants": [15], "conditions": [4], "products": [11, 22]}, {"reactants": [11], "conditions": [], "products": [21]}, {"reactants": [21, 19], "conditions": [12, 2], "products": [15]}], "diagram_type": "graph"}, {"id": 452, "width": 1344, "height": 1008, "file_name": "op2001047-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [11.0, 276.0, 1333.0, 732.0], "category_id": 4}, {"id": 1, "bbox": [1134.5, 185.0, 87.5, 61.2], "category_id": 3}, {"id": 2, "bbox": [503.05, 192.65, 47.0, 49.0], "category_id": 3}, {"id": 3, "bbox": [100.46, 193.3, 104.0, 45.0], "category_id": 3}, {"id": 4, "bbox": [1033.9, 6.0, 241.8, 124.7], "category_id": 1}, {"id": 5, "bbox": [63.1, 16.8, 159.7, 129.6], "category_id": 1}, {"id": 6, "bbox": [387.0, 3.9, 237.6, 115.0], "category_id": 1}, {"id": 7, "bbox": [789.0, 33.0, 95.0, 47.0], "category_id": 2}, {"id": 8, "bbox": [700.0, 103.0, 275.0, 59.0], "category_id": 2}], "reactions": [{"reactants": [5, 6], "conditions": [7, 8], "products": [4]}], "corefs": [[5, 3], [6, 2], [4, 1]], "caption": "Table 3. Comparison between microwave batch and contin- uous \ufb02ow conditions in the Wittig reaction of aldehydes 4a c with (acetylmethylene)triphenylphosphorane (5)a ", "pdf": {"Page": 4, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [437, 458, 771, 503], "ImageBB": [437, 513, 773, 765]}, "diagram_type": "single"}, {"id": 860, "width": 1356, "height": 464, "file_name": "jo200480h-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [46.0, 279.0, 47.0, 41.0], "category_id": 3}, {"id": 1, "bbox": [1088.0, 277.0, 39.0, 42.0], "category_id": 3}, {"id": 2, "bbox": [998.0, 2.0, 354.0, 296.0], "category_id": 1}, {"id": 3, "bbox": [651.0, 62.0, 331.0, 137.0], "category_id": 2}, {"id": 4, "bbox": [658.0, 210.0, 321.0, 50.0], "category_id": 2}, {"id": 5, "bbox": [10.0, 363.0, 1339.0, 98.0], "category_id": 4}, {"id": 6, "bbox": [2.0, 130.0, 243.0, 147.0], "category_id": 1}, {"id": 7, "bbox": [261.0, 139.0, 383.0, 122.0], "category_id": 1}, {"id": 8, "bbox": [430.0, 273.0, 51.0, 49.0], "category_id": 3}], "reactions": [{"reactants": [6, 7], "conditions": [3, 4], "products": [2]}], "corefs": [[6, 0], [7, 8], [2, 1]], "caption": "Table 1. Optimization of the Heteroannulation Reaction between 4-Acetamido-3-iodopyridine (1) and Diphenylace- tylene (2) ", "pdf": {"Page": 2, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [437, 92, 764, 137], "ImageBB": [436, 148, 775, 264]}, "diagram_type": "single"}, {"id": 1369, "width": 1300, "height": 1420, "file_name": "op970105v-Scheme-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [726.19, 659.92, 263.62, 58.25], "category_id": 2}, {"id": 1, "bbox": [699.9, 1231.05, 105.88, 56.11], "category_id": 2}, {"id": 2, "bbox": [88.11, 1212.58, 102.32, 60.38], "category_id": 2}, {"id": 3, "bbox": [930.12, 815.49, 160.59, 105.84], "category_id": 2}, {"id": 4, "bbox": [726.9, 294.09, 103.03, 53.98], "category_id": 2}, {"id": 5, "bbox": [412.12, 423.37, 49.74, 44.75], "category_id": 3}, {"id": 6, "bbox": [260.07, 493.7, 436.99, 384.3], "category_id": 1}, {"id": 7, "bbox": [68.92, 269.22, 100.19, 58.25], "category_id": 2}, {"id": 8, "bbox": [687.11, 1096.08, 161.3, 95.9], "category_id": 2}, {"id": 9, "bbox": [412.12, 1368.85, 54.72, 46.89], "category_id": 3}, {"id": 10, "bbox": [574.13, 441.84, 235.91, 104.42], "category_id": 2}, {"id": 11, "bbox": [1116.29, 703.25, 33.4, 47.6], "category_id": 3}, {"id": 12, "bbox": [971.34, 1365.3, 58.97, 50.44], "category_id": 3}, {"id": 13, "bbox": [867.59, 26.28, 432.41, 466.0], "category_id": 1}, {"id": 14, "bbox": [804.35, 546.26, 162.72, 60.38], "category_id": 2}, {"id": 15, "bbox": [258.64, 939.09, 424.21, 480.91], "category_id": 1}, {"id": 16, "bbox": [687.11, 156.28, 189.01, 102.29], "category_id": 2}, {"id": 17, "bbox": [0.0, 1162.14, 44.77, 53.28], "category_id": 3}, {"id": 18, "bbox": [0.0, 229.44, 40.5, 50.44], "category_id": 3}, {"id": 19, "bbox": [989.1, 426.92, 58.27, 53.99], "category_id": 3}, {"id": 20, "bbox": [243.01, 0.0, 430.6, 476.65], "category_id": 1}, {"id": 21, "bbox": [859.07, 954.01, 431.31, 465.99], "category_id": 1}, {"id": 22, "bbox": [64.66, 179.72, 147.09, 59.67], "category_id": 2}, {"id": 23, "bbox": [68.92, 1077.61, 165.56, 96.61], "category_id": 2}, {"id": 24, "bbox": [428.47, 873.03, 61.82, 49.01], "category_id": 3}], "caption": "Scheme 2", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [73, 395, 134, 409], "ImageBB": [79, 416, 404, 771]}, "reactions": [{"reactants": [18], "conditions": [22, 7], "products": [20]}, {"reactants": [20], "conditions": [16, 4], "products": [13]}, {"reactants": [13], "conditions": [10, 14], "products": [6]}, {"reactants": [6], "conditions": [0], "products": [11]}, {"reactants": [17], "conditions": [23, 2], "products": [15]}, {"reactants": [15], "conditions": [8, 1], "products": [21]}, {"reactants": [21], "conditions": [3], "products": [11]}], "diagram_type": "tree"}, {"id": 1330, "width": 2820, "height": 1424, "file_name": "op400242j-Scheme-c7.png", "license": 0, "bboxes": [{"id": 0, "bbox": [427.44, 571.44, 404.88, 266.67], "category_id": 1}, {"id": 1, "bbox": [873.23, 658.91, 251.1, 57.85], "category_id": 2}, {"id": 2, "bbox": [1238.6, 1030.0, 414.75, 321.69], "category_id": 1}, {"id": 3, "bbox": [1551.78, 794.37, 71.94, 57.85], "category_id": 3}, {"id": 4, "bbox": [878.87, 716.76, 255.34, 47.98], "category_id": 2}, {"id": 5, "bbox": [1551.78, 237.04, 64.89, 55.03], "category_id": 3}, {"id": 6, "bbox": [2251.49, 794.37, 69.12, 55.02], "category_id": 3}, {"id": 7, "bbox": [1990.51, 571.44, 402.05, 262.43], "category_id": 1}, {"id": 8, "bbox": [689.83, 800.01, 46.56, 49.38], "category_id": 3}, {"id": 9, "bbox": [1635.38, 526.95, 114.85, 57.42], "category_id": 2}, {"id": 10, "bbox": [1232.96, 18.34, 517.73, 262.44], "category_id": 1}, {"id": 11, "bbox": [1785.95, 664.56, 211.61, 62.08], "category_id": 2}, {"id": 12, "bbox": [1238.6, 488.2, 407.2, 345.67], "category_id": 1}, {"id": 13, "bbox": [1553.19, 1322.06, 77.59, 59.26], "category_id": 3}], "caption": "Scheme 7. Hypothesized chlorination mechanism to form chloroimidate 18", "pdf": {"Page": 7, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 507, 110], "ImageBB": [82, 116, 787, 472]}, "reactions": [{"reactants": [0], "conditions": [1, 4], "products": [10, 12, 2]}, {"reactants": [12, 9], "conditions": [11], "products": [7]}], "diagram_type": "tree"}, {"id": 408, "width": 1704, "height": 3984, "file_name": "op400278d-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [70.0, 2094.0, 1634.0, 1890.0], "category_id": 2}, {"id": 1, "bbox": [130.0, 1529.5, 235.4, 95.0], "category_id": 3}, {"id": 2, "bbox": [573.3, 1532.4, 234.1, 93.8], "category_id": 3}, {"id": 3, "bbox": [147.0, 1938.0, 271.3, 111.1], "category_id": 3}, {"id": 4, "bbox": [1040.1, 1534.0, 238.8, 91.4], "category_id": 3}, {"id": 5, "bbox": [118.0, 626.0, 265.0, 100.6], "category_id": 3}, {"id": 6, "bbox": [568.0, 625.1, 249.0, 101.0], "category_id": 3}, {"id": 7, "bbox": [1048.2, 1949.6, 231.3, 98.7], "category_id": 3}, {"id": 8, "bbox": [556.0, 1950.0, 380.6, 114.7], "category_id": 3}, {"id": 9, "bbox": [83.8, 1224.8, 335.6, 268.0], "category_id": 1}, {"id": 10, "bbox": [745.5, 776.7, 553.8, 295.3], "category_id": 1}, {"id": 11, "bbox": [199.0, 761.0, 424.5, 322.4], "category_id": 1}, {"id": 12, "bbox": [526.0, 1231.5, 328.2, 270.5], "category_id": 1}, {"id": 13, "bbox": [979.4, 1209.0, 369.4, 310.4], "category_id": 1}, {"id": 14, "bbox": [700.8, 63.5, 355.5, 100.5], "category_id": 2}, {"id": 15, "bbox": [676.4, 190.2, 387.9, 65.9], "category_id": 2}, {"id": 16, "bbox": [472.0, 4.0, 911.0, 60.0], "category_id": 2}, {"id": 17, "bbox": [1018.0, 630.0, 301.0, 96.6], "category_id": 3}, {"id": 18, "bbox": [829.0, 1080.0, 402.0, 113.0], "category_id": 3}, {"id": 19, "bbox": [295.0, 1076.0, 233.0, 104.0], "category_id": 3}, {"id": 20, "bbox": [132.3, 142.5, 119.7, 68.9], "category_id": 1}, {"id": 21, "bbox": [365.82, 213.4, 204.11, 64.34], "category_id": 2}, {"id": 22, "bbox": [75.18, 213.4, 206.33, 64.34], "category_id": 2}, {"id": 23, "bbox": [1169.4, 143.4, 172.8, 64.2], "category_id": 1}, {"id": 24, "bbox": [89.1, 345.0, 320.6, 253.0], "category_id": 1}, {"id": 25, "bbox": [943.8, 328.7, 431.9, 293.3], "category_id": 1}, {"id": 26, "bbox": [529.7, 345.0, 328.0, 257.3], "category_id": 1}, {"id": 27, "bbox": [426.1, 148.0, 120.2, 60.7], "category_id": 1}, {"id": 28, "bbox": [943.7, 1652.3, 433.5, 282.3], "category_id": 1}, {"id": 29, "bbox": [581.4, 1662.0, 332.9, 266.0], "category_id": 1}, {"id": 30, "bbox": [78.0, 1654.0, 432.6, 274.0], "category_id": 1}], "reactions": [{"reactants": [20, 27], "conditions": [16, 14, 15], "products": [23]}], "corefs": [[24, 5], [26, 6], [25, 17], [11, 19], [10, 18], [9, 1], [12, 2], [13, 4], [30, 3], [29, 8], [28, 7]], "caption": "Table 3. Room temperature aryl sul\ufb01nations mediated by pre-catalyst Pd-PEPPSI-IPentCl-picoline (35) ", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 95, 773, 126], "ImageBB": [433, 131, 859, 1127]}, "diagram_type": "single"}, {"id": 1149, "width": 1352, "height": 1556, "file_name": "ol036510q-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [203.2, 1112.32, 117.56, 51.37], "category_id": 2}, {"id": 1, "bbox": [425.09, 227.29, 218.77, 93.41], "category_id": 1}, {"id": 2, "bbox": [330.1, 1059.39, 509.95, 162.68], "category_id": 1}, {"id": 3, "bbox": [814.36, 667.86, 505.28, 307.46], "category_id": 1}, {"id": 4, "bbox": [33.48, 1057.83, 168.94, 137.0], "category_id": 1}, {"id": 5, "bbox": [854.07, 194.6, 36.59, 38.14], "category_id": 3}, {"id": 6, "bbox": [293.51, 254.53, 94.99, 49.82], "category_id": 2}, {"id": 7, "bbox": [813.58, 1197.94, 509.17, 305.91], "category_id": 1}, {"id": 8, "bbox": [498.27, 1179.26, 35.81, 39.7], "category_id": 3}, {"id": 9, "bbox": [699.14, 303.57, 475.69, 252.98], "category_id": 1}, {"id": 10, "bbox": [140.92, 393.86, 33.47, 38.92], "category_id": 3}, {"id": 11, "bbox": [1271.37, 916.94, 32.7, 38.92], "category_id": 3}, {"id": 12, "bbox": [112.11, 202.38, 171.28, 135.44], "category_id": 1}, {"id": 13, "bbox": [830.71, 0.0, 289.62, 246.75], "category_id": 1}, {"id": 14, "bbox": [63.84, 1215.84, 32.7, 41.26], "category_id": 3}], "caption": "Scheme 1", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [212, 75, 265, 88], "ImageBB": [73, 93, 411, 482]}, "reactions": [{"reactants": [12, 6, 1], "conditions": [], "products": [13]}, {"reactants": [4, 0, 2], "conditions": [], "products": [3]}], "diagram_type": "tree"}, {"id": 54, "width": 2820, "height": 2000, "file_name": "ja406383h-Table-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1524.72, 229.66, 23.37, 31.63], "category_id": 3}, {"id": 1, "bbox": [1436.32, 4.28, 305.58, 244.38], "category_id": 1}, {"id": 2, "bbox": [127.22, 288.63, 2560.9, 1540.84], "category_id": 4}, {"id": 3, "bbox": [0.0, 1850.03, 2814.0, 119.79], "category_id": 4}, {"id": 4, "bbox": [491.08, 48.0, 274.98, 168.61], "category_id": 1}, {"id": 5, "bbox": [867.04, 75.2, 125.36, 120.52], "category_id": 1}, {"id": 6, "bbox": [1073.96, 33.91, 304.13, 82.15], "category_id": 2}, {"id": 7, "bbox": [2045.98, 215.89, 278.88, 52.85], "category_id": 2}, {"id": 8, "bbox": [1121.56, 150.49, 188.04, 78.26], "category_id": 2}, {"id": 9, "bbox": [624.66, 228.69, 22.89, 31.63], "category_id": 3}, {"id": 10, "bbox": [921.93, 230.63, 24.83, 30.66], "category_id": 3}], "reactions": [{"reactants": [4, 5], "conditions": [6, 8], "products": [1]}], "corefs": [[4, 9], [5, 10], [1, 0]], "caption": "Table 4. Iridium Catalyzed Direct Amidation of Ole\ufb01nic C\u2212H Bondsa", "pdf": {"Page": 6, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 89, 480, 110], "ImageBB": [82, 116, 787, 616]}, "diagram_type": "single"}, {"id": 1232, "width": 1216, "height": 664, "file_name": "op0102013-Scheme-c7.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1166.73, 509.07, 49.27, 36.49], "category_id": 3}, {"id": 1, "bbox": [0.0, 2.43, 438.59, 313.84], "category_id": 1}, {"id": 2, "bbox": [0.0, 331.47, 491.51, 316.27], "category_id": 1}, {"id": 3, "bbox": [675.83, 620.98, 43.79, 32.85], "category_id": 3}, {"id": 4, "bbox": [130.18, 291.33, 44.4, 36.5], "category_id": 3}, {"id": 5, "bbox": [445.28, 85.76, 172.15, 77.24], "category_id": 2}, {"id": 6, "bbox": [675.83, 297.42, 52.31, 35.88], "category_id": 3}, {"id": 7, "bbox": [538.35, 330.87, 489.08, 313.23], "category_id": 1}, {"id": 8, "bbox": [129.57, 623.42, 54.75, 34.06], "category_id": 3}, {"id": 9, "bbox": [548.08, 7.91, 490.3, 313.83], "category_id": 1}, {"id": 10, "bbox": [445.28, 445.82, 151.47, 71.16], "category_id": 2}, {"id": 11, "bbox": [1020.73, 200.71, 86.38, 35.88], "category_id": 2}, {"id": 12, "bbox": [970.85, 437.3, 191.62, 77.85], "category_id": 2}, {"id": 13, "bbox": [1005.53, 115.56, 132.0, 45.62], "category_id": 2}, {"id": 14, "bbox": [970.85, 538.27, 100.98, 38.31], "category_id": 2}], "caption": "Scheme 7. Process for 16r-Me epoxide (3b)", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 53, 689, 67], "ImageBB": [456, 72, 760, 238]}, "reactions": [{"reactants": [1], "conditions": [5], "products": [9]}, {"reactants": [9], "conditions": [13, 11], "products": [2]}, {"reactants": [2], "conditions": [10], "products": [7]}, {"reactants": [7], "conditions": [12, 14], "products": [0]}], "diagram_type": "multiple"}, {"id": 1034, "width": 1268, "height": 1716, "file_name": "jo001614p-Scheme-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [420.63, 262.68, 266.97, 197.44], "category_id": 1}, {"id": 1, "bbox": [700.47, 551.11, 54.94, 69.53], "category_id": 3}, {"id": 2, "bbox": [0.0, 1072.18, 237.78, 86.7], "category_id": 1}, {"id": 3, "bbox": [830.09, 739.97, 333.07, 189.71], "category_id": 1}, {"id": 4, "bbox": [0.0, 664.42, 363.11, 123.62], "category_id": 1}, {"id": 5, "bbox": [830.09, 265.25, 293.58, 194.87], "category_id": 1}, {"id": 6, "bbox": [0.0, 265.25, 265.25, 195.73], "category_id": 1}, {"id": 7, "bbox": [420.63, 664.42, 349.37, 123.62], "category_id": 1}, {"id": 8, "bbox": [1017.23, 48.93, 159.67, 141.64], "category_id": 1}, {"id": 9, "bbox": [1110.8, 825.81, 66.1, 72.11], "category_id": 3}, {"id": 10, "bbox": [277.27, 0.0, 234.35, 111.6], "category_id": 2}, {"id": 11, "bbox": [612.05, 196.58, 112.46, 51.51], "category_id": 3}, {"id": 12, "bbox": [783.74, 999.21, 223.19, 111.6], "category_id": 2}, {"id": 13, "bbox": [130.48, 193.15, 111.59, 57.51], "category_id": 3}, {"id": 14, "bbox": [13.73, 1416.41, 517.63, 299.59], "category_id": 1}, {"id": 15, "bbox": [529.65, 1044.71, 230.05, 145.07], "category_id": 1}, {"id": 16, "bbox": [592.31, 1194.08, 95.29, 49.78], "category_id": 3}, {"id": 17, "bbox": [420.63, 460.12, 289.28, 194.0], "category_id": 1}, {"id": 18, "bbox": [78.12, 1190.64, 103.01, 54.08], "category_id": 3}, {"id": 19, "bbox": [0.0, 463.55, 303.88, 190.57], "category_id": 1}, {"id": 20, "bbox": [73.82, 88.42, 161.39, 71.25], "category_id": 1}, {"id": 21, "bbox": [280.7, 367.41, 64.39, 64.38], "category_id": 3}, {"id": 22, "bbox": [280.7, 549.39, 63.53, 69.54], "category_id": 3}, {"id": 23, "bbox": [323.62, 139.92, 143.36, 63.53], "category_id": 2}, {"id": 24, "bbox": [1080.75, 194.01, 102.15, 54.93], "category_id": 3}, {"id": 25, "bbox": [280.7, 994.06, 220.62, 113.31], "category_id": 2}, {"id": 26, "bbox": [700.47, 367.41, 62.67, 64.38], "category_id": 3}, {"id": 27, "bbox": [783.74, 0.0, 194.86, 113.31], "category_id": 2}, {"id": 28, "bbox": [310.75, 1138.28, 145.07, 60.95], "category_id": 2}, {"id": 29, "bbox": [548.53, 1637.02, 134.77, 62.67], "category_id": 3}, {"id": 30, "bbox": [1018.95, 1044.71, 235.2, 145.07], "category_id": 1}, {"id": 31, "bbox": [18.89, 1270.48, 778.58, 71.24], "category_id": 2}, {"id": 32, "bbox": [1115.09, 359.68, 64.38, 65.24], "category_id": 3}, {"id": 33, "bbox": [1179.94, 506.73, 41.2, 53.56], "category_id": 3}, {"id": 34, "bbox": [1223.2, 648.87, 41.21, 55.62], "category_id": 3}, {"id": 35, "bbox": [704.08, 755.99, 61.8, 55.62], "category_id": 3}, {"id": 36, "bbox": [830.09, 617.21, 391.91, 120.18], "category_id": 1}, {"id": 37, "bbox": [830.09, 470.42, 354.01, 126.19], "category_id": 1}, {"id": 38, "bbox": [545.96, 47.21, 184.56, 143.36], "category_id": 1}, {"id": 39, "bbox": [280.7, 751.98, 69.54, 66.1], "category_id": 3}, {"id": 40, "bbox": [1085.04, 1194.08, 94.43, 50.64], "category_id": 3}], "caption": "Scheme 3", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [573, 385, 636, 399], "ImageBB": [449, 405, 766, 834]}, "reactions": [{"reactants": [20], "conditions": [10, 23], "products": [38]}, {"reactants": [38], "conditions": [27], "products": [8]}, {"reactants": [2], "conditions": [25, 28], "products": [15]}, {"reactants": [15], "conditions": [12], "products": [30]}], "diagram_type": "multiple"}, {"id": 477, "width": 1352, "height": 3832, "file_name": "ol0703579-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [156.0, 256.0, 66.0, 51.0], "category_id": 3}, {"id": 1, "bbox": [12.0, 333.0, 665.0, 1164.0], "category_id": 4}, {"id": 2, "bbox": [604.0, 174.0, 262.0, 94.0], "category_id": 2}, {"id": 3, "bbox": [599.0, 106.0, 296.0, 56.0], "category_id": 2}, {"id": 4, "bbox": [416.0, 247.0, 112.0, 60.0], "category_id": 3}, {"id": 5, "bbox": [66.0, 62.0, 209.0, 191.0], "category_id": 1}, {"id": 6, "bbox": [339.0, 82.0, 256.0, 186.0], "category_id": 1}, {"id": 7, "bbox": [995.0, 254.0, 118.0, 53.0], "category_id": 3}, {"id": 8, "bbox": [680.0, 328.0, 668.0, 1169.0], "category_id": 4}, {"id": 9, "bbox": [920.3, 0.0, 336.6, 303.5], "category_id": 1}], "reactions": [{"reactants": [5, 6], "conditions": [3, 2], "products": [9]}], "corefs": [[5, 0], [6, 4], [9, 7]], "caption": "Table 3. Variation of the Indole Substrate", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 76, 665, 89], "ImageBB": [439, 93, 777, 1051]}, "diagram_type": "single"}, {"id": 448, "width": 2808, "height": 428, "file_name": "op2001047-Table-c7.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1598.7, 8.5, 253.2, 133.9], "category_id": 1}, {"id": 1, "bbox": [1312.0, 117.4, 195.0, 93.1], "category_id": 2}, {"id": 2, "bbox": [957.7, 8.1, 248.8, 134.3], "category_id": 1}, {"id": 3, "bbox": [1676.0, 171.0, 108.5, 57.0], "category_id": 3}, {"id": 4, "bbox": [6.0, 258.0, 2799.0, 170.0], "category_id": 4}, {"id": 5, "bbox": [1044.0, 177.0, 96.0, 54.0], "category_id": 3}, {"id": 6, "bbox": [1336.0, 0.0, 174.0, 99.0], "category_id": 2}], "reactions": [{"reactants": [2], "conditions": [6, 1], "products": [0]}], "corefs": [[2, 5], [0, 3]], "caption": "Table 7. Optimized reaction conditions for the \ufb02ow hydrogenation of 4-aryl-3-buten-2-ones 1a ca", "pdf": {"Page": 8, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [71, 87, 617, 109], "ImageBB": [71, 117, 773, 224]}, "diagram_type": "single"}, {"id": 191, "width": 1352, "height": 640, "file_name": "op0601316-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [531.0, 380.0, 238.0, 59.9], "category_id": 2}, {"id": 1, "bbox": [811.2, 0.0, 347.8, 209.9], "category_id": 1}, {"id": 2, "bbox": [867.0, 216.0, 236.3, 100.0], "category_id": 2}, {"id": 3, "bbox": [220.2, 10.0, 213.5, 192.8], "category_id": 1}, {"id": 4, "bbox": [898.2, 334.1, 256.3, 190.8], "category_id": 1}, {"id": 5, "bbox": [361.2, 358.0, 127.5, 131.7], "category_id": 1}, {"id": 6, "bbox": [28.2, 333.2, 214.5, 193.7], "category_id": 1}, {"id": 7, "bbox": [193.73, 213.91, 267.13, 62.2], "category_id": 2}, {"id": 8, "bbox": [137.0, 86.0, 41.0, 54.0], "category_id": 3}, {"id": 9, "bbox": [2.0, 539.0, 272.0, 63.0], "category_id": 2}, {"id": 10, "bbox": [301.0, 545.0, 265.0, 53.0], "category_id": 2}, {"id": 11, "bbox": [696.0, 539.0, 656.0, 101.0], "category_id": 2}, {"id": 12, "bbox": [526.0, 57.0, 241.0, 65.0], "category_id": 2}], "reactions": [{"reactants": [3], "conditions": [12], "products": [1]}, {"reactants": [6, 5], "conditions": [0], "products": [4]}], "corefs": [[3, 7], [1, 2], [6, 9], [5, 10], [4, 11]], "caption": "Figure 1. BAL-catalyzed carboligation.", "pdf": {"Page": 1, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 410, 661, 424], "ImageBB": [439, 247, 777, 407]}, "diagram_type": "multiple"}, {"id": 61, "width": 1340, "height": 800, "file_name": "ja312277g-Table-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [91.12, 201.46, 43.4, 38.0], "category_id": 3}, {"id": 1, "bbox": [2.92, 570.46, 273.8, 119.0], "category_id": 1}, {"id": 2, "bbox": [1073.92, 282.46, 228.78, 189.2], "category_id": 1}, {"id": 3, "bbox": [766.12, 282.46, 228.8, 187.4], "category_id": 1}, {"id": 4, "bbox": [503.32, 280.66, 189.2, 174.8], "category_id": 1}, {"id": 5, "bbox": [28.12, 280.66, 192.8, 173.0], "category_id": 1}, {"id": 6, "bbox": [1100.92, 5.26, 234.2, 180.2], "category_id": 1}, {"id": 7, "bbox": [798.52, 7.06, 234.2, 180.2], "category_id": 1}, {"id": 8, "bbox": [499.72, 52.06, 261.2, 135.2], "category_id": 1}, {"id": 9, "bbox": [4.72, 34.06, 234.2, 144.2], "category_id": 1}, {"id": 10, "bbox": [514.12, 577.66, 273.8, 115.4], "category_id": 1}, {"id": 11, "bbox": [931.72, 575.86, 290.0, 128.04], "category_id": 1}, {"id": 12, "bbox": [272.92, 53.86, 137.0, 83.0], "category_id": 2}, {"id": 13, "bbox": [258.52, 174.46, 196.4, 36.2], "category_id": 2}, {"id": 14, "bbox": [272.92, 293.3, 137.0, 77.56], "category_id": 2}, {"id": 15, "bbox": [253.12, 410.26, 200.0, 38.0], "category_id": 2}, {"id": 16, "bbox": [307.12, 590.26, 63.2, 34.4], "category_id": 2}, {"id": 17, "bbox": [258.52, 698.26, 209.0, 90.2], "category_id": 2}, {"id": 18, "bbox": [89.32, 475.06, 44.68, 34.64], "category_id": 3}, {"id": 19, "bbox": [537.52, 203.26, 143.88, 41.24], "category_id": 3}, {"id": 20, "bbox": [527.38, 478.21, 144.92, 39.19], "category_id": 3}, {"id": 21, "bbox": [834.67, 477.17, 144.93, 39.33], "category_id": 3}, {"id": 22, "bbox": [1132.58, 478.21, 143.92, 39.29], "category_id": 3}, {"id": 23, "bbox": [963.76, 704.72, 144.36, 87.31], "category_id": 3}, {"id": 24, "bbox": [101.61, 704.72, 43.09, 33.07], "category_id": 3}, {"id": 25, "bbox": [1131.18, 204.57, 145.36, 41.09], "category_id": 3}, {"id": 26, "bbox": [853.49, 203.46, 135.33, 41.1], "category_id": 3}, {"id": 27, "bbox": [526.67, 704.72, 143.36, 87.31], "category_id": 3}], "reactions": [{"reactants": [9], "conditions": [12, 13], "products": [8, 7, 6]}, {"reactants": [5], "conditions": [14, 15], "products": [4, 3, 2]}, {"reactants": [1], "conditions": [16, 17], "products": [10, 11]}], "corefs": [[9, 0], [8, 19], [7, 26], [6, 25], [5, 18], [4, 20], [3, 21], [2, 22], [1, 24], [10, 27], [11, 23]], "caption": "Table 4. Sequential C(sp3)\u2212H Methylation", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 696, 325, 715], "ImageBB": [83, 720, 418, 920]}, "diagram_type": "multiple"}, {"id": 65, "width": 1352, "height": 1188, "file_name": "ja307151x-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [290.33, 355.29, 218.56, 82.44], "category_id": 2}, {"id": 1, "bbox": [896.7, 271.76, 351.59, 42.22], "category_id": 3}, {"id": 2, "bbox": [103.15, 1014.26, 198.46, 40.68], "category_id": 3}, {"id": 3, "bbox": [970.95, 1014.26, 299.0, 42.22], "category_id": 3}, {"id": 4, "bbox": [359.94, 1103.98, 563.51, 79.35], "category_id": 3}, {"id": 5, "bbox": [579.59, 607.44, 264.97, 40.67], "category_id": 3}, {"id": 6, "bbox": [214.53, 271.76, 170.61, 42.22], "category_id": 3}, {"id": 7, "bbox": [745.11, 692.51, 204.64, 80.89], "category_id": 2}, {"id": 8, "bbox": [78.4, 5.7, 453.69, 234.03], "category_id": 1}, {"id": 9, "bbox": [854.94, 8.79, 424.29, 249.5], "category_id": 1}, {"id": 10, "bbox": [513.08, 353.75, 398.0, 234.03], "category_id": 1}, {"id": 11, "bbox": [8.79, 757.48, 394.91, 235.58], "category_id": 1}, {"id": 12, "bbox": [448.11, 760.58, 401.09, 334.57], "category_id": 1}, {"id": 13, "bbox": [893.61, 755.94, 430.48, 235.57], "category_id": 1}, {"id": 14, "bbox": [590.42, 78.4, 223.2, 40.7], "category_id": 2}, {"id": 15, "bbox": [605.89, 144.92, 176.8, 80.89], "category_id": 2}, {"id": 16, "bbox": [1001.89, 579.59, 173.7, 79.35], "category_id": 2}], "reactions": [{"reactants": [8], "conditions": [14, 15], "products": [9]}, {"reactants": [8], "conditions": [0], "products": [10]}, {"reactants": [10], "conditions": [7], "products": [12]}, {"reactants": [10], "conditions": [16], "products": [13]}], "corefs": [[8, 6], [9, 1], [10, 5], [11, 2], [12, 4], [13, 3]], "caption": "Figure 1. Formations of monodictyphenone (2) and related xanthones 3\u22126 proceed by a deoxygenation reaction and BV oxidation.2\u22125,7 Chrysophanol (7) has been shown to be a precursor of 4\u22126.4c,d,5d,7 Each deoxygenation site is highlighted by a circle. ", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 640, 784, 695], "ImageBB": [448, 333, 786, 630]}, "diagram_type": "tree"}, {"id": 865, "width": 1356, "height": 1376, "file_name": "jo2001534-Table-c6.png", "license": 0, "bboxes": [{"id": 0, "bbox": [146.0, 415.0, 211.0, 120.0], "category_id": 3}, {"id": 1, "bbox": [562.0, 228.0, 218.0, 112.0], "category_id": 3}, {"id": 2, "bbox": [8.0, 1008.0, 1347.0, 368.0], "category_id": 4}, {"id": 3, "bbox": [1000.0, 424.9, 198.2, 101.2], "category_id": 3}, {"id": 4, "bbox": [38.1, 803.5, 192.5, 96.0], "category_id": 3}, {"id": 5, "bbox": [616.2, 392.0, 57.0, 174.0], "category_id": 2}, {"id": 6, "bbox": [1088.0, 600.1, 264.5, 174.0], "category_id": 1}, {"id": 7, "bbox": [513.1, 606.8, 334.1, 231.4], "category_id": 1}, {"id": 8, "bbox": [882.0, 671.0, 178.9, 43.6], "category_id": 2}, {"id": 9, "bbox": [582.7, 854.2, 178.1, 101.7], "category_id": 3}, {"id": 10, "bbox": [1129.6, 799.9, 188.6, 100.5], "category_id": 3}, {"id": 11, "bbox": [789.0, 421.3, 149.2, 164.1], "category_id": 2}, {"id": 12, "bbox": [298.5, 683.4, 164.8, 47.9], "category_id": 2}, {"id": 13, "bbox": [407.2, 416.1, 147.3, 158.4], "category_id": 2}, {"id": 14, "bbox": [957.3, 234.8, 279.7, 188.0], "category_id": 1}, {"id": 15, "bbox": [551.5, 1.8, 237.6, 207.1], "category_id": 1}, {"id": 16, "bbox": [5.3, 594.8, 257.5, 183.0], "category_id": 1}, {"id": 17, "bbox": [125.7, 208.5, 256.3, 203.5], "category_id": 1}], "reactions": [{"reactants": [7], "conditions": [12], "products": [16]}, {"reactants": [7], "conditions": [8], "products": [6]}, {"reactants": [7], "conditions": [13], "products": [17]}, {"reactants": [7], "conditions": [5], "products": [15]}, {"reactants": [7], "conditions": [11], "products": [14]}], "corefs": [[7, 9], [16, 4], [6, 10], [17, 0], [15, 1], [14, 3]], "caption": "Table 6. Comparison of 5-Exo-Trig, 5-Endo-Trig, 6-Exo-Trig, 6-Endo-Trig, and 7-Endo-Trig Ring-Forming Reactions of Anion 1a- and 1d-. (Activation Barriers (Erel TS) and Reaction Energies (Erel Cycle) with Regard to the Global Minimum Structures of the Open-Chain Form (Erel = 0.0 kcal/mol)): SCS-MP2/6-311\u00feG(d,p)//B3LYP/6-31\u00feG(d,p) (Corrected for Zero-Point Energies) [kcal/mol]; See the Supporting Information for Optimized Structures) ", "pdf": {"Page": 6, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [437, 366, 771, 487], "ImageBB": [436, 498, 775, 842]}, "diagram_type": "tree"}, {"id": 1209, "width": 1348, "height": 956, "file_name": "ol800523j-Scheme-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [758.63, 254.32, 542.17, 116.71], "category_id": 1}, {"id": 1, "bbox": [794.37, 2.7, 374.93, 51.94], "category_id": 2}, {"id": 2, "bbox": [720.19, 665.15, 540.82, 124.13], "category_id": 1}, {"id": 3, "bbox": [957.56, 372.38, 205.67, 52.62], "category_id": 3}, {"id": 4, "bbox": [493.61, 107.26, 211.07, 53.29], "category_id": 3}, {"id": 5, "bbox": [294.01, 372.38, 133.52, 51.27], "category_id": 3}, {"id": 6, "bbox": [124.08, 111.31, 69.45, 53.29], "category_id": 3}, {"id": 7, "bbox": [128.12, 840.55, 384.38, 55.99], "category_id": 3}, {"id": 8, "bbox": [722.22, 840.55, 528.68, 55.99], "category_id": 3}, {"id": 9, "bbox": [38.44, 32.38, 238.71, 89.72], "category_id": 1}, {"id": 10, "bbox": [38.44, 431.74, 475.4, 400.04], "category_id": 1}, {"id": 11, "bbox": [621.06, 437.14, 389.1, 156.5], "category_id": 2}, {"id": 12, "bbox": [441.02, 24.96, 323.68, 74.88], "category_id": 1}, {"id": 13, "bbox": [61.36, 263.09, 541.5, 111.99], "category_id": 1}, {"id": 14, "bbox": [848.99, 99.84, 296.71, 87.02], "category_id": 2}], "caption": "Scheme 3. Trapping of Isomerization Intermediate", "pdf": {"Page": 3, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [462, 242, 723, 257], "ImageBB": [425, 264, 762, 503]}, "reactions": [{"reactants": [9, 12], "conditions": [1, 14], "products": [13, 0]}, {"reactants": [13, 0], "conditions": [11], "products": [10, 2]}], "diagram_type": "tree"}, {"id": 178, "width": 1300, "height": 660, "file_name": "op0602270-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [0.0, 5.9, 342.2, 219.1], "category_id": 1}, {"id": 1, "bbox": [936.6, 2.0, 344.8, 224.3], "category_id": 1}, {"id": 2, "bbox": [430.0, 366.7, 415.5, 59.5], "category_id": 2}, {"id": 3, "bbox": [367.1, 482.8, 570.3, 61.7], "category_id": 2}, {"id": 4, "bbox": [1064.1, 597.9, 118.9, 51.1], "category_id": 3}, {"id": 5, "bbox": [127.88, 226.96, 88.0, 55.0], "category_id": 3}, {"id": 6, "bbox": [1068.94, 242.02, 126.0, 55.0], "category_id": 3}, {"id": 7, "bbox": [413.6, 23.6, 412.8, 55.9], "category_id": 2}, {"id": 8, "bbox": [374.0, 141.6, 524.3, 57.8], "category_id": 2}, {"id": 9, "bbox": [276.06, 600.02, 79.0, 55.0], "category_id": 3}, {"id": 10, "bbox": [961.0, 352.0, 339.0, 223.0], "category_id": 1}, {"id": 11, "bbox": [15.0, 344.0, 233.0, 316.0], "category_id": 1}], "reactions": [{"reactants": [0], "conditions": [7, 8], "products": [1]}, {"reactants": [11], "conditions": [2, 3], "products": [10]}], "corefs": [[0, 5], [1, 6], [11, 9], [10, 4]], "caption": "Table 1. Hydrogenation of E-7 and Z-7 with different 4,5-dihydro-3H-dinaphtho[2,1-c;1\u2032,2\u2032-e]phosphepines (6a-6i) ", "pdf": {"Page": 7, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 53, 403, 81], "ImageBB": [80, 89, 405, 254]}, "diagram_type": "multiple"}, {"id": 1116, "width": 1328, "height": 1696, "file_name": "jo982024i-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [289.25, 172.23, 112.81, 50.91], "category_id": 2}, {"id": 1, "bbox": [609.03, 319.86, 27.14, 45.81], "category_id": 3}, {"id": 2, "bbox": [290.1, 104.36, 142.5, 49.2], "category_id": 2}, {"id": 3, "bbox": [343.53, 424.21, 354.57, 400.46], "category_id": 1}, {"id": 4, "bbox": [413.94, 850.12, 309.6, 367.37], "category_id": 1}, {"id": 5, "bbox": [982.25, 426.76, 326.57, 318.16], "category_id": 1}, {"id": 6, "bbox": [1056.05, 1604.37, 189.16, 86.54], "category_id": 3}, {"id": 7, "bbox": [609.03, 1204.76, 61.92, 48.36], "category_id": 3}, {"id": 8, "bbox": [536.93, 784.79, 41.56, 45.82], "category_id": 3}, {"id": 9, "bbox": [701.49, 96.72, 336.75, 61.09], "category_id": 2}, {"id": 10, "bbox": [966.99, 0.0, 359.65, 404.7], "category_id": 1}, {"id": 11, "bbox": [782.07, 1024.05, 221.39, 50.9], "category_id": 2}, {"id": 12, "bbox": [719.3, 605.77, 271.44, 55.15], "category_id": 2}, {"id": 13, "bbox": [982.25, 853.51, 326.57, 315.62], "category_id": 1}, {"id": 14, "bbox": [0.0, 60.24, 305.36, 263.86], "category_id": 1}, {"id": 15, "bbox": [1182.44, 313.92, 46.65, 48.36], "category_id": 3}, {"id": 16, "bbox": [117.06, 1463.53, 122.14, 56.85], "category_id": 2}, {"id": 17, "bbox": [656.53, 1467.77, 310.46, 107.75], "category_id": 2}, {"id": 18, "bbox": [186.61, 315.61, 40.72, 48.36], "category_id": 3}, {"id": 19, "bbox": [58.53, 1016.41, 349.47, 56.0], "category_id": 2}, {"id": 20, "bbox": [27.99, 598.99, 357.96, 61.93], "category_id": 2}, {"id": 21, "bbox": [782.07, 960.42, 189.16, 55.14], "category_id": 2}, {"id": 22, "bbox": [454.65, 1616.25, 61.92, 40.72], "category_id": 3}, {"id": 23, "bbox": [965.29, 1287.06, 329.96, 312.22], "category_id": 1}, {"id": 24, "bbox": [743.9, 527.72, 195.09, 64.48], "category_id": 2}, {"id": 25, "bbox": [1049.26, 1164.04, 184.92, 103.51], "category_id": 3}, {"id": 26, "bbox": [1115.43, 790.73, 43.26, 43.27], "category_id": 3}, {"id": 27, "bbox": [59.38, 1395.66, 256.16, 52.6], "category_id": 2}, {"id": 28, "bbox": [363.04, 0.0, 349.48, 404.7], "category_id": 1}, {"id": 29, "bbox": [295.18, 1275.18, 343.54, 313.07], "category_id": 1}, {"id": 30, "bbox": [89.06, 948.54, 234.96, 62.78], "category_id": 2}, {"id": 31, "bbox": [27.99, 525.17, 306.21, 60.24], "category_id": 2}, {"id": 32, "bbox": [658.23, 1399.9, 324.02, 51.75], "category_id": 2}, {"id": 33, "bbox": [702.78, 173.01, 293.19, 118.09], "category_id": 2}], "caption": "Scheme 1", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [207, 64, 270, 78], "ImageBB": [77, 86, 409, 510]}, "reactions": [{"reactants": [14], "conditions": [2, 0], "products": [28]}, {"reactants": [28], "conditions": [9, 33], "products": [10]}, {"reactants": [10], "conditions": [31, 20], "products": [3]}, {"reactants": [3], "conditions": [24, 12], "products": [5]}, {"reactants": [5], "conditions": [30, 19], "products": [4]}, {"reactants": [4], "conditions": [21, 11], "products": [13]}, {"reactants": [13], "conditions": [27, 16], "products": [29]}, {"reactants": [29], "conditions": [32, 17], "products": [23]}], "diagram_type": "multiple"}, {"id": 210, "width": 1352, "height": 1144, "file_name": "op0340816-Figure-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1024.17, 961.5, 253.6, 178.6], "category_id": 1}, {"id": 1, "bbox": [787.57, 597.87, 38.56, 51.0], "category_id": 3}, {"id": 2, "bbox": [1305.53, 166.13, 44.0, 50.3], "category_id": 3}, {"id": 3, "bbox": [826.87, 173.07, 50.0, 46.0], "category_id": 3}, {"id": 4, "bbox": [492.0, 955.9, 225.0, 182.1], "category_id": 1}, {"id": 5, "bbox": [1031.5, 434.3, 251.4, 246.0], "category_id": 1}, {"id": 6, "bbox": [501.7, 431.1, 281.1, 202.5], "category_id": 1}, {"id": 7, "bbox": [494.2, 11.0, 328.8, 197.7], "category_id": 1}, {"id": 8, "bbox": [626.33, 292.2, 63.57, 51.3], "category_id": 2}, {"id": 9, "bbox": [1182.93, 300.13, 67.47, 48.17], "category_id": 2}, {"id": 10, "bbox": [258.0, 143.0, 137.8, 55.7], "category_id": 2}, {"id": 11, "bbox": [291.1, 33.3, 90.9, 50.7], "category_id": 2}, {"id": 12, "bbox": [6.0, 8.0, 252.0, 177.0], "category_id": 1}, {"id": 13, "bbox": [1044.6, 14.0, 261.4, 235.0], "category_id": 1}, {"id": 14, "bbox": [1276.87, 602.4, 40.93, 45.0], "category_id": 3}, {"id": 15, "bbox": [721.4, 1078.53, 33.7, 45.8], "category_id": 3}, {"id": 16, "bbox": [1244.87, 1086.03, 38.13, 47.3], "category_id": 3}], "reactions": [{"reactants": [12], "conditions": [11, 10], "products": [7, 13]}, {"reactants": [7], "conditions": [8], "products": [6]}, {"reactants": [6], "conditions": [], "products": [4]}, {"reactants": [13], "conditions": [9], "products": [5]}, {"reactants": [5], "conditions": [], "products": [0]}], "corefs": [[7, 3], [13, 2], [6, 1], [5, 14], [4, 15], [0, 16]], "caption": "Figure 2. Production of 1,3-dichloro-2-fluorobenzene from 2,3,4-trichloro-1-benzenesulfonyl chloride. ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 529, 409, 557], "ImageBB": [74, 240, 412, 526]}, "diagram_type": "tree"}, {"id": 286, "width": 1352, "height": 1152, "file_name": "ol800086s-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [11.0, 294.0, 1341.0, 858.0], "category_id": 4}, {"id": 1, "bbox": [230.0, 242.0, 48.0, 42.0], "category_id": 3}, {"id": 2, "bbox": [93.0, 0.0, 217.0, 231.0], "category_id": 1}, {"id": 3, "bbox": [15.0, 50.0, 53.0, 137.0], "category_id": 1}, {"id": 4, "bbox": [1092.0, 4.0, 240.0, 231.0], "category_id": 1}, {"id": 5, "bbox": [19.0, 231.0, 190.0, 53.0], "category_id": 3}, {"id": 6, "bbox": [442.0, 21.0, 253.5, 96.1], "category_id": 2}, {"id": 7, "bbox": [890.0, 237.97, 103.0, 49.0], "category_id": 3}, {"id": 8, "bbox": [1157.0, 240.0, 101.1, 49.0], "category_id": 3}, {"id": 9, "bbox": [804.3, 4.0, 245.7, 227.5], "category_id": 1}, {"id": 10, "bbox": [400.0, 122.9, 334.0, 93.1], "category_id": 2}], "reactions": [{"reactants": [3, 2], "conditions": [6, 10], "products": [9, 4]}], "corefs": [[3, 5], [2, 1], [9, 7], [4, 8]], "caption": "Table 1. Alkyne Scope", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 588, 569, 601], "ImageBB": [439, 601, 777, 889]}, "diagram_type": "single"}, {"id": 458, "width": 1356, "height": 796, "file_name": "op200038y-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [658.0, 219.0, 43.0, 32.0], "category_id": 3}, {"id": 1, "bbox": [929.0, 219.0, 46.0, 43.0], "category_id": 3}, {"id": 2, "bbox": [4.0, 56.0, 245.0, 125.0], "category_id": 1}, {"id": 3, "bbox": [513.0, 8.0, 298.0, 199.0], "category_id": 1}, {"id": 4, "bbox": [265.0, 92.0, 238.0, 52.0], "category_id": 2}, {"id": 5, "bbox": [1099.0, 54.7, 253.0, 122.4], "category_id": 1}, {"id": 6, "bbox": [90.0, 217.0, 49.0, 37.0], "category_id": 3}, {"id": 7, "bbox": [823.0, 57.5, 239.0, 122.5], "category_id": 1}, {"id": 8, "bbox": [1133.0, 210.0, 206.0, 91.0], "category_id": 3}], "reactions": [{"reactants": [2], "conditions": [4], "products": [3, 7]}], "corefs": [[2, 6], [3, 0], [7, 1], [5, 8]], "caption": "Table 2. Selective hydrolysis of diester 3c with various bases", "pdf": {"Page": 3, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [71, 247, 405, 262], "ImageBB": [71, 272, 410, 471]}, "diagram_type": "single"}, {"id": 502, "width": 1352, "height": 960, "file_name": "ol052245s-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [493.0, 270.0, 188.0, 91.0], "category_id": 2}, {"id": 1, "bbox": [623.0, 382.0, 361.0, 190.0], "category_id": 1}, {"id": 2, "bbox": [427.0, 616.0, 152.0, 33.0], "category_id": 2}, {"id": 3, "bbox": [702.0, 608.0, 150.0, 50.0], "category_id": 2}, {"id": 4, "bbox": [277.0, 323.0, 94.0, 44.0], "category_id": 3}, {"id": 5, "bbox": [495.14, 168.29, 175.0, 78.0], "category_id": 2}, {"id": 6, "bbox": [221.2, 384.9, 306.3, 183.4], "category_id": 1}, {"id": 7, "bbox": [29.7, 184.7, 386.0, 131.3], "category_id": 1}, {"id": 8, "bbox": [727.86, 567.0, 94.0, 38.0], "category_id": 3}, {"id": 9, "bbox": [457.0, 565.0, 94.1, 45.0], "category_id": 3}, {"id": 10, "bbox": [168.9, 677.3, 430.8, 110.8], "category_id": 4}, {"id": 11, "bbox": [1089.0, 567.0, 217.0, 41.9], "category_id": 3}, {"id": 12, "bbox": [1008.0, 386.0, 327.0, 185.0], "category_id": 1}], "reactions": [{"reactants": [7], "conditions": [5, 0], "products": [6, 1, 12]}], "corefs": [[7, 4], [6, 9], [1, 8], [12, 11]], "caption": "Table 1. Platinum-Catalyzed Hydrosilylation of Para- and Ortho-Substituted Alkynes 1a,b with Triethylsilanea ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 296, 746, 324], "ImageBB": [439, 51, 777, 291]}, "diagram_type": "multiple"}, {"id": 564, "width": 1348, "height": 920, "file_name": "acs.orglett.5b01692-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [547.0, 591.0, 232.0, 97.0], "category_id": 3}, {"id": 1, "bbox": [26.0, 353.7, 346.0, 217.3], "category_id": 1}, {"id": 2, "bbox": [748.99, 77.67, 216.0, 83.0], "category_id": 2}, {"id": 3, "bbox": [951.3, 385.3, 360.7, 269.7], "category_id": 1}, {"id": 4, "bbox": [521.7, 371.3, 292.3, 198.7], "category_id": 1}, {"id": 5, "bbox": [1057.0, 6.67, 269.34, 269.0], "category_id": 1}, {"id": 6, "bbox": [397.7, 36.7, 248.97, 236.31], "category_id": 1}, {"id": 7, "bbox": [34.01, 66.01, 280.99, 178.69], "category_id": 1}, {"id": 8, "bbox": [515.32, 284.0, 60.0, 44.0], "category_id": 3}, {"id": 9, "bbox": [121.99, 279.66, 67.0, 53.0], "category_id": 3}, {"id": 10, "bbox": [32.0, 597.0, 322.0, 233.0], "category_id": 3}, {"id": 11, "bbox": [1096.0, 599.0, 38.0, 47.0], "category_id": 3}, {"id": 12, "bbox": [9.0, 851.0, 1339.0, 69.0], "category_id": 4}, {"id": 13, "bbox": [739.0, 184.0, 245.0, 76.0], "category_id": 2}, {"id": 14, "bbox": [1158.0, 281.0, 83.0, 48.0], "category_id": 3}], "reactions": [{"reactants": [7, 6], "conditions": [2, 13], "products": [5]}], "corefs": [[7, 9], [6, 8], [5, 14], [1, 10], [4, 0], [3, 11]], "caption": "Table 1. Optimization of the Reaction Conditionsa", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 362, 366, 383], "ImageBB": [82, 389, 419, 619]}, "diagram_type": "single"}, {"id": 51, "width": 1352, "height": 2500, "file_name": "ja407689a-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [551.83, 4.07, 258.46, 95.26], "category_id": 2}, {"id": 1, "bbox": [403.92, 209.53, 50.09, 39.89], "category_id": 3}, {"id": 2, "bbox": [355.83, 37.58, 123.68, 153.55], "category_id": 1}, {"id": 3, "bbox": [144.54, 42.68, 79.23, 125.86], "category_id": 1}, {"id": 4, "bbox": [3.73, 292.57, 1345.98, 2201.25], "category_id": 4}, {"id": 5, "bbox": [890.62, 18.64, 318.21, 205.28], "category_id": 1}, {"id": 6, "bbox": [554.01, 135.94, 254.1, 131.69], "category_id": 2}, {"id": 7, "bbox": [160.57, 178.93, 50.81, 41.34], "category_id": 3}, {"id": 8, "bbox": [980.24, 197.87, 52.27, 41.35], "category_id": 3}], "reactions": [{"reactants": [3, 2], "conditions": [0, 6], "products": [5]}], "corefs": [[3, 7], [2, 1], [5, 8]], "caption": "Table 1. 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Oxazaborolidine bound to a polystyrene.", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 541, 358, 555], "ImageBB": [105, 54, 380, 538]}, "diagram_type": "tree"}, {"id": 1309, "width": 1352, "height": 1248, "file_name": "op300170q-Scheme-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1193.74, 630.58, 65.6, 56.16], "category_id": 3}, {"id": 1, "bbox": [1113.93, 418.81, 203.58, 192.83], "category_id": 1}, {"id": 2, "bbox": [528.9, 77.13, 139.32, 172.53], "category_id": 1}, {"id": 3, "bbox": [447.74, 849.8, 328.7, 74.42], "category_id": 2}, {"id": 4, "bbox": [973.25, 391.75, 67.63, 54.12], "category_id": 3}, {"id": 5, "bbox": [185.32, 1083.22, 42.61, 56.16], "category_id": 3}, {"id": 6, "bbox": [835.95, 713.8, 378.08, 462.12], "category_id": 1}, {"id": 7, "bbox": [121.74, 382.95, 72.37, 59.54], "category_id": 3}, {"id": 8, "bbox": [986.78, 1107.58, 64.25, 59.54], "category_id": 3}, {"id": 9, "bbox": [47.34, 77.13, 267.16, 329.5], "category_id": 1}, {"id": 10, "bbox": [33.14, 748.99, 365.9, 338.97], "category_id": 1}, {"id": 11, "bbox": [432.86, 151.56, 51.4, 76.45], "category_id": 2}, {"id": 12, "bbox": [808.22, 0.0, 372.67, 442.49], "category_id": 1}], "caption": "Scheme 2. Access to Key Intermediate 7 from Acetophenone 12 ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 422, 417, 452], "ImageBB": [82, 461, 420, 773]}, "reactions": [{"reactants": [9, 11, 2], "conditions": [], "products": [12]}, {"reactants": [12, 1], "conditions": [], "products": [6]}, {"reactants": [6], "conditions": [3], "products": [10]}], "diagram_type": "tree"}], "roles": [{"id": 1, "name": "reactants"}, {"id": 2, "name": "conditions"}, {"id": 3, "name": "products"}]}